An experimental investigation into the salt-weathering susceptibility of building limestones.

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Title: An experimental investigation into the salt-weathering susceptibility of building limestones.
Authors: Scrivano, Simona1 (AUTHOR) simona.scrivano@edu.unige.it, Gaggero, Laura1 (AUTHOR)
Source: Rock Mechanics & Rock Engineering. 2020, Vol. 53 Issue 12, p5329-5343. 15p.
Subjects: Chemical weathering, Building stones, Animal droppings, Limestone, Acid rain, Saline solutions, Deoxynivalenol
Abstract: Dimension and ornamental stones used for built heritage are frequently affected, under all climates, by intense weathering induced by the transport of saline solutions. Accordingly, researchers addressed the weathering mechanisms induced by salts (primarily Na2SO4), the stresses generated in the host material, and the durability of ornamental and dimension stones. This study investigates the behaviour of four sedimentary lithotypes, differing in texture and structure (Breccia Aurora, Rosso Verona, and fine- and coarse-grained Vicenza Stone) exposed to a selection of saline solutions, aiming at evaluating their susceptibility to weathering and the influence of petrographic features on durability. The chosen Na2SO4, MgSO4, Na2CO3, NaCl, and KNO3 solutions include the anions characterizing the major saline sources affecting built heritage: capillary rise, acid rain, atmospheric particulate deposition, bird or other animal scat, and de-icing salt contamination. The petrophysical properties of unweathered and salt-weathered samples were characterized by relative mass variation estimation, capillary rise, and hygroscopic absorption-based porosimetry. Scanning Electron Microscopy coupled with microprobe allowed studying the morphological changes triggered by weathering and analysing the chemical composition of the efflorescence crust. The whole of data, consistently with literature, allowed inferring pore type and distribution as the main intrinsic parameters controlling salt weathering susceptibility. Moreover, Na2SO4 and Na2CO3 proved to be the most harmful, probably due to their ability to crystallize in different hydration stages at room temperature. The comparative analysis of the induced weathering can help to choose suitable dimension stones for new buildings or restoration replacements. [ABSTRACT FROM AUTHOR]
Copyright of Rock Mechanics & Rock Engineering is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: An experimental investigation into the salt-weathering susceptibility of building limestones.
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  Data: <searchLink fieldCode="AR" term="%22Scrivano%2C+Simona%22">Scrivano, Simona</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> simona.scrivano@edu.unige.it</i><br /><searchLink fieldCode="AR" term="%22Gaggero%2C+Laura%22">Gaggero, Laura</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="DE" term="%22Chemical+weathering%22">Chemical weathering</searchLink><br /><searchLink fieldCode="DE" term="%22Building+stones%22">Building stones</searchLink><br /><searchLink fieldCode="DE" term="%22Animal+droppings%22">Animal droppings</searchLink><br /><searchLink fieldCode="DE" term="%22Limestone%22">Limestone</searchLink><br /><searchLink fieldCode="DE" term="%22Acid+rain%22">Acid rain</searchLink><br /><searchLink fieldCode="DE" term="%22Saline+solutions%22">Saline solutions</searchLink><br /><searchLink fieldCode="DE" term="%22Deoxynivalenol%22">Deoxynivalenol</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Dimension and ornamental stones used for built heritage are frequently affected, under all climates, by intense weathering induced by the transport of saline solutions. Accordingly, researchers addressed the weathering mechanisms induced by salts (primarily Na2SO4), the stresses generated in the host material, and the durability of ornamental and dimension stones. This study investigates the behaviour of four sedimentary lithotypes, differing in texture and structure (Breccia Aurora, Rosso Verona, and fine- and coarse-grained Vicenza Stone) exposed to a selection of saline solutions, aiming at evaluating their susceptibility to weathering and the influence of petrographic features on durability. The chosen Na2SO4, MgSO4, Na2CO3, NaCl, and KNO3 solutions include the anions characterizing the major saline sources affecting built heritage: capillary rise, acid rain, atmospheric particulate deposition, bird or other animal scat, and de-icing salt contamination. The petrophysical properties of unweathered and salt-weathered samples were characterized by relative mass variation estimation, capillary rise, and hygroscopic absorption-based porosimetry. Scanning Electron Microscopy coupled with microprobe allowed studying the morphological changes triggered by weathering and analysing the chemical composition of the efflorescence crust. The whole of data, consistently with literature, allowed inferring pore type and distribution as the main intrinsic parameters controlling salt weathering susceptibility. Moreover, Na2SO4 and Na2CO3 proved to be the most harmful, probably due to their ability to crystallize in different hydration stages at room temperature. The comparative analysis of the induced weathering can help to choose suitable dimension stones for new buildings or restoration replacements. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Rock Mechanics & Rock Engineering is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1007/s00603-020-02208-x
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      – Code: eng
        Text: English
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        PageCount: 15
        StartPage: 5329
    Subjects:
      – SubjectFull: Chemical weathering
        Type: general
      – SubjectFull: Building stones
        Type: general
      – SubjectFull: Animal droppings
        Type: general
      – SubjectFull: Limestone
        Type: general
      – SubjectFull: Acid rain
        Type: general
      – SubjectFull: Saline solutions
        Type: general
      – SubjectFull: Deoxynivalenol
        Type: general
    Titles:
      – TitleFull: An experimental investigation into the salt-weathering susceptibility of building limestones.
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          Name:
            NameFull: Scrivano, Simona
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          Name:
            NameFull: Gaggero, Laura
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            – D: 01
              M: 12
              Text: 2020
              Type: published
              Y: 2020
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              Value: 53
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              Value: 12
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