First example of mixed azoheterocycles: structural studies of metallo-macrocycle Ag(I) versus tetrahedral Cd(II) complexes of pyridyl-azo-imidazole
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| Title: | First example of mixed azoheterocycles: structural studies of metallo-macrocycle Ag(I) versus tetrahedral Cd(II) complexes of pyridyl-azo-imidazole |
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| Authors: | Mathur, T.1, Jasimuddin, Sk.1, Milton, H.2, Woollins, J.D.2, Sinha, C.1 c_r_sinha@yahoo.com |
| Source: | Inorganica Chimica Acta. Sep2004, Vol. 357 Issue 12, p3503-3509. 7p. |
| Subjects: | Silver, Alkylation, Heterocyclic compounds, X-ray diffraction |
| Abstract: | Imidazolyl and 3′-pyridyl are linked by azo bond (–N&z.dbnd6;N–) to synthesize hitherto unknown mixed heterocyclic azo molecules, 2-[(3′-pyridyl)azo]imidazole (3′-PyaiH). Alkylation in presence of NaH has synthesized 1-alkyl-2-[(3′-pyridyl)azo]imidazole (3′-PyaiR′). 3′-PyaiR′ include three types of N-donor centers: N(imidazole), N(azo) and a peripheral N(pyridine). They bind to Ag+ to form 2:2 metallo-macrocycle, [Ag(3′-PyaiR′)] |
| Copyright of Inorganica Chimica Acta is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 14312659 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: First example of mixed azoheterocycles: structural studies of metallo-macrocycle Ag(I) versus tetrahedral Cd(II) complexes of pyridyl-azo-imidazole – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Mathur%2C+T%2E%22">Mathur, T.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Jasimuddin%2C+Sk%2E%22">Jasimuddin, Sk.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Milton%2C+H%2E%22">Milton, H.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Woollins%2C+J%2ED%2E%22">Woollins, J.D.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Sinha%2C+C%2E%22">Sinha, C.</searchLink><relatesTo>1</relatesTo><i> c_r_sinha@yahoo.com</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Inorganica+Chimica+Acta%22">Inorganica Chimica Acta</searchLink>. Sep2004, Vol. 357 Issue 12, p3503-3509. 7p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Silver%22">Silver</searchLink><br /><searchLink fieldCode="DE" term="%22Alkylation%22">Alkylation</searchLink><br /><searchLink fieldCode="DE" term="%22Heterocyclic+compounds%22">Heterocyclic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Imidazolyl and 3′-pyridyl are linked by azo bond (–N&z.dbnd6;N–) to synthesize hitherto unknown mixed heterocyclic azo molecules, 2-[(3′-pyridyl)azo]imidazole (3′-PyaiH). Alkylation in presence of NaH has synthesized 1-alkyl-2-[(3′-pyridyl)azo]imidazole (3′-PyaiR′). 3′-PyaiR′ include three types of N-donor centers: N(imidazole), N(azo) and a peripheral N(pyridine). They bind to Ag+ to form 2:2 metallo-macrocycle, [Ag(3′-PyaiR′)]<f>2</f>2+, while the reaction with Cd2+ forms Cd(3′-PyaiR′)<f>4</f>2+. The complexes are structurally characterized by X-ray diffraction studies. [Copyright &y& Elsevier] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Inorganica Chimica Acta is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.ica.2004.04.028 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 7 StartPage: 3503 Subjects: – SubjectFull: Silver Type: general – SubjectFull: Alkylation Type: general – SubjectFull: Heterocyclic compounds Type: general – SubjectFull: X-ray diffraction Type: general Titles: – TitleFull: First example of mixed azoheterocycles: structural studies of metallo-macrocycle Ag(I) versus tetrahedral Cd(II) complexes of pyridyl-azo-imidazole Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Mathur, T. – PersonEntity: Name: NameFull: Jasimuddin, Sk. – PersonEntity: Name: NameFull: Milton, H. – PersonEntity: Name: NameFull: Woollins, J.D. – PersonEntity: Name: NameFull: Sinha, C. IsPartOfRelationships: – BibEntity: Dates: – D: 10 M: 09 Text: Sep2004 Type: published Y: 2004 Identifiers: – Type: issn-print Value: 00201693 Numbering: – Type: volume Value: 357 – Type: issue Value: 12 Titles: – TitleFull: Inorganica Chimica Acta Type: main |
| ResultId | 1 |
