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Structural diversity, magnetic property, or luminescence sensing of Co(ii) and Cd(ii) coordination polymers derived from designed 3,3′-((5-carboxy-1,3-phenylene)bis(oxy))dibenzoic acid.

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Title: Structural diversity, magnetic property, or luminescence sensing of Co(ii) and Cd(ii) coordination polymers derived from designed 3,3′-((5-carboxy-1,3-phenylene)bis(oxy))dibenzoic acid.
Authors: Yang, Dong-Dong1, Lu, Li-Ping1, Zhu, Miao-Li1,2
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 7/21/2019, Vol. 48 Issue 27, p10220-10234. 15p.
Subjects: Coordination polymers, Carboxylates, Luminescence, X-ray powder diffraction, Magnetic properties, Aqueous solutions, Complex ions
Abstract: Five novel coordination polymers (CPs), formulated as {[Co3(μ4-cpboda)2(μ1,1-OH2)2(2,2-bipy)2]·1.5DMF·2H2O}n (1), {[Co3(μ3-cpboda)2(4,4′-bpy)3(H2O)2]·4H2O}n (2), {[Co(μ2-H2cpboda)2(1,4-bib)3(H2O)2]·H2O·DMF·1.5HCOOH}n (3), [Cd(μ3-Hcpboda)(1,4-bib)]n (4), and {[Cd3(μ4-cpboda)2(μ1,1-OH2)2(phen)2]·2DMF·1.5H2O}n (5) (H3cpboda = 3,3′-((5-carboxy-1,3-phenylene)bis(oxy))dibenzoic acid, 2,2-bipy = 2,2-bipyridine, 4,4′-bpy = 4,4′-bipyridine, 1,4-bib = 1,4-di(1H-imidazol-1-yl)benzene, phen = 1,10-phenanthroline) have been synthesized under solvothermal conditions and characterized by elemental analyses (EAs), single-crystal X-ray diffraction analyses, X-ray powder diffraction analyses (PXRD), FT-IR spectra, and thermogravimetric analyses (TGAs). The structural analyses reveal that these complexes have four 2D coordinate polymers and one 3D framework, in which metal ions are in octahedral coordination geometries in 1–3 and 5, but seven-coordinated disordered pentagonal bipyramids in 4. Complexes 1 and 5 represent linear trinuclear [M3(μ1,1-OH2)2(μ1,3-COO)4] SBUs in 1 (M = Co(ii)) and in 5 (M = Cd(ii)) based on a 3,4,6-connected net with a point symbol (32·4)2(32·83·9)2(34·42·82·94·103) net, complex 2 exhibiting a (3-c)2(4-c)(4-c)2 3D structure with the (52·6·82·9)2(52·62·92)(52·6)2 topology and complexes 3 and 4 having a novel 2D framework with the point symbol of (44·62). Magnetization analyses disclose the antiferromagnetic (AF) behaviors between Co(ii) ions in complexes 1 & 3 and S = 3/2 (Co2+) spin Heisenberg chains with alternating magnetic sequences (F/F/AF)n in 2. Fluorescence measurements indicate that 4 and 5 are promising luminescence sensors for the detection of CrO42− and Cr2O72− anions in aqueous solution. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Structural diversity, magnetic property, or luminescence sensing of Co(ii) and Cd(ii) coordination polymers derived from designed 3,3′-((5-carboxy-1,3-phenylene)bis(oxy))dibenzoic acid.
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  Data: <searchLink fieldCode="AR" term="%22Yang%2C+Dong-Dong%22">Yang, Dong-Dong</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Lu%2C+Li-Ping%22">Lu, Li-Ping</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Zhu%2C+Miao-Li%22">Zhu, Miao-Li</searchLink><relatesTo>1,2</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. 7/21/2019, Vol. 48 Issue 27, p10220-10234. 15p.
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  Data: <searchLink fieldCode="DE" term="%22Coordination+polymers%22">Coordination polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Carboxylates%22">Carboxylates</searchLink><br /><searchLink fieldCode="DE" term="%22Luminescence%22">Luminescence</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+powder+diffraction%22">X-ray powder diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22Magnetic+properties%22">Magnetic properties</searchLink><br /><searchLink fieldCode="DE" term="%22Aqueous+solutions%22">Aqueous solutions</searchLink><br /><searchLink fieldCode="DE" term="%22Complex+ions%22">Complex ions</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Five novel coordination polymers (CPs), formulated as {[Co3(μ4-cpboda)2(μ1,1-OH2)2(2,2-bipy)2]·1.5DMF·2H2O}n (1), {[Co3(μ3-cpboda)2(4,4′-bpy)3(H2O)2]·4H2O}n (2), {[Co(μ2-H2cpboda)2(1,4-bib)3(H2O)2]·H2O·DMF·1.5HCOOH}n (3), [Cd(μ3-Hcpboda)(1,4-bib)]n (4), and {[Cd3(μ4-cpboda)2(μ1,1-OH2)2(phen)2]·2DMF·1.5H2O}n (5) (H3cpboda = 3,3′-((5-carboxy-1,3-phenylene)bis(oxy))dibenzoic acid, 2,2-bipy = 2,2-bipyridine, 4,4′-bpy = 4,4′-bipyridine, 1,4-bib = 1,4-di(1H-imidazol-1-yl)benzene, phen = 1,10-phenanthroline) have been synthesized under solvothermal conditions and characterized by elemental analyses (EAs), single-crystal X-ray diffraction analyses, X-ray powder diffraction analyses (PXRD), FT-IR spectra, and thermogravimetric analyses (TGAs). The structural analyses reveal that these complexes have four 2D coordinate polymers and one 3D framework, in which metal ions are in octahedral coordination geometries in 1–3 and 5, but seven-coordinated disordered pentagonal bipyramids in 4. Complexes 1 and 5 represent linear trinuclear [M3(μ1,1-OH2)2(μ1,3-COO)4] SBUs in 1 (M = Co(ii)) and in 5 (M = Cd(ii)) based on a 3,4,6-connected net with a point symbol (32·4)2(32·83·9)2(34·42·82·94·103) net, complex 2 exhibiting a (3-c)2(4-c)(4-c)2 3D structure with the (52·6·82·9)2(52·62·92)(52·6)2 topology and complexes 3 and 4 having a novel 2D framework with the point symbol of (44·62). Magnetization analyses disclose the antiferromagnetic (AF) behaviors between Co(ii) ions in complexes 1 & 3 and S = 3/2 (Co2+) spin Heisenberg chains with alternating magnetic sequences (F/F/AF)n in 2. Fluorescence measurements indicate that 4 and 5 are promising luminescence sensors for the detection of CrO42− and Cr2O72− anions in aqueous solution. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1039/c9dt01736d
    Languages:
      – Code: eng
        Text: English
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      Pagination:
        PageCount: 15
        StartPage: 10220
    Subjects:
      – SubjectFull: Coordination polymers
        Type: general
      – SubjectFull: Carboxylates
        Type: general
      – SubjectFull: Luminescence
        Type: general
      – SubjectFull: X-ray powder diffraction
        Type: general
      – SubjectFull: Magnetic properties
        Type: general
      – SubjectFull: Aqueous solutions
        Type: general
      – SubjectFull: Complex ions
        Type: general
    Titles:
      – TitleFull: Structural diversity, magnetic property, or luminescence sensing of Co(ii) and Cd(ii) coordination polymers derived from designed 3,3′-((5-carboxy-1,3-phenylene)bis(oxy))dibenzoic acid.
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          Name:
            NameFull: Yang, Dong-Dong
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            NameFull: Lu, Li-Ping
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            NameFull: Zhu, Miao-Li
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            – D: 21
              M: 07
              Text: 7/21/2019
              Type: published
              Y: 2019
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              Value: 48
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              Value: 27
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            – TitleFull: Dalton Transactions: An International Journal of Inorganic Chemistry
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