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Role of Substrate in Au Nanoparticle Decoration by Electroless Deposition.

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Title: Role of Substrate in Au Nanoparticle Decoration by Electroless Deposition.
Authors: Bruno, Luca1 (AUTHOR) luca.bruno@dfa.unict.it, Urso, Mario1 (AUTHOR) francesco.priolo@ct.infn.it, Shacham-Diamand, Yosi2 (AUTHOR) YosiSh@tauex.tau.ac.il, Priolo, Francesco1 (AUTHOR) salvo.mirabella@dfa.unict.it, Mirabella, Salvo1 (AUTHOR)
Source: Nanomaterials (2079-4991). Nov2020, Vol. 10 Issue 11, p2180-2180. 1p.
Subjects: Gold nanoparticles, Electroless deposition, Rutherford backscattering spectrometry, Potassium cyanide, Surface conductivity, Metallic films, Surface enhanced Raman effect
Abstract: Decoration of nanostructures is a promising way of improving performances of nanomaterials. In particular, decoration with Au nanoparticles is considerably efficient in sensing and catalysis applications. Here, the mechanism of decoration with Au nanoparticles by means of low-cost electroless deposition (ELD) is investigated on different substrates, demonstrating largely different outcomes. ELD solution with Au potassium cyanide and sodium hypophosphite, at constant temperature (80 °C) and pH (7.5), is used to decorate by immersion metal (Ni) or semiconductor (Si, NiO) substrates, as well as NiO nanowalls. All substrates were pre-treated with a hydrazine hydrate bath. Scanning electron microscopy and Rutherford backscattering spectrometry were used to quantitatively analyze the amount, shape and size of deposited Au. Au nanoparticle decoration by ELD is greatly affected by the substrates, leading to a fast film deposition onto metallic substrate, or to a slow cluster (50–200 nm sized) formation on semiconducting substrate. Size and density of resulting Au clusters strongly depend on substrate material and morphology. Au ELD is shown to proceed through a galvanic displacement on Ni substrate, and it can be modeled with a local cell mechanism widely affected by the substrate conductivity at surface. These data are presented and discussed, allowing for cheap and reproducible Au nanoparticle decoration on several substrates. [ABSTRACT FROM AUTHOR]
Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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Items – Name: Title
  Label: Title
  Group: Ti
  Data: Role of Substrate in Au Nanoparticle Decoration by Electroless Deposition.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Bruno%2C+Luca%22">Bruno, Luca</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> luca.bruno@dfa.unict.it</i><br /><searchLink fieldCode="AR" term="%22Urso%2C+Mario%22">Urso, Mario</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> francesco.priolo@ct.infn.it</i><br /><searchLink fieldCode="AR" term="%22Shacham-Diamand%2C+Yosi%22">Shacham-Diamand, Yosi</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> YosiSh@tauex.tau.ac.il</i><br /><searchLink fieldCode="AR" term="%22Priolo%2C+Francesco%22">Priolo, Francesco</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> salvo.mirabella@dfa.unict.it</i><br /><searchLink fieldCode="AR" term="%22Mirabella%2C+Salvo%22">Mirabella, Salvo</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Nanomaterials+%282079-4991%29%22">Nanomaterials (2079-4991)</searchLink>. Nov2020, Vol. 10 Issue 11, p2180-2180. 1p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Gold+nanoparticles%22">Gold nanoparticles</searchLink><br /><searchLink fieldCode="DE" term="%22Electroless+deposition%22">Electroless deposition</searchLink><br /><searchLink fieldCode="DE" term="%22Rutherford+backscattering+spectrometry%22">Rutherford backscattering spectrometry</searchLink><br /><searchLink fieldCode="DE" term="%22Potassium+cyanide%22">Potassium cyanide</searchLink><br /><searchLink fieldCode="DE" term="%22Surface+conductivity%22">Surface conductivity</searchLink><br /><searchLink fieldCode="DE" term="%22Metallic+films%22">Metallic films</searchLink><br /><searchLink fieldCode="DE" term="%22Surface+enhanced+Raman+effect%22">Surface enhanced Raman effect</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Decoration of nanostructures is a promising way of improving performances of nanomaterials. In particular, decoration with Au nanoparticles is considerably efficient in sensing and catalysis applications. Here, the mechanism of decoration with Au nanoparticles by means of low-cost electroless deposition (ELD) is investigated on different substrates, demonstrating largely different outcomes. ELD solution with Au potassium cyanide and sodium hypophosphite, at constant temperature (80 °C) and pH (7.5), is used to decorate by immersion metal (Ni) or semiconductor (Si, NiO) substrates, as well as NiO nanowalls. All substrates were pre-treated with a hydrazine hydrate bath. Scanning electron microscopy and Rutherford backscattering spectrometry were used to quantitatively analyze the amount, shape and size of deposited Au. Au nanoparticle decoration by ELD is greatly affected by the substrates, leading to a fast film deposition onto metallic substrate, or to a slow cluster (50–200 nm sized) formation on semiconducting substrate. Size and density of resulting Au clusters strongly depend on substrate material and morphology. Au ELD is shown to proceed through a galvanic displacement on Ni substrate, and it can be modeled with a local cell mechanism widely affected by the substrate conductivity at surface. These data are presented and discussed, allowing for cheap and reproducible Au nanoparticle decoration on several substrates. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.3390/nano10112180
    Languages:
      – Code: eng
        Text: English
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        StartPage: 2180
    Subjects:
      – SubjectFull: Gold nanoparticles
        Type: general
      – SubjectFull: Electroless deposition
        Type: general
      – SubjectFull: Rutherford backscattering spectrometry
        Type: general
      – SubjectFull: Potassium cyanide
        Type: general
      – SubjectFull: Surface conductivity
        Type: general
      – SubjectFull: Metallic films
        Type: general
      – SubjectFull: Surface enhanced Raman effect
        Type: general
    Titles:
      – TitleFull: Role of Substrate in Au Nanoparticle Decoration by Electroless Deposition.
        Type: main
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          Name:
            NameFull: Bruno, Luca
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            NameFull: Urso, Mario
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            NameFull: Shacham-Diamand, Yosi
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            NameFull: Priolo, Francesco
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            NameFull: Mirabella, Salvo
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              M: 11
              Text: Nov2020
              Type: published
              Y: 2020
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