Study on the ionic conductivity, dielectric, and optical properties of CsYP2O7compound.

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Title: Study on the ionic conductivity, dielectric, and optical properties of CsYP2O7compound.
Authors: Karray, M.1 (AUTHOR) mayssakarray@gmail.com, Ouesleti, A.1 (AUTHOR), Khirouni, K.2 (AUTHOR), Gargouri, M.1 (AUTHOR)
Source: Journal of Materials Science: Materials in Electronics. Aug2021, Vol. 32 Issue 16, p21553-21567. 15p.
Subjects: Ionic conductivity, Optical properties, Optical conductivity, Scanning electron microscopes, Dielectrics, Ultraviolet-visible spectroscopy
Abstract: The CsYP2O7 compound was synthesized by the classical "solid-state" reaction. The phase identification of the obtained samples was performed by X-ray diffraction proving their crystallization in the monoclinic structure with the P21/c space group. Its morphology and the particle size were evaluated by scanning electron microscope (SEM). The impedance spectroscopy technique was used in order to understand the evolution of the electrical behavior and the relaxation process in this material. Accordingly, the experimental data of the Nyquist were fitted to the equivalent circuit created by a series combination of two cells. As a matter of fact, the DC conductivity exhibits a semiconductor behavior. The AC conductivity obeys the Jonscher's law. The close values, of activation energies, obtained from the dc-conductivity and hopping frequencies, prove that the transport of the charge carrier happens through an ion hopping mechanism, influenced by the motion of the Cs+ cations within the structure of CsYP2O7. The electrical modulus confirms the existence of non-Debye type relaxation behavior. The optical properties of UV–visible spectroscopy for our sample showed that the gap value is equal to 3.7 eV. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Materials Science: Materials in Electronics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Study on the ionic conductivity, dielectric, and optical properties of CsYP<subscript>2</subscript>O<subscript>7</subscript>compound.
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Materials+Science%3A+Materials+in+Electronics%22">Journal of Materials Science: Materials in Electronics</searchLink>. Aug2021, Vol. 32 Issue 16, p21553-21567. 15p.
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  Data: <searchLink fieldCode="DE" term="%22Ionic+conductivity%22">Ionic conductivity</searchLink><br /><searchLink fieldCode="DE" term="%22Optical+properties%22">Optical properties</searchLink><br /><searchLink fieldCode="DE" term="%22Optical+conductivity%22">Optical conductivity</searchLink><br /><searchLink fieldCode="DE" term="%22Scanning+electron+microscopes%22">Scanning electron microscopes</searchLink><br /><searchLink fieldCode="DE" term="%22Dielectrics%22">Dielectrics</searchLink><br /><searchLink fieldCode="DE" term="%22Ultraviolet-visible+spectroscopy%22">Ultraviolet-visible spectroscopy</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: The CsYP2O7 compound was synthesized by the classical "solid-state" reaction. The phase identification of the obtained samples was performed by X-ray diffraction proving their crystallization in the monoclinic structure with the P21/c space group. Its morphology and the particle size were evaluated by scanning electron microscope (SEM). The impedance spectroscopy technique was used in order to understand the evolution of the electrical behavior and the relaxation process in this material. Accordingly, the experimental data of the Nyquist were fitted to the equivalent circuit created by a series combination of two cells. As a matter of fact, the DC conductivity exhibits a semiconductor behavior. The AC conductivity obeys the Jonscher's law. The close values, of activation energies, obtained from the dc-conductivity and hopping frequencies, prove that the transport of the charge carrier happens through an ion hopping mechanism, influenced by the motion of the Cs+ cations within the structure of CsYP2O7. The electrical modulus confirms the existence of non-Debye type relaxation behavior. The optical properties of UV–visible spectroscopy for our sample showed that the gap value is equal to 3.7 eV. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Materials Science: Materials in Electronics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1007/s10854-021-06663-2
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      – Code: eng
        Text: English
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        PageCount: 15
        StartPage: 21553
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      – SubjectFull: Ionic conductivity
        Type: general
      – SubjectFull: Optical properties
        Type: general
      – SubjectFull: Optical conductivity
        Type: general
      – SubjectFull: Scanning electron microscopes
        Type: general
      – SubjectFull: Dielectrics
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      – SubjectFull: Ultraviolet-visible spectroscopy
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      – TitleFull: Study on the ionic conductivity, dielectric, and optical properties of CsYP2O7compound.
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            NameFull: Karray, M.
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            NameFull: Ouesleti, A.
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            NameFull: Khirouni, K.
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              Text: Aug2021
              Type: published
              Y: 2021
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