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Oxidative drying properties of a helmet pentadentate phthalocyanine-derived iron(III) complex.

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Title: Oxidative drying properties of a helmet pentadentate phthalocyanine-derived iron(III) complex.
Authors: Dubrulle, L.1 (AUTHOR), Lebeuf, R.1 (AUTHOR) raphael.lebeuf@univ-lille.fr, Nardello-Rataj, V.1 (AUTHOR) veronique.rataj@univ-lille.fr
Source: Progress in Organic Coatings. Jun2019, Vol. 131, p364-370. 7p.
Subjects: Emulsion paint, Chemical processes, Hydroperoxides, Alkyd resins, Iron, Paint materials, Catalytic oxidation
Abstract: Graphical abstract Highlights • Structural reassignment of a hexaisoindoline Fe(III) complex into a phthalocyanine-derived Fe(III) one. • It has a high catalytic activity on the oxidation of FAMEs and on the decomposition of hydroperoxides. • It induces good hardness and low yellowing of a paint film. Abstract The structure of a hexaisoindoline iron(III) complex reported in 1962 was corrected as the one of a recently described helmet phthalocyanine-like iron(III) complex. Accordingly, its catalytic activities were compared to commercial Co(II) and Fe(II) driers towards the oxidation of bulk FAMEs through oxygen uptake measurements and by ATR-FTIR spectroscopy, as well as its ability to decompose methyl linoleate hydroperoxides. It is shown that the phthalocyanine-like iron(III) complex presents higher catalytic performances at low concentrations and under mild conditions of temperature and pressure, both on the overall oxidation process and on the decomposition steps of the drying chemical process. The efficiency of the phthalocyanine-derived iron(III) complex was confirmed by the drying of an alkyd resin emulsion and a satin white paint formulation which exhibits a very good hardness and a low yellowing of the film. [ABSTRACT FROM AUTHOR]
Copyright of Progress in Organic Coatings is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 135743429
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Oxidative drying properties of a helmet pentadentate phthalocyanine-derived iron(III) complex.
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  Data: <searchLink fieldCode="AR" term="%22Dubrulle%2C+L%2E%22">Dubrulle, L.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Lebeuf%2C+R%2E%22">Lebeuf, R.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> raphael.lebeuf@univ-lille.fr</i><br /><searchLink fieldCode="AR" term="%22Nardello-Rataj%2C+V%2E%22">Nardello-Rataj, V.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> veronique.rataj@univ-lille.fr</i>
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  Data: <searchLink fieldCode="JN" term="%22Progress+in+Organic+Coatings%22">Progress in Organic Coatings</searchLink>. Jun2019, Vol. 131, p364-370. 7p.
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  Data: <searchLink fieldCode="DE" term="%22Emulsion+paint%22">Emulsion paint</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+processes%22">Chemical processes</searchLink><br /><searchLink fieldCode="DE" term="%22Hydroperoxides%22">Hydroperoxides</searchLink><br /><searchLink fieldCode="DE" term="%22Alkyd+resins%22">Alkyd resins</searchLink><br /><searchLink fieldCode="DE" term="%22Iron%22">Iron</searchLink><br /><searchLink fieldCode="DE" term="%22Paint+materials%22">Paint materials</searchLink><br /><searchLink fieldCode="DE" term="%22Catalytic+oxidation%22">Catalytic oxidation</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Graphical abstract Highlights • Structural reassignment of a hexaisoindoline Fe(III) complex into a phthalocyanine-derived Fe(III) one. • It has a high catalytic activity on the oxidation of FAMEs and on the decomposition of hydroperoxides. • It induces good hardness and low yellowing of a paint film. Abstract The structure of a hexaisoindoline iron(III) complex reported in 1962 was corrected as the one of a recently described helmet phthalocyanine-like iron(III) complex. Accordingly, its catalytic activities were compared to commercial Co(II) and Fe(II) driers towards the oxidation of bulk FAMEs through oxygen uptake measurements and by ATR-FTIR spectroscopy, as well as its ability to decompose methyl linoleate hydroperoxides. It is shown that the phthalocyanine-like iron(III) complex presents higher catalytic performances at low concentrations and under mild conditions of temperature and pressure, both on the overall oxidation process and on the decomposition steps of the drying chemical process. The efficiency of the phthalocyanine-derived iron(III) complex was confirmed by the drying of an alkyd resin emulsion and a satin white paint formulation which exhibits a very good hardness and a low yellowing of the film. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Group: Ab
  Data: <i>Copyright of Progress in Organic Coatings is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.porgcoat.2019.03.007
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      – Code: eng
        Text: English
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        PageCount: 7
        StartPage: 364
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      – SubjectFull: Emulsion paint
        Type: general
      – SubjectFull: Chemical processes
        Type: general
      – SubjectFull: Hydroperoxides
        Type: general
      – SubjectFull: Alkyd resins
        Type: general
      – SubjectFull: Iron
        Type: general
      – SubjectFull: Paint materials
        Type: general
      – SubjectFull: Catalytic oxidation
        Type: general
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      – TitleFull: Oxidative drying properties of a helmet pentadentate phthalocyanine-derived iron(III) complex.
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            NameFull: Nardello-Rataj, V.
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              Text: Jun2019
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              Y: 2019
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