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Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)].

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Title: Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)].
Authors: Reinholdt, Anders1, Bendix, Jesper1, Hill, Anthony F.2, Manzano, Richard A.2
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 11/14/2018, Vol. 47 Issue 42, p14893-14896. 4p.
Subjects: Tungsten compounds, Chemical reactions, Carbon
Abstract: The reaction of [Ru(CAuCl)Cl2(PCy3)2] with [W(≡CSnnBu3)(CO)2(Tp*)] (obtained from [W(≡CBr)(CO)2(Tp*)], nBuLi and ClSnnBu3) affords the heterotetrametallic bis(carbido) complex [WRuAu2(μ-C)2Cl3(CO)2(PCy3)2(Tp*)] in which the two distinct μ-carbido ligands adopt linear and T-shaped geometry at carbon. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 132762019
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Confluence of disparate carbido chemistries: [WRuAu<subscript>2</subscript>(μ-C)<subscript>2</subscript>Cl<subscript>2</subscript>(CO)<subscript>2</subscript>(PCy<subscript>3</subscript>)<subscript>2</subscript>(Tp*)].
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  Data: <searchLink fieldCode="AR" term="%22Reinholdt%2C+Anders%22">Reinholdt, Anders</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Bendix%2C+Jesper%22">Bendix, Jesper</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Hill%2C+Anthony+F%2E%22">Hill, Anthony F.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Manzano%2C+Richard+A%2E%22">Manzano, Richard A.</searchLink><relatesTo>2</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. 11/14/2018, Vol. 47 Issue 42, p14893-14896. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Tungsten+compounds%22">Tungsten compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reactions%22">Chemical reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Carbon%22">Carbon</searchLink>
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  Data: The reaction of [Ru(CAuCl)Cl2(PCy3)2] with [W(≡CSnnBu3)(CO)2(Tp*)] (obtained from [W(≡CBr)(CO)2(Tp*)], nBuLi and ClSnnBu3) affords the heterotetrametallic bis(carbido) complex [WRuAu2(μ-C)2Cl3(CO)2(PCy3)2(Tp*)] in which the two distinct μ-carbido ligands adopt linear and T-shaped geometry at carbon. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1039/c8dt03851a
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        Text: English
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        PageCount: 4
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        Type: general
      – SubjectFull: Chemical reactions
        Type: general
      – SubjectFull: Carbon
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      – TitleFull: Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)].
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              Text: 11/14/2018
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              Y: 2018
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