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Modern sulfocationites for separation of lanthanides and transplutonium elements partitioning via displacement complexing chromatography.

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Title: Modern sulfocationites for separation of lanthanides and transplutonium elements partitioning via displacement complexing chromatography.
Authors: Kharitonov, O. V.1, Firsova, L. A.1, Milyutin, V. V.1, Kozlitin, E. A.1 evgeny_kozlitin@mail.ru
Source: Journal of Radioanalytical & Nuclear Chemistry. Jul2018, Vol. 317 Issue 1, p585-592. 8p. 3 Charts, 8 Graphs.
Subjects: Rare earth metals, Transplutonium elements, Grain size, Polydisperse media
Abstract: Separation of rare earth elements (REE) as a model system for transplutonium elements (TPE) partitioning via displacement complexing chromatography technique was investigated using sulfocationites commercially available from Purolite (UK), Dow Chemical (USA), Rohm and Haas (USA), and LLC SPA ‘Tokem’ (Russia). The specific volume, total mass and volume capacity of the sorbents were determined. Effects of the dispersity (monodispersed and polydispersed), grain size and cross-linking degree on the REE and TPE separation performance were discussed. Materials and conditions for the highest REE and TPE separation process efficiency were selected. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Radioanalytical & Nuclear Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Separation of rare earth elements (REE) as a model system for transplutonium elements (TPE) partitioning via displacement complexing chromatography technique was investigated using sulfocationites commercially available from Purolite (UK), Dow Chemical (USA), Rohm and Haas (USA), and LLC SPA ‘Tokem’ (Russia). The specific volume, total mass and volume capacity of the sorbents were determined. Effects of the dispersity (monodispersed and polydispersed), grain size and cross-linking degree on the REE and TPE separation performance were discussed. Materials and conditions for the highest REE and TPE separation process efficiency were selected. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Journal of Radioanalytical & Nuclear Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1007/s10967-018-5906-1
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        Text: English
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        Type: general
      – SubjectFull: Transplutonium elements
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      – SubjectFull: Grain size
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              Text: Jul2018
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