Composites for « white and green » solutions: Coupling UV resistance and chain extension effect from poly(butylene succinate) and layered double hydroxides composites.
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| Title: | Composites for « white and green » solutions: Coupling UV resistance and chain extension effect from poly(butylene succinate) and layered double hydroxides composites. |
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| Authors: | Marek, Adam A.1,2 adam.a.marek@polsl.pl, Verney, Vincent1, Totaro, Grazia3, Sisti, Laura3, Celli, Annamaria3, Leroux, Fabrice1 |
| Source: | Journal of Solid State Chemistry. Dec2018, Vol. 268, p9-15. 7p. |
| Subjects: | Layered double hydroxides, Solution (Chemistry), Coupling agents (Chemistry), Polybutenes, Thermal analysis, X-ray diffraction |
| Abstract: | Abstract Hybridization of layered double hydroxide (LDH) platelets of Zn 2 Al cation intra-sheet composition was performed with L -tyrosine (TYR), L -tryptophan (TRP) and 3-(4-hydroxyphenyl) propionic (HPP) acid, and the hybrid LDH materials were characterized by the means of conventional techniques as X-ray diffraction and thermal analysis to address their sandwich structures and their mass formulae, respectively. Subsequently they have been considered as "green" filler and dispersed into poly(butylene succinate) (PBS) through a melt extrusion process. In regard of the rheological properties, it was possible to extend the PBS chain thus leading to a better processability. Another aspect was the ability to stand photo-degradation under UV radiation for applicative purposes. Owing to the organic chromophores acting as potential UV stabilizers, it was found a higher chain extension effect for PBS in the case of LDH/TRP that was also performing in time of irradiation tests. This opens new routes for designing filler of "white and green" relevances to endow bio-source polymer with properties for practical applications and in respect of environment and global sustainability. Graphical abstract fx1 Highlights • The organo-modified Zn-Al layered double hydroxides were synthesized. • 3-(4-hydroxyphenyl)propionic acid, L -tyrosine and L -tryptophan were intercalated. • PBS composites with Zn-Al LDHs were prepared by melt extrusion. • The effect of Zn-Al LDHs on chain extension and photostability of PBS was observed. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Solid State Chemistry is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 132941292 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Composites for « white and green » solutions: Coupling UV resistance and chain extension effect from poly(butylene succinate) and layered double hydroxides composites. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Marek%2C+Adam+A%2E%22">Marek, Adam A.</searchLink><relatesTo>1,2</relatesTo><i> adam.a.marek@polsl.pl</i><br /><searchLink fieldCode="AR" term="%22Verney%2C+Vincent%22">Verney, Vincent</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Totaro%2C+Grazia%22">Totaro, Grazia</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Sisti%2C+Laura%22">Sisti, Laura</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Celli%2C+Annamaria%22">Celli, Annamaria</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Leroux%2C+Fabrice%22">Leroux, Fabrice</searchLink><relatesTo>1</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Solid+State+Chemistry%22">Journal of Solid State Chemistry</searchLink>. Dec2018, Vol. 268, p9-15. 7p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Layered+double+hydroxides%22">Layered double hydroxides</searchLink><br /><searchLink fieldCode="DE" term="%22Solution+%28Chemistry%29%22">Solution (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Coupling+agents+%28Chemistry%29%22">Coupling agents (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Polybutenes%22">Polybutenes</searchLink><br /><searchLink fieldCode="DE" term="%22Thermal+analysis%22">Thermal analysis</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Abstract Hybridization of layered double hydroxide (LDH) platelets of Zn 2 Al cation intra-sheet composition was performed with L -tyrosine (TYR), L -tryptophan (TRP) and 3-(4-hydroxyphenyl) propionic (HPP) acid, and the hybrid LDH materials were characterized by the means of conventional techniques as X-ray diffraction and thermal analysis to address their sandwich structures and their mass formulae, respectively. Subsequently they have been considered as "green" filler and dispersed into poly(butylene succinate) (PBS) through a melt extrusion process. In regard of the rheological properties, it was possible to extend the PBS chain thus leading to a better processability. Another aspect was the ability to stand photo-degradation under UV radiation for applicative purposes. Owing to the organic chromophores acting as potential UV stabilizers, it was found a higher chain extension effect for PBS in the case of LDH/TRP that was also performing in time of irradiation tests. This opens new routes for designing filler of "white and green" relevances to endow bio-source polymer with properties for practical applications and in respect of environment and global sustainability. Graphical abstract fx1 Highlights • The organo-modified Zn-Al layered double hydroxides were synthesized. • 3-(4-hydroxyphenyl)propionic acid, L -tyrosine and L -tryptophan were intercalated. • PBS composites with Zn-Al LDHs were prepared by melt extrusion. • The effect of Zn-Al LDHs on chain extension and photostability of PBS was observed. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Solid State Chemistry is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.jssc.2018.08.026 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 7 StartPage: 9 Subjects: – SubjectFull: Layered double hydroxides Type: general – SubjectFull: Solution (Chemistry) Type: general – SubjectFull: Coupling agents (Chemistry) Type: general – SubjectFull: Polybutenes Type: general – SubjectFull: Thermal analysis Type: general – SubjectFull: X-ray diffraction Type: general Titles: – TitleFull: Composites for « white and green » solutions: Coupling UV resistance and chain extension effect from poly(butylene succinate) and layered double hydroxides composites. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Marek, Adam A. – PersonEntity: Name: NameFull: Verney, Vincent – PersonEntity: Name: NameFull: Totaro, Grazia – PersonEntity: Name: NameFull: Sisti, Laura – PersonEntity: Name: NameFull: Celli, Annamaria – PersonEntity: Name: NameFull: Leroux, Fabrice IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 12 Text: Dec2018 Type: published Y: 2018 Identifiers: – Type: issn-print Value: 00224596 Numbering: – Type: volume Value: 268 Titles: – TitleFull: Journal of Solid State Chemistry Type: main |
| ResultId | 1 |
