Carbocatalysis: From Acetylene Trimerization to Modern Organic Synthesis. A Review.
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| Title: | Carbocatalysis: From Acetylene Trimerization to Modern Organic Synthesis. A Review. |
|---|---|
| Authors: | Pentsak, E. O.1 (AUTHOR), Gordeev, E. G.1 (AUTHOR), Ananikov, V. P.1 (AUTHOR) val@ioc.ac.ru |
| Source: | Doklady Physical Chemistry. Aug2020, Vol. 493 Issue 2, p95-122. 28p. |
| Subjects: | Organic synthesis, Trimerization, Acetylene, Metal catalysts, Manufacturing processes |
| Abstract: | In recent years, the topic of catalysis by carbon materials (carbocatalysis) has experienced rapid growth. Every year the scope of application of carbocatalysts is expanding swiftly, spreading to areas in which metal catalysts seemed to have no alternative until recently. Due to their structural diversity and functionalization possibilities, carbon materials offer almost limitless possibilities for creating various catalytically active sites. It is of crucial importance to understand the mechanisms of action of chemically active sites of carbocatalysts for the development of this field. The latest discoveries have unveiled the complexity of this topic and the need to take into account the effects associated with the simultaneous presence of various active sites on the surface of carbon materials. Despite the significant advances in modern research in the field of carbocatalysis, it is important to remember the origins of the use of carbon materials in catalysis. New methods of studying old and almost forgotten reactions often lead to very interesting discoveries. This review focuses on the historical development of ideas about the catalytic activity of carbon materials, modern concepts of the mechanisms of carbocatalytic reactions, and recent studies of the role of carbene centers of graphene materials in catalytic processes. [ABSTRACT FROM AUTHOR] |
| Copyright of Doklady Physical Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Links: – Type: pdflink Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 146652115 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1134/S0012501620380017 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 28 StartPage: 95 Subjects: – SubjectFull: Organic synthesis Type: general – SubjectFull: Trimerization Type: general – SubjectFull: Acetylene Type: general – SubjectFull: Metal catalysts Type: general – SubjectFull: Manufacturing processes Type: general Titles: – TitleFull: Carbocatalysis: From Acetylene Trimerization to Modern Organic Synthesis. A Review. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Pentsak, E. O. – PersonEntity: Name: NameFull: Gordeev, E. G. – PersonEntity: Name: NameFull: Ananikov, V. P. IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 08 Text: Aug2020 Type: published Y: 2020 Identifiers: – Type: issn-print Value: 00125016 Numbering: – Type: volume Value: 493 – Type: issue Value: 2 Titles: – TitleFull: Doklady Physical Chemistry Type: main |
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