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Spectroscopic characterization of intramolecular charge transfer of sodium 4-(N,N-dimethylamino)naphthalene-1-sulfonate

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Title: Spectroscopic characterization of intramolecular charge transfer of sodium 4-(N,N-dimethylamino)naphthalene-1-sulfonate
Authors: Lin, Li-Rong1 linlr@jingxian.xmu.edu.cn, Yang, Wen-Liang1, Zheng, Guang-Le1, Jiang, Yun-Bao1,2
Source: Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy. Aug2004, Vol. 60 Issue 10, p2209-2213. 5p.
Subjects: Naphthalene, Fluorescence, Organic solvents, Water, Cyclodextrins
Abstract: In this paper, a new dual fluorescent N,N-dimethylaminonaphthalene derivative, sodium 4-(N,N-dimethylamino)naphthalene-1-sulfonate (SDMDNS), was reported. It was found that SDMDNS emits dual fluorescence only in highly polar solvent water but not in organic solvents such as methanol, dioxane and acetonitrile. Only a single broad band emission at ca. 420 nm was observed in the short wavelength region in organic solvents. The dual fluorescence of SDMDNS in water was found at 423 and 520 nm, respectively. Introduction of organic solvent as ethanol into aqueous solution of SDMDNS leads to blue shift of the long-wavelength emission, and this was evidently supported by introduction of cyclodextrin or surfactant in the aqueous solution. It indicates that a highly polar solvent was required to bring out dual fluorescence; furthermore, the short wavelength fluorescence is emitted from locally excited (LE) state and the long wavelength fluorescence is emitted from charge transfer (CT) state. The pH dependence of the dual fluorescence of SDMDNS demonstrates that the neutral form of the molecular has a higher ratio of CT band intensity to LE band. Temperature effect on the excited state of SDMDNS was also examined and gave stabilization enthalpy (-ΔH ) of the CT reaction 8.7 kJ mol-1. [Copyright &y& Elsevier]
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Database: Engineering Source
Description
Abstract:In this paper, a new dual fluorescent N,N-dimethylaminonaphthalene derivative, sodium 4-(N,N-dimethylamino)naphthalene-1-sulfonate (SDMDNS), was reported. It was found that SDMDNS emits dual fluorescence only in highly polar solvent water but not in organic solvents such as methanol, dioxane and acetonitrile. Only a single broad band emission at ca. 420 nm was observed in the short wavelength region in organic solvents. The dual fluorescence of SDMDNS in water was found at 423 and 520 nm, respectively. Introduction of organic solvent as ethanol into aqueous solution of SDMDNS leads to blue shift of the long-wavelength emission, and this was evidently supported by introduction of cyclodextrin or surfactant in the aqueous solution. It indicates that a highly polar solvent was required to bring out dual fluorescence; furthermore, the short wavelength fluorescence is emitted from locally excited (LE) state and the long wavelength fluorescence is emitted from charge transfer (CT) state. The pH dependence of the dual fluorescence of SDMDNS demonstrates that the neutral form of the molecular has a higher ratio of CT band intensity to LE band. Temperature effect on the excited state of SDMDNS was also examined and gave stabilization enthalpy (-ΔH ) of the CT reaction 8.7 kJ mol-1. [Copyright &y& Elsevier]
ISSN:13861425
DOI:10.1016/j.saa.2003.11.017