Highly Efficient Binuclear Copper‐catalyzed Oxidation of N,N‐Dimethylanilines with O2.
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| Title: | Highly Efficient Binuclear Copper‐catalyzed Oxidation of N,N‐Dimethylanilines with O |
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| Authors: | Liu, Yuxia1 (AUTHOR) yuxialiu@nwu.edu.cn, Yan, Yonggang2 (AUTHOR), Xue, Dong2 (AUTHOR), Wang, Zhongfu1 (AUTHOR), Xiao, Jianliang2,3 (AUTHOR), Wang, Chao2 (AUTHOR) c.wang@snnu.edu.cn |
| Source: | ChemCatChem. 4/20/2020, Vol. 12 Issue 8, p2221-2225. 5p. |
| Subjects: | Oxidation, Homogeneous catalysis |
| Abstract: | A binuclear copper‐salicylate complex, [Cu(Sal)2(NCMe)]2 (Sal=salicylate), was found to be an active catalyst for the oxidation of N,N‐dimethylanilines by O2, affording the corresponding N‐methyl‐N‐phenylformamides as major products. The reactions were carried out with a O2 balloon and the S/C (substrate/catalyst ratio) of the model reaction could be up to 1×105, providing a practical and highly efficient catalytic protocol for accessing N‐methyl‐N‐phenylformamides. [ABSTRACT FROM AUTHOR] |
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| Database: | Engineering Source |
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| Abstract: | A binuclear copper‐salicylate complex, [Cu(Sal)2(NCMe)]2 (Sal=salicylate), was found to be an active catalyst for the oxidation of N,N‐dimethylanilines by O2, affording the corresponding N‐methyl‐N‐phenylformamides as major products. The reactions were carried out with a O2 balloon and the S/C (substrate/catalyst ratio) of the model reaction could be up to 1×105, providing a practical and highly efficient catalytic protocol for accessing N‐methyl‐N‐phenylformamides. [ABSTRACT FROM AUTHOR] |
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| ISSN: | 18673880 |
| DOI: | 10.1002/cctc.201901962 |
