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Synthesis, structure and magnetic properties of a series of Ln(III) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization.

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Title: Synthesis, structure and magnetic properties of a series of Ln(III) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization.
Authors: Long, Jérôme1 (AUTHOR) jerome.long@umontpellier.fr, Skvortsov, Grigorii G.2 (AUTHOR), Cherkasov, Anton V.2 (AUTHOR), Lyssenko, Konstantin A.3 (AUTHOR), Poddel'sky, Andrei I.2 (AUTHOR), Guari, Yannick1 (AUTHOR), Larionova, Joulia1 (AUTHOR), Trifonov, Alexander A.2,3 (AUTHOR) trif@iomc.ras.ru
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 8/28/2019, Vol. 48 Issue 32, p12018-12022. 5p.
Subjects: Magnetic structure, Magnetic properties, Magnetization, Magnetic anisotropy, Ligands (Chemistry), Ions, Relaxation for health
Abstract: We report the investigation of synthesis, structure and magnetic properties of a series of homoleptic Ln(III) complexes coordinated by radical-anionic iminopyridine ligands of general formula [Ln(IPy)3]·solv (IPy = iminopyridine; Ln = Tb, Dy, Er, Y, Gd). The dysprosium analogue exhibits a zero-field Single-Molecule Magnet (SMM) behavior. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 138030682
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Synthesis, structure and magnetic properties of a series of Ln(III) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization.
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  Data: We report the investigation of synthesis, structure and magnetic properties of a series of homoleptic Ln(III) complexes coordinated by radical-anionic iminopyridine ligands of general formula [Ln(IPy)3]·solv (IPy = iminopyridine; Ln = Tb, Dy, Er, Y, Gd). The dysprosium analogue exhibits a zero-field Single-Molecule Magnet (SMM) behavior. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1039/c9dt00738e
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      – SubjectFull: Magnetization
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      – SubjectFull: Ligands (Chemistry)
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      – SubjectFull: Ions
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      – SubjectFull: Relaxation for health
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              Text: 8/28/2019
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