Preparation of YSZ electrolyte coating on conducting porous Ni–YSZ cermet by DC and pulsed constant voltage electrophoretic deposition process for SOFCs applications.

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Title: Preparation of YSZ electrolyte coating on conducting porous Ni–YSZ cermet by DC and pulsed constant voltage electrophoretic deposition process for SOFCs applications.
Authors: Oskouyi, Omid Ekhlasi1 (AUTHOR), Maghsoudipour, Amir1,2 (AUTHOR) am.maghsoudipour@gmail.com, Shahmiri, Mohammad1 (AUTHOR), Hasheminiasari, Masood1 (AUTHOR)
Source: Journal of Alloys & Compounds. Jul2019, Vol. 795, p361-369. 9p.
Subjects: Electrophoretic deposition, Anodes, Solid oxide fuel cells, Electrolytes, Fuel cells, Scanning electron microscopes
Abstract: In this article, electrolyte coating of solid oxide fuel cells (SOFCs) based on yttria stabilized zirconia (YSZ) on Ni-YSZ cermet fuel cells anode in ethanol was investigated using pulsed constant voltage and DC electrophoretic deposition (EPD). The NiO-YSZ substrate was prepared by hydraulic pressing of mixed YSZ, NiO and starch powders following pre-sintering at 1200 °C for 3 h. The NiO-YSZ composite was reduced in hydrogen atmosphere in order to produce Ni-YSZ cermet. The suspension properties and EPD process parameters were investigated. The YSZ electrolyte was sintered at 1350 °C for 4 h. The morphology of sintered YSZ electrolyte coating was investigated by scanning electron microscope (SEM) and optical microscopy (OM). Results showed that dense and uniform coatings were deposited in ethanol with solid concentration of 10 g/L of YSZ, 0.5 g/L of iodine at distance of anode to cathode being 5 mm. The thickness of YSZ electrolyte after 6 min of deposition with pulsed constant voltage and DC electrophoretic deposition were 20 and 88 ± 1 μm, respectively. • YSZ suspension in ethanol was more suitable than isopropanol for EPD. • In PC relative to DC the formed YSZ coating was more uniform, dense and crack-free. • The optimal thickness of YSZ coating by PC and DC were 20 and 88±1 μm, respectively. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Alloys & Compounds is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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Items – Name: Title
  Label: Title
  Group: Ti
  Data: Preparation of YSZ electrolyte coating on conducting porous Ni–YSZ cermet by DC and pulsed constant voltage electrophoretic deposition process for SOFCs applications.
– Name: Author
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  Data: <searchLink fieldCode="AR" term="%22Oskouyi%2C+Omid+Ekhlasi%22">Oskouyi, Omid Ekhlasi</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Maghsoudipour%2C+Amir%22">Maghsoudipour, Amir</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> am.maghsoudipour@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Shahmiri%2C+Mohammad%22">Shahmiri, Mohammad</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hasheminiasari%2C+Masood%22">Hasheminiasari, Masood</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Alloys+%26+Compounds%22">Journal of Alloys & Compounds</searchLink>. Jul2019, Vol. 795, p361-369. 9p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Electrophoretic+deposition%22">Electrophoretic deposition</searchLink><br /><searchLink fieldCode="DE" term="%22Anodes%22">Anodes</searchLink><br /><searchLink fieldCode="DE" term="%22Solid+oxide+fuel+cells%22">Solid oxide fuel cells</searchLink><br /><searchLink fieldCode="DE" term="%22Electrolytes%22">Electrolytes</searchLink><br /><searchLink fieldCode="DE" term="%22Fuel+cells%22">Fuel cells</searchLink><br /><searchLink fieldCode="DE" term="%22Scanning+electron+microscopes%22">Scanning electron microscopes</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: In this article, electrolyte coating of solid oxide fuel cells (SOFCs) based on yttria stabilized zirconia (YSZ) on Ni-YSZ cermet fuel cells anode in ethanol was investigated using pulsed constant voltage and DC electrophoretic deposition (EPD). The NiO-YSZ substrate was prepared by hydraulic pressing of mixed YSZ, NiO and starch powders following pre-sintering at 1200 °C for 3 h. The NiO-YSZ composite was reduced in hydrogen atmosphere in order to produce Ni-YSZ cermet. The suspension properties and EPD process parameters were investigated. The YSZ electrolyte was sintered at 1350 °C for 4 h. The morphology of sintered YSZ electrolyte coating was investigated by scanning electron microscope (SEM) and optical microscopy (OM). Results showed that dense and uniform coatings were deposited in ethanol with solid concentration of 10 g/L of YSZ, 0.5 g/L of iodine at distance of anode to cathode being 5 mm. The thickness of YSZ electrolyte after 6 min of deposition with pulsed constant voltage and DC electrophoretic deposition were 20 and 88 ± 1 μm, respectively. • YSZ suspension in ethanol was more suitable than isopropanol for EPD. • In PC relative to DC the formed YSZ coating was more uniform, dense and crack-free. • The optimal thickness of YSZ coating by PC and DC were 20 and 88±1 μm, respectively. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Alloys & Compounds is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.jallcom.2019.04.334
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      – Code: eng
        Text: English
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        PageCount: 9
        StartPage: 361
    Subjects:
      – SubjectFull: Electrophoretic deposition
        Type: general
      – SubjectFull: Anodes
        Type: general
      – SubjectFull: Solid oxide fuel cells
        Type: general
      – SubjectFull: Electrolytes
        Type: general
      – SubjectFull: Fuel cells
        Type: general
      – SubjectFull: Scanning electron microscopes
        Type: general
    Titles:
      – TitleFull: Preparation of YSZ electrolyte coating on conducting porous Ni–YSZ cermet by DC and pulsed constant voltage electrophoretic deposition process for SOFCs applications.
        Type: main
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      – PersonEntity:
          Name:
            NameFull: Oskouyi, Omid Ekhlasi
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            NameFull: Maghsoudipour, Amir
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            NameFull: Shahmiri, Mohammad
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            NameFull: Hasheminiasari, Masood
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          Dates:
            – D: 30
              M: 07
              Text: Jul2019
              Type: published
              Y: 2019
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              Value: 795
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            – TitleFull: Journal of Alloys & Compounds
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