A new porous Co(II)-metal–organic framework for high sorption selectivity and affinity to CO2 and efficient catalytic oxidation of benzyl alcohols to benzaldehydes.
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| Title: | A new porous Co(II)-metal–organic framework for high sorption selectivity and affinity to CO |
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| Authors: | Wu, Yun-Long1,2 (AUTHOR) 20180717@xpu.edu.cn, Yang, Rong-Rong1 (AUTHOR), Yang, Guo-Ping2 (AUTHOR), Yan, Yang-Tian1 (AUTHOR), Su, Xiao-Lei1 (AUTHOR), He, Xin-Hai1 (AUTHOR), Song, Yan-Yan1 (AUTHOR), Ma, Zheng-Sheng2 (AUTHOR), Wang, Yao-Yu2 (AUTHOR) |
| Source: | CrystEngComm. 5/28/2021, Vol. 23 Issue 20, p3717-3723. 7p. |
| Subjects: | Benzaldehyde, Benzyl alcohol, Alcohol oxidation, Catalytic oxidation, Sorption, Metal-organic frameworks, Proline |
| Abstract: | Herein, we report a new 3D porous Co(II)-based metal–organic framework catalyst (Me2NH2)2[Co3(L)2(H2O)2]·2DMF (MOF I), which has been successfully prepared by using Co(II) ions and rigid V-shaped 3,5-di(2,4-dicarboxylphenyl)pyridine (H4L) via the solvothermal reaction. Structural analysis reveals that I displays a porous structure with the pore size of 16.2 × 7.2 Å2 based on the trinuclear [Co3(COO)4(H2O)2N2] secondary building units (SBUs). Gas sorption experiments on the guest free sample I′ reveals a high capacity and selectivity to CO2 over CH4. And further, the catalytic explorations of the I′-catalyzed system (I′: 3 mol%; proline: 40 mol%; CH3CN: 2 mL) reveal that benzyl alcohols with different structures can be efficiently transformed into benzyl alcohols without by-products under mild conditions. [ABSTRACT FROM AUTHOR] |
| Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 150465000 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: A new porous Co(II)-metal–organic framework for high sorption selectivity and affinity to CO<subscript>2</subscript> and efficient catalytic oxidation of benzyl alcohols to benzaldehydes. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Wu%2C+Yun-Long%22">Wu, Yun-Long</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> 20180717@xpu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Yang%2C+Rong-Rong%22">Yang, Rong-Rong</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yang%2C+Guo-Ping%22">Yang, Guo-Ping</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yan%2C+Yang-Tian%22">Yan, Yang-Tian</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Su%2C+Xiao-Lei%22">Su, Xiao-Lei</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22He%2C+Xin-Hai%22">He, Xin-Hai</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Song%2C+Yan-Yan%22">Song, Yan-Yan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ma%2C+Zheng-Sheng%22">Ma, Zheng-Sheng</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Yao-Yu%22">Wang, Yao-Yu</searchLink><relatesTo>2</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22CrystEngComm%22">CrystEngComm</searchLink>. 5/28/2021, Vol. 23 Issue 20, p3717-3723. 7p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Benzaldehyde%22">Benzaldehyde</searchLink><br /><searchLink fieldCode="DE" term="%22Benzyl+alcohol%22">Benzyl alcohol</searchLink><br /><searchLink fieldCode="DE" term="%22Alcohol+oxidation%22">Alcohol oxidation</searchLink><br /><searchLink fieldCode="DE" term="%22Catalytic+oxidation%22">Catalytic oxidation</searchLink><br /><searchLink fieldCode="DE" term="%22Sorption%22">Sorption</searchLink><br /><searchLink fieldCode="DE" term="%22Metal-organic+frameworks%22">Metal-organic frameworks</searchLink><br /><searchLink fieldCode="DE" term="%22Proline%22">Proline</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Herein, we report a new 3D porous Co(II)-based metal–organic framework catalyst (Me2NH2)2[Co3(L)2(H2O)2]·2DMF (MOF I), which has been successfully prepared by using Co(II) ions and rigid V-shaped 3,5-di(2,4-dicarboxylphenyl)pyridine (H4L) via the solvothermal reaction. Structural analysis reveals that I displays a porous structure with the pore size of 16.2 × 7.2 Å2 based on the trinuclear [Co3(COO)4(H2O)2N2] secondary building units (SBUs). Gas sorption experiments on the guest free sample I′ reveals a high capacity and selectivity to CO2 over CH4. And further, the catalytic explorations of the I′-catalyzed system (I′: 3 mol%; proline: 40 mol%; CH3CN: 2 mL) reveal that benzyl alcohols with different structures can be efficiently transformed into benzyl alcohols without by-products under mild conditions. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1039/d1ce00250c Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 7 StartPage: 3717 Subjects: – SubjectFull: Benzaldehyde Type: general – SubjectFull: Benzyl alcohol Type: general – SubjectFull: Alcohol oxidation Type: general – SubjectFull: Catalytic oxidation Type: general – SubjectFull: Sorption Type: general – SubjectFull: Metal-organic frameworks Type: general – SubjectFull: Proline Type: general Titles: – TitleFull: A new porous Co(II)-metal–organic framework for high sorption selectivity and affinity to CO2 and efficient catalytic oxidation of benzyl alcohols to benzaldehydes. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Wu, Yun-Long – PersonEntity: Name: NameFull: Yang, Rong-Rong – PersonEntity: Name: NameFull: Yang, Guo-Ping – PersonEntity: Name: NameFull: Yan, Yang-Tian – PersonEntity: Name: NameFull: Su, Xiao-Lei – PersonEntity: Name: NameFull: He, Xin-Hai – PersonEntity: Name: NameFull: Song, Yan-Yan – PersonEntity: Name: NameFull: Ma, Zheng-Sheng – PersonEntity: Name: NameFull: Wang, Yao-Yu IsPartOfRelationships: – BibEntity: Dates: – D: 28 M: 05 Text: 5/28/2021 Type: published Y: 2021 Identifiers: – Type: issn-print Value: 14668033 Numbering: – Type: volume Value: 23 – Type: issue Value: 20 Titles: – TitleFull: CrystEngComm Type: main |
| ResultId | 1 |
