Volumetric, acoustic and transport properties of ternary solutions of l-serine and l-arginine in aqueous solutions of thiamine hydrochloride at different temperatures.
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| Title: | Volumetric, acoustic and transport properties of ternary solutions of l-serine and l-arginine in aqueous solutions of thiamine hydrochloride at different temperatures. |
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| Authors: | Rani, Ruby1 (AUTHOR), Kumar, Ashwani1 (AUTHOR), Sharma, Taniya1 (AUTHOR), Sharma, Tanu1 (AUTHOR), Bamezai, Rajinder K.1 (AUTHOR) rkbamezai@gmail.com |
| Source: | Journal of Chemical Thermodynamics. Aug2019, Vol. 135, p260-277. 18p. |
| Subjects: | Aqueous solutions, Vitamin B1, Molecular volume, Isentropic compression, Atmospheric pressure, Glycine |
| Abstract: | • Volumetric, acoustic and viscometric properties of amino acids in aqueous thiamine-HCl solutions were determined. • Apparent molar volume and transfer volume were calculated and analyzed. • Hepler's constant and d B /d T suggests structure making behavior of both the amino acids in aqueous thiamine-HCl solution. • The nature of solute-solute and solute-solvent interactions has been probed. The volumetric, acoustic and viscometric properties are used for investigating the interactions of l -serine and l -arginine in aqueous solutions of a vitamin, namely, thiamine hydrochloride, over a temperature range of (293.15–313.15) K and at atmospheric pressure. The limiting apparent molar volume, V 0 ϕ , and empirical parameter, S v , is evaluated from apparent molar volume, V ϕ. Similarly, limiting apparent molar isentropic compression, K 0 ϕ,s , and slope, S k , is evaluated from apparent molar isentropic compression, K ϕ,s. The corresponding transfer properties (Δ tr V 0 ϕ and Δ tr K 0 ϕ,s) from water to aqueous vitamin solutions are also evaluated. The viscosity data has also been used to analyze relative viscosity, ƞ r , viscosity B -coefficients and temperature derivative of B -coefficients, dB / dT. The various calculated parameters assist to procure valuable information regarding the presence of different kinds of intermolecular interactions in the ternary (l -serine/ l -arginine + water + thiamine-HCl) solutions. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Chemical Thermodynamics is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 136419221 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Volumetric, acoustic and transport properties of ternary solutions of l-serine and l-arginine in aqueous solutions of thiamine hydrochloride at different temperatures. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Rani%2C+Ruby%22">Rani, Ruby</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Kumar%2C+Ashwani%22">Kumar, Ashwani</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sharma%2C+Taniya%22">Sharma, Taniya</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sharma%2C+Tanu%22">Sharma, Tanu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Bamezai%2C+Rajinder+K%2E%22">Bamezai, Rajinder K.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> rkbamezai@gmail.com</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Chemical+Thermodynamics%22">Journal of Chemical Thermodynamics</searchLink>. Aug2019, Vol. 135, p260-277. 18p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Aqueous+solutions%22">Aqueous solutions</searchLink><br /><searchLink fieldCode="DE" term="%22Vitamin+B1%22">Vitamin B1</searchLink><br /><searchLink fieldCode="DE" term="%22Molecular+volume%22">Molecular volume</searchLink><br /><searchLink fieldCode="DE" term="%22Isentropic+compression%22">Isentropic compression</searchLink><br /><searchLink fieldCode="DE" term="%22Atmospheric+pressure%22">Atmospheric pressure</searchLink><br /><searchLink fieldCode="DE" term="%22Glycine%22">Glycine</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: • Volumetric, acoustic and viscometric properties of amino acids in aqueous thiamine-HCl solutions were determined. • Apparent molar volume and transfer volume were calculated and analyzed. • Hepler's constant and d B /d T suggests structure making behavior of both the amino acids in aqueous thiamine-HCl solution. • The nature of solute-solute and solute-solvent interactions has been probed. The volumetric, acoustic and viscometric properties are used for investigating the interactions of l -serine and l -arginine in aqueous solutions of a vitamin, namely, thiamine hydrochloride, over a temperature range of (293.15–313.15) K and at atmospheric pressure. The limiting apparent molar volume, V 0 ϕ , and empirical parameter, S v , is evaluated from apparent molar volume, V ϕ. Similarly, limiting apparent molar isentropic compression, K 0 ϕ,s , and slope, S k , is evaluated from apparent molar isentropic compression, K ϕ,s. The corresponding transfer properties (Δ tr V 0 ϕ and Δ tr K 0 ϕ,s) from water to aqueous vitamin solutions are also evaluated. The viscosity data has also been used to analyze relative viscosity, ƞ r , viscosity B -coefficients and temperature derivative of B -coefficients, dB / dT. The various calculated parameters assist to procure valuable information regarding the presence of different kinds of intermolecular interactions in the ternary (l -serine/ l -arginine + water + thiamine-HCl) solutions. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Chemical Thermodynamics is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.jct.2019.03.039 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 18 StartPage: 260 Subjects: – SubjectFull: Aqueous solutions Type: general – SubjectFull: Vitamin B1 Type: general – SubjectFull: Molecular volume Type: general – SubjectFull: Isentropic compression Type: general – SubjectFull: Atmospheric pressure Type: general – SubjectFull: Glycine Type: general Titles: – TitleFull: Volumetric, acoustic and transport properties of ternary solutions of l-serine and l-arginine in aqueous solutions of thiamine hydrochloride at different temperatures. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Rani, Ruby – PersonEntity: Name: NameFull: Kumar, Ashwani – PersonEntity: Name: NameFull: Sharma, Taniya – PersonEntity: Name: NameFull: Sharma, Tanu – PersonEntity: Name: NameFull: Bamezai, Rajinder K. IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 08 Text: Aug2019 Type: published Y: 2019 Identifiers: – Type: issn-print Value: 00219614 Numbering: – Type: volume Value: 135 Titles: – TitleFull: Journal of Chemical Thermodynamics Type: main |
| ResultId | 1 |
