View in EDS

Design and programmable self-assembly of an eight-coordinate Cu(II) heterometallic structure via a dipalladium corner as a building block.

Saved in:
Bibliographic Details
Title: Design and programmable self-assembly of an eight-coordinate Cu(II) heterometallic structure via a dipalladium corner as a building block.
Authors: Tong, Jin1 (AUTHOR) jintong@bjut.edu.cn, Lu, Hong-Lin1 (AUTHOR), Sun, Wen-Qing1 (AUTHOR), Yu, Shu-Yan1 (AUTHOR) selfassembly@bjut.edu.cn
Source: CrystEngComm. 12/21/2020, Vol. 22 Issue 47, p8166-8170. 5p.
Subjects: Right angle, Coordinates, Atoms, Design
Abstract: An eight-coordinate (8C) Cu(II) heterometallic complex, displaying a distorted dodecahedral structure with an [(O2)4] donor set, has been synthesized by programmable self-assembly. Two 4-(4-carboxylatophenyl)pyrazolate di-anions coordinate to protected-Pd(II) units forming an extended right angle metalloligand as a building block, which links a Cu(II) atom to four short Cu–O(carboxy) bonds [2.052 Å] and four long Cu–O(carboxy) bonds [2.766 Å] in an eight-coordinated environment forming a unique 8C heteromultimetallic complex. [ABSTRACT FROM AUTHOR]
Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 147600513
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Design and programmable self-assembly of an eight-coordinate Cu(II) heterometallic structure via a dipalladium corner as a building block.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Tong%2C+Jin%22">Tong, Jin</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> jintong@bjut.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Lu%2C+Hong-Lin%22">Lu, Hong-Lin</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sun%2C+Wen-Qing%22">Sun, Wen-Qing</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yu%2C+Shu-Yan%22">Yu, Shu-Yan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> selfassembly@bjut.edu.cn</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22CrystEngComm%22">CrystEngComm</searchLink>. 12/21/2020, Vol. 22 Issue 47, p8166-8170. 5p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Right+angle%22">Right angle</searchLink><br /><searchLink fieldCode="DE" term="%22Coordinates%22">Coordinates</searchLink><br /><searchLink fieldCode="DE" term="%22Atoms%22">Atoms</searchLink><br /><searchLink fieldCode="DE" term="%22Design%22">Design</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: An eight-coordinate (8C) Cu(II) heterometallic complex, displaying a distorted dodecahedral structure with an [(O2)4] donor set, has been synthesized by programmable self-assembly. Two 4-(4-carboxylatophenyl)pyrazolate di-anions coordinate to protected-Pd(II) units forming an extended right angle metalloligand as a building block, which links a Cu(II) atom to four short Cu–O(carboxy) bonds [2.052 Å] and four long Cu–O(carboxy) bonds [2.766 Å] in an eight-coordinated environment forming a unique 8C heteromultimetallic complex. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=147600513
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1039/d0ce00520g
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 5
        StartPage: 8166
    Subjects:
      – SubjectFull: Right angle
        Type: general
      – SubjectFull: Coordinates
        Type: general
      – SubjectFull: Atoms
        Type: general
      – SubjectFull: Design
        Type: general
    Titles:
      – TitleFull: Design and programmable self-assembly of an eight-coordinate Cu(II) heterometallic structure via a dipalladium corner as a building block.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Tong, Jin
      – PersonEntity:
          Name:
            NameFull: Lu, Hong-Lin
      – PersonEntity:
          Name:
            NameFull: Sun, Wen-Qing
      – PersonEntity:
          Name:
            NameFull: Yu, Shu-Yan
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 21
              M: 12
              Text: 12/21/2020
              Type: published
              Y: 2020
          Identifiers:
            – Type: issn-print
              Value: 14668033
          Numbering:
            – Type: volume
              Value: 22
            – Type: issue
              Value: 47
          Titles:
            – TitleFull: CrystEngComm
              Type: main
ResultId 1