Development of Al-5%Zn-0.5%Sn-2.6%Mg Alloy as Sacrificial Anode for Cathodic Protection of Steel in 3 wt.% NaCl Solution.

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Title: Development of Al-5%Zn-0.5%Sn-2.6%Mg Alloy as Sacrificial Anode for Cathodic Protection of Steel in 3 wt.% NaCl Solution.
Authors: Oulmas, Cilya1,2, Mameri, Sonia1, Boughrara, Dalila1 d_boughrara@yahoo.fr, Boutarfaia, Slimane3, Delhalle, Joseph2, Mekhalif, Zineb2, Kadri, Abdelaziz1
Source: Journal of The Electrochemical Society. Mar2021, Vol. 168 Issue 3, p1-18. 18p.
Subjects: Cathodic protection, Energy dispersive X-ray spectroscopy, Salt, X-ray photoelectron spectroscopy, Mild steel, Copper corrosion, Aluminum alloys, Anodes
Abstract: In this work, two aluminum alloys, Al-5Zn-0.5Sn and Al-5Zn-0.5Sn-2.6Mg, were prepared by melting in an induction furnace to be used as sacrificial anodes for cathodic protection of marine structures. The alloys are characterized by scanning electron microscopy mapping coupled to energy dispersive X-ray analysis, X-ray photoelectron spectroscopy and X-ray diffraction. Afterwards, the corrosion behavior was studied in 3 wt.% NaCl solution through immersion tests, potentiodynamic polarization, electrochemical impedance spectroscopy and weight-loss measurements. Results display that active dissolution of Al-5%Zn-0.5%Sn-2.6%Mg alloy and its quasi-uniform corrosion is associated with the major precipitates MgZn2 and Mg2Sn particles formed during the melting process. Galvanic coupling measurements over 45 d were carried out on both alloys. The sacrificial cathodic protection of both anodes was successful but the couple efficiency was greater for Al-Zn-Sn-Mg owing to its more negative corrosion potential and uniform dissolution. [ABSTRACT FROM AUTHOR]
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  Data: In this work, two aluminum alloys, Al-5Zn-0.5Sn and Al-5Zn-0.5Sn-2.6Mg, were prepared by melting in an induction furnace to be used as sacrificial anodes for cathodic protection of marine structures. The alloys are characterized by scanning electron microscopy mapping coupled to energy dispersive X-ray analysis, X-ray photoelectron spectroscopy and X-ray diffraction. Afterwards, the corrosion behavior was studied in 3 wt.% NaCl solution through immersion tests, potentiodynamic polarization, electrochemical impedance spectroscopy and weight-loss measurements. Results display that active dissolution of Al-5%Zn-0.5%Sn-2.6%Mg alloy and its quasi-uniform corrosion is associated with the major precipitates MgZn2 and Mg2Sn particles formed during the melting process. Galvanic coupling measurements over 45 d were carried out on both alloys. The sacrificial cathodic protection of both anodes was successful but the couple efficiency was greater for Al-Zn-Sn-Mg owing to its more negative corrosion potential and uniform dissolution. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Journal of The Electrochemical Society is the property of IOP Publishing and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1149/1945-7111/abec96
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      – Code: eng
        Text: English
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        PageCount: 18
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      – SubjectFull: Cathodic protection
        Type: general
      – SubjectFull: Energy dispersive X-ray spectroscopy
        Type: general
      – SubjectFull: Salt
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      – SubjectFull: X-ray photoelectron spectroscopy
        Type: general
      – SubjectFull: Mild steel
        Type: general
      – SubjectFull: Copper corrosion
        Type: general
      – SubjectFull: Aluminum alloys
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      – SubjectFull: Anodes
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      – TitleFull: Development of Al-5%Zn-0.5%Sn-2.6%Mg Alloy as Sacrificial Anode for Cathodic Protection of Steel in 3 wt.% NaCl Solution.
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              M: 03
              Text: Mar2021
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              Y: 2021
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