Lanthanide/ATP Interaction in Water Mediated by Luminescent Hemispherical-Shaped Complexes.
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| Title: | Lanthanide/ATP Interaction in Water Mediated by Luminescent Hemispherical-Shaped Complexes. |
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| Authors: | Mameri, Samir1, Charbonnière, Loïc J.1, Ziessel, Raymond F.1 ziessel@chimie.u-strasbg.fr |
| Source: | Inorganic Chemistry. 3/22/2004, Vol. 43 Issue 6, p1819-1821. 3p. 2 Charts, 4 Graphs. |
| Subjects: | Ligands (Chemistry), Rare earth metals, Adenosine triphosphate, Water, Metal complexes, Emission spectroscopy |
| Abstract: | Ligand LH2, composed of two bipyridylcarboxylate fragments linked to an amino butyl chain, reacts with europium and terbium to form luminescent complexes in water at neutral pH. When testing these unsaturated complexes as anion sensors with NO3-, HPO42-, AMP, ADP, and ATP, a marked selectivity is observed for HPO42- and ATP4- at pH = 7.0. The interaction of these anions with the complex was investigated by means of absorption and emission spectroscopies. With ATP4-, ES-MS and 31P NMR experiments revealed the formation of a [Ln·U·(ATP)]3- ternary species. [ABSTRACT FROM AUTHOR] |
| Copyright of Inorganic Chemistry is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 12918993 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Lanthanide/ATP Interaction in Water Mediated by Luminescent Hemispherical-Shaped Complexes. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Mameri%2C+Samir%22">Mameri, Samir</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Charbonnière%2C+Loïc+J%2E%22">Charbonnière, Loïc J.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Ziessel%2C+Raymond+F%2E%22">Ziessel, Raymond F.</searchLink><relatesTo>1</relatesTo><i> ziessel@chimie.u-strasbg.fr</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Inorganic+Chemistry%22">Inorganic Chemistry</searchLink>. 3/22/2004, Vol. 43 Issue 6, p1819-1821. 3p. 2 Charts, 4 Graphs. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Ligands+%28Chemistry%29%22">Ligands (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Rare+earth+metals%22">Rare earth metals</searchLink><br /><searchLink fieldCode="DE" term="%22Adenosine+triphosphate%22">Adenosine triphosphate</searchLink><br /><searchLink fieldCode="DE" term="%22Water%22">Water</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+complexes%22">Metal complexes</searchLink><br /><searchLink fieldCode="DE" term="%22Emission+spectroscopy%22">Emission spectroscopy</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Ligand LH2, composed of two bipyridylcarboxylate fragments linked to an amino butyl chain, reacts with europium and terbium to form luminescent complexes in water at neutral pH. When testing these unsaturated complexes as anion sensors with NO3-, HPO42-, AMP, ADP, and ATP, a marked selectivity is observed for HPO42- and ATP4- at pH = 7.0. The interaction of these anions with the complex was investigated by means of absorption and emission spectroscopies. With ATP4-, ES-MS and 31P NMR experiments revealed the formation of a [Ln·U·(ATP)]3- ternary species. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Inorganic Chemistry is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1021/ic030295s Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 3 StartPage: 1819 Subjects: – SubjectFull: Ligands (Chemistry) Type: general – SubjectFull: Rare earth metals Type: general – SubjectFull: Adenosine triphosphate Type: general – SubjectFull: Water Type: general – SubjectFull: Metal complexes Type: general – SubjectFull: Emission spectroscopy Type: general Titles: – TitleFull: Lanthanide/ATP Interaction in Water Mediated by Luminescent Hemispherical-Shaped Complexes. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Mameri, Samir – PersonEntity: Name: NameFull: Charbonnière, Loïc J. – PersonEntity: Name: NameFull: Ziessel, Raymond F. IsPartOfRelationships: – BibEntity: Dates: – D: 22 M: 03 Text: 3/22/2004 Type: published Y: 2004 Identifiers: – Type: issn-print Value: 00201669 Numbering: – Type: volume Value: 43 – Type: issue Value: 6 Titles: – TitleFull: Inorganic Chemistry Type: main |
| ResultId | 1 |
