Preparation of activated porous glass adsorbent through thermochemical reforming of ampoules and eggshells for remediation of direct blue dye pollution.

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Title: Preparation of activated porous glass adsorbent through thermochemical reforming of ampoules and eggshells for remediation of direct blue dye pollution.
Authors: Hussain, Zahid1 (AUTHOR), Zada, Amir1 (AUTHOR), Hussain, Khadim2 (AUTHOR), Naz, Muhammad Y.3 (AUTHOR) yasin603@yahoo.com, AbdEl‐Salam, Nasser M.4 (AUTHOR), Ibrahim, Khalid A.5 (AUTHOR)
Source: Asia-Pacific Journal of Chemical Engineering. Mar2021, Vol. 16 Issue 2, p1-11. 11p.
Subjects: Glass-ceramics, Eggshells, Porous materials, Char, Glass, Glass bottles, Deionization of water, Activated carbon
Abstract: The recycling of chemical containing glass bottles is generally not recommended due to high health risk. In this study, used glass ampoules were devitrified into a porous material by coprocessing with eggshells, salt, and soda at different temperatures. In this thermochemical reaction, eggshells decomposed into calcium, porogenic gases, and char. The calcium worked as a flux in the reaction while char and gases promoted the porosity of the devitrified glass. The thermochemically processed glass was treated with deionized water to clear the water‐soluble fractions and to improve the surface porosity. The final product was characterized for its chemical composition, functional groups, surface morphology, and pore sizes. The porous product revealed the pore volume of.010 cc/g, surface area of 32.0399 m2/g and pore radius of 1.522 nm. The well‐known Freundlich and Longmuir models were used to investigate the adsorption of blue dye onto the prepared porous glass adsorbent. The adsorbed amount of dye was found influenced by the contact time, adsorbent dose, pH of solution, and dye concentration. The porous glass adsorbed about 2.788 mg/g of dye at pH 2, which decreased to 1.938 mg/g at pH 7. The dye adsorption data followed the best fit for Freundlich model as compared to the Longmuir model. [ABSTRACT FROM AUTHOR]
Copyright of Asia-Pacific Journal of Chemical Engineering is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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Items – Name: Title
  Label: Title
  Group: Ti
  Data: Preparation of activated porous glass adsorbent through thermochemical reforming of ampoules and eggshells for remediation of direct blue dye pollution.
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  Data: <searchLink fieldCode="AR" term="%22Hussain%2C+Zahid%22">Hussain, Zahid</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zada%2C+Amir%22">Zada, Amir</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hussain%2C+Khadim%22">Hussain, Khadim</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Naz%2C+Muhammad+Y%2E%22">Naz, Muhammad Y.</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> yasin603@yahoo.com</i><br /><searchLink fieldCode="AR" term="%22AbdEl‐Salam%2C+Nasser+M%2E%22">AbdEl‐Salam, Nasser M.</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ibrahim%2C+Khalid+A%2E%22">Ibrahim, Khalid A.</searchLink><relatesTo>5</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Asia-Pacific+Journal+of+Chemical+Engineering%22">Asia-Pacific Journal of Chemical Engineering</searchLink>. Mar2021, Vol. 16 Issue 2, p1-11. 11p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Glass-ceramics%22">Glass-ceramics</searchLink><br /><searchLink fieldCode="DE" term="%22Eggshells%22">Eggshells</searchLink><br /><searchLink fieldCode="DE" term="%22Porous+materials%22">Porous materials</searchLink><br /><searchLink fieldCode="DE" term="%22Char%22">Char</searchLink><br /><searchLink fieldCode="DE" term="%22Glass%22">Glass</searchLink><br /><searchLink fieldCode="DE" term="%22Glass+bottles%22">Glass bottles</searchLink><br /><searchLink fieldCode="DE" term="%22Deionization+of+water%22">Deionization of water</searchLink><br /><searchLink fieldCode="DE" term="%22Activated+carbon%22">Activated carbon</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The recycling of chemical containing glass bottles is generally not recommended due to high health risk. In this study, used glass ampoules were devitrified into a porous material by coprocessing with eggshells, salt, and soda at different temperatures. In this thermochemical reaction, eggshells decomposed into calcium, porogenic gases, and char. The calcium worked as a flux in the reaction while char and gases promoted the porosity of the devitrified glass. The thermochemically processed glass was treated with deionized water to clear the water‐soluble fractions and to improve the surface porosity. The final product was characterized for its chemical composition, functional groups, surface morphology, and pore sizes. The porous product revealed the pore volume of.010 cc/g, surface area of 32.0399 m2/g and pore radius of 1.522 nm. The well‐known Freundlich and Longmuir models were used to investigate the adsorption of blue dye onto the prepared porous glass adsorbent. The adsorbed amount of dye was found influenced by the contact time, adsorbent dose, pH of solution, and dye concentration. The porous glass adsorbed about 2.788 mg/g of dye at pH 2, which decreased to 1.938 mg/g at pH 7. The dye adsorption data followed the best fit for Freundlich model as compared to the Longmuir model. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Asia-Pacific Journal of Chemical Engineering is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1002/apj.2610
    Languages:
      – Code: eng
        Text: English
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      Pagination:
        PageCount: 11
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    Subjects:
      – SubjectFull: Glass-ceramics
        Type: general
      – SubjectFull: Eggshells
        Type: general
      – SubjectFull: Porous materials
        Type: general
      – SubjectFull: Char
        Type: general
      – SubjectFull: Glass
        Type: general
      – SubjectFull: Glass bottles
        Type: general
      – SubjectFull: Deionization of water
        Type: general
      – SubjectFull: Activated carbon
        Type: general
    Titles:
      – TitleFull: Preparation of activated porous glass adsorbent through thermochemical reforming of ampoules and eggshells for remediation of direct blue dye pollution.
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          Name:
            NameFull: Hussain, Zahid
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            NameFull: Zada, Amir
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            NameFull: Hussain, Khadim
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            NameFull: Naz, Muhammad Y.
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            NameFull: AbdEl‐Salam, Nasser M.
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            NameFull: Ibrahim, Khalid A.
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            – D: 01
              M: 03
              Text: Mar2021
              Type: published
              Y: 2021
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              Value: 19322135
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              Value: 16
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            – TitleFull: Asia-Pacific Journal of Chemical Engineering
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