Biological anodic oxidation and cathodic reduction reactions for improved bioelectrochemical treatment of petroleum refinery wastewater.

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Title: Biological anodic oxidation and cathodic reduction reactions for improved bioelectrochemical treatment of petroleum refinery wastewater.
Authors: Mohanakrishna, Gunda1, Abu-Reesh, Ibrahim M.1 abureesh@qu.edu.qa, Al-Raoush, Riyadh I.2
Source: Journal of Cleaner Production. Jul2018, Vol. 190, p44-52. 9p.
Subjects: Petroleum refineries -- Waste, Wastewater treatment, Electrolytic oxidation, Cathodes, Oxidation-reduction reaction, Bioelectrochemistry
Abstract: Bioelectrochemical systems (BESs) were evaluated for the bioelectrochemical treatment (BET) of petroleum refinery wastewater (PRW) by applying mild electrochemical potential in the range of 400–1000 mV on a single chamber membrane-less BES configured with anodic and cathodic biofilms. After four days of cycle operation in batch mode, BES achieved a maximum current density of 278 mA/m 2 and a power density of 222 mW/m 2 using applied potential of 800 mV. This system also achieved COD degradation rate of 0.364 kg COD/m 3 -day. Diesel range organics (DROs) exhibited more than 90% degradation, which is 15 times higher than the abiotic control. Electrochemically active bioanode and biocathode contributed to the degradation of PRW through both oxidation and reduction reactions with mild applied potentials. This also resulted in a 30% improvement in COD removal compared to MFC with biocatalyst only on the anode. The function of improved bioelectrochemical treatment was also exhibited by redox current values of cyclic voltammograms. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Cleaner Production is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Biological anodic oxidation and cathodic reduction reactions for improved bioelectrochemical treatment of petroleum refinery wastewater.
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  Data: <searchLink fieldCode="AR" term="%22Mohanakrishna%2C+Gunda%22">Mohanakrishna, Gunda</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Abu-Reesh%2C+Ibrahim+M%2E%22">Abu-Reesh, Ibrahim M.</searchLink><relatesTo>1</relatesTo><i> abureesh@qu.edu.qa</i><br /><searchLink fieldCode="AR" term="%22Al-Raoush%2C+Riyadh+I%2E%22">Al-Raoush, Riyadh I.</searchLink><relatesTo>2</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Cleaner+Production%22">Journal of Cleaner Production</searchLink>. Jul2018, Vol. 190, p44-52. 9p.
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  Data: <searchLink fieldCode="DE" term="%22Petroleum+refineries+--+Waste%22">Petroleum refineries -- Waste</searchLink><br /><searchLink fieldCode="DE" term="%22Wastewater+treatment%22">Wastewater treatment</searchLink><br /><searchLink fieldCode="DE" term="%22Electrolytic+oxidation%22">Electrolytic oxidation</searchLink><br /><searchLink fieldCode="DE" term="%22Cathodes%22">Cathodes</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidation-reduction+reaction%22">Oxidation-reduction reaction</searchLink><br /><searchLink fieldCode="DE" term="%22Bioelectrochemistry%22">Bioelectrochemistry</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Bioelectrochemical systems (BESs) were evaluated for the bioelectrochemical treatment (BET) of petroleum refinery wastewater (PRW) by applying mild electrochemical potential in the range of 400–1000 mV on a single chamber membrane-less BES configured with anodic and cathodic biofilms. After four days of cycle operation in batch mode, BES achieved a maximum current density of 278 mA/m 2 and a power density of 222 mW/m 2 using applied potential of 800 mV. This system also achieved COD degradation rate of 0.364 kg COD/m 3 -day. Diesel range organics (DROs) exhibited more than 90% degradation, which is 15 times higher than the abiotic control. Electrochemically active bioanode and biocathode contributed to the degradation of PRW through both oxidation and reduction reactions with mild applied potentials. This also resulted in a 30% improvement in COD removal compared to MFC with biocatalyst only on the anode. The function of improved bioelectrochemical treatment was also exhibited by redox current values of cyclic voltammograms. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Cleaner Production is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1016/j.jclepro.2018.04.141
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 9
        StartPage: 44
    Subjects:
      – SubjectFull: Petroleum refineries -- Waste
        Type: general
      – SubjectFull: Wastewater treatment
        Type: general
      – SubjectFull: Electrolytic oxidation
        Type: general
      – SubjectFull: Cathodes
        Type: general
      – SubjectFull: Oxidation-reduction reaction
        Type: general
      – SubjectFull: Bioelectrochemistry
        Type: general
    Titles:
      – TitleFull: Biological anodic oxidation and cathodic reduction reactions for improved bioelectrochemical treatment of petroleum refinery wastewater.
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            NameFull: Mohanakrishna, Gunda
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            NameFull: Abu-Reesh, Ibrahim M.
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            NameFull: Al-Raoush, Riyadh I.
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            – D: 20
              M: 07
              Text: Jul2018
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              Y: 2018
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              Value: 190
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