Bibliographic Details
| Title: |
Design and programmable self-assembly of an eight-coordinate Cu(II) heterometallic structure via a dipalladium corner as a building block. |
| Authors: |
Tong, Jin1 (AUTHOR) jintong@bjut.edu.cn, Lu, Hong-Lin1 (AUTHOR), Sun, Wen-Qing1 (AUTHOR), Yu, Shu-Yan1 (AUTHOR) selfassembly@bjut.edu.cn |
| Source: |
CrystEngComm. 12/21/2020, Vol. 22 Issue 47, p8166-8170. 5p. |
| Subjects: |
Right angle, Coordinates, Atoms, Design |
| Abstract: |
An eight-coordinate (8C) Cu(II) heterometallic complex, displaying a distorted dodecahedral structure with an [(O2)4] donor set, has been synthesized by programmable self-assembly. Two 4-(4-carboxylatophenyl)pyrazolate di-anions coordinate to protected-Pd(II) units forming an extended right angle metalloligand as a building block, which links a Cu(II) atom to four short Cu–O(carboxy) bonds [2.052 Å] and four long Cu–O(carboxy) bonds [2.766 Å] in an eight-coordinated environment forming a unique 8C heteromultimetallic complex. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
