Source and drinking water organic and total iodine and correlation with water quality parameters.

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Title: Source and drinking water organic and total iodine and correlation with water quality parameters.
Authors: Sayess, Rassil1 (AUTHOR) re232@cornell.edu, Eyring, Adam M.2 (AUTHOR), Reckhow, David A.3 (AUTHOR)
Source: Water Research. Feb2021, Vol. 190, pN.PAG-N.PAG. 1p.
Subjects: Drinking water, Water quality, Iodine, Water purification, Tobits, Disinfection by-product
Geographic Terms: Suva (Fiji)
Abstract: • The occurrence, magnitude, and seasonality of TOI and TI was established. • Measured TOI did not increase upon treatment. • DOC, SUVA, TCl 2 , and pH were all significantly correlated with TOI in treated water. • A predictive model was fit for TOI occurrence in treated water. Iodinated disinfection by-products (I-DBPs) have recently emerged as part of the pool of DBPs of public health concern. Due to limitations in measuring individual I-DBPs in a water sample, the surrogate measure of total organic iodine (TOI) is often used to account for the sum of all I-DBPs. In this study, TOI and total iodine (TI) are quantified in raw and treated waters in treatment trains at three sites in the Northeast United States. The occurrence, magnitude, and seasonality of these species was investigated within each sampling train and across the different sites. A regression model was developed to explore how TOI occurrence varies with routinely measured physical and chemical parameters in a water sample. The TOI and TI concentration at the three sites ranged from below the method detection limit to 18 µg/L and from 3 and 18.9 µg/L, respectively. There was substantial inter-monthly variability in TOI without a clear seasonal signal, and the concentration of TOI did not increase upon treatment. The results of the multivariate regression model showed that dissolved organic carbon (DOC), specific UV 254 absorbance (SUVA), combined chlorine residual (TCl 2), and pH were all significantly related to TOI concentration to varying degrees. A Tobit model was fit to show TOI predictions against observed (measured) TOI values. The model could explain approximately 46% of the variance of TOI concentrations in the treated waters. Image, graphical abstract [ABSTRACT FROM AUTHOR]
Copyright of Water Research is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Source and drinking water organic and total iodine and correlation with water quality parameters.
– Name: Author
  Label: Authors
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  Data: <searchLink fieldCode="AR" term="%22Sayess%2C+Rassil%22">Sayess, Rassil</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> re232@cornell.edu</i><br /><searchLink fieldCode="AR" term="%22Eyring%2C+Adam+M%2E%22">Eyring, Adam M.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Reckhow%2C+David+A%2E%22">Reckhow, David A.</searchLink><relatesTo>3</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Water+Research%22">Water Research</searchLink>. Feb2021, Vol. 190, pN.PAG-N.PAG. 1p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Drinking+water%22">Drinking water</searchLink><br /><searchLink fieldCode="DE" term="%22Water+quality%22">Water quality</searchLink><br /><searchLink fieldCode="DE" term="%22Iodine%22">Iodine</searchLink><br /><searchLink fieldCode="DE" term="%22Water+purification%22">Water purification</searchLink><br /><searchLink fieldCode="DE" term="%22Tobits%22">Tobits</searchLink><br /><searchLink fieldCode="DE" term="%22Disinfection+by-product%22">Disinfection by-product</searchLink>
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  Label: Geographic Terms
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  Data: <searchLink fieldCode="DE" term="%22Suva+%28Fiji%29%22">Suva (Fiji)</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: • The occurrence, magnitude, and seasonality of TOI and TI was established. • Measured TOI did not increase upon treatment. • DOC, SUVA, TCl 2 , and pH were all significantly correlated with TOI in treated water. • A predictive model was fit for TOI occurrence in treated water. Iodinated disinfection by-products (I-DBPs) have recently emerged as part of the pool of DBPs of public health concern. Due to limitations in measuring individual I-DBPs in a water sample, the surrogate measure of total organic iodine (TOI) is often used to account for the sum of all I-DBPs. In this study, TOI and total iodine (TI) are quantified in raw and treated waters in treatment trains at three sites in the Northeast United States. The occurrence, magnitude, and seasonality of these species was investigated within each sampling train and across the different sites. A regression model was developed to explore how TOI occurrence varies with routinely measured physical and chemical parameters in a water sample. The TOI and TI concentration at the three sites ranged from below the method detection limit to 18 µg/L and from 3 and 18.9 µg/L, respectively. There was substantial inter-monthly variability in TOI without a clear seasonal signal, and the concentration of TOI did not increase upon treatment. The results of the multivariate regression model showed that dissolved organic carbon (DOC), specific UV 254 absorbance (SUVA), combined chlorine residual (TCl 2), and pH were all significantly related to TOI concentration to varying degrees. A Tobit model was fit to show TOI predictions against observed (measured) TOI values. The model could explain approximately 46% of the variance of TOI concentrations in the treated waters. Image, graphical abstract [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Water Research is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.watres.2020.116686
    Languages:
      – Code: eng
        Text: English
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      Pagination:
        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Drinking water
        Type: general
      – SubjectFull: Water quality
        Type: general
      – SubjectFull: Iodine
        Type: general
      – SubjectFull: Water purification
        Type: general
      – SubjectFull: Tobits
        Type: general
      – SubjectFull: Disinfection by-product
        Type: general
      – SubjectFull: Suva (Fiji)
        Type: general
    Titles:
      – TitleFull: Source and drinking water organic and total iodine and correlation with water quality parameters.
        Type: main
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          Name:
            NameFull: Sayess, Rassil
      – PersonEntity:
          Name:
            NameFull: Eyring, Adam M.
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            NameFull: Reckhow, David A.
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            – D: 15
              M: 02
              Text: Feb2021
              Type: published
              Y: 2021
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              Value: 00431354
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              Value: 190
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            – TitleFull: Water Research
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