Role of Humic Organic Compounds in Controlling Equilibrium Speciation of Elements in Lakes in the Kola Peninsula: Experimental and Computation Results.

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Title: Role of Humic Organic Compounds in Controlling Equilibrium Speciation of Elements in Lakes in the Kola Peninsula: Experimental and Computation Results.
Authors: Dinu, M. I.1 (AUTHOR) marinadinu999@gmail.com, Baranov, D. Yu.1 (AUTHOR)
Source: Geochemistry International. Jan2022, Vol. 60 Issue 1, p67-77. 11p.
Subjects: Organic compounds, Thermodynamic control, Fulvic acids, Sulfuric acid, Mines & mineral resources, Trace elements
Geographic Terms: Kola Peninsula (Russia)
Abstract: The paper discusses variations in the migration activities of elements in parent rocks of soils under the effect of anthropogenic and geochemical factors. The unique geological characteristics and the diverse mineral resources of the study area predetermined the high susceptibility of water bodies in the Kola Peninsula to influences of parent soil-forming rocks at watersheds and to anthropogenic impacts. Selected typical alkaline and acid rocks of the area were used in static and dynamic experiments on leaching elements from these rocks. The extracting agents were doubly distilled water, sulfuric acid, solutions of fulvic acids, and solutions of fulvic acids after their degradation by sulfuric acid. The results show differences in the extraction of trace elements from rocks by the various extraction agents: the water extracts are characterized by the maximum recovery of some elements in experiments with alkaline rocks (the extraction Ni and Cu was four- and threefold greater than in the other experiments), and extracts by sulfuric acids from acid rocks resulted in higher concentrations of U (twofold) and Cu (less than one order of magnitude). Fulvic acids most strongly affect all of the studied rocks. According to data of discriminant analysis, the greatest contributions (with a coefficient close to 10) to the discrimination is made by the following parameters: trace elements of the La group, heavy-metal ions (Ni, Cu, and Pb), and pH. [ABSTRACT FROM AUTHOR]
Copyright of Geochemistry International is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Role of Humic Organic Compounds in Controlling Equilibrium Speciation of Elements in Lakes in the Kola Peninsula: Experimental and Computation Results.
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  Data: <searchLink fieldCode="JN" term="%22Geochemistry+International%22">Geochemistry International</searchLink>. Jan2022, Vol. 60 Issue 1, p67-77. 11p.
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  Data: <searchLink fieldCode="DE" term="%22Organic+compounds%22">Organic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Thermodynamic+control%22">Thermodynamic control</searchLink><br /><searchLink fieldCode="DE" term="%22Fulvic+acids%22">Fulvic acids</searchLink><br /><searchLink fieldCode="DE" term="%22Sulfuric+acid%22">Sulfuric acid</searchLink><br /><searchLink fieldCode="DE" term="%22Mines+%26+mineral+resources%22">Mines & mineral resources</searchLink><br /><searchLink fieldCode="DE" term="%22Trace+elements%22">Trace elements</searchLink>
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  Data: <searchLink fieldCode="DE" term="%22Kola+Peninsula+%28Russia%29%22">Kola Peninsula (Russia)</searchLink>
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  Label: Abstract
  Group: Ab
  Data: The paper discusses variations in the migration activities of elements in parent rocks of soils under the effect of anthropogenic and geochemical factors. The unique geological characteristics and the diverse mineral resources of the study area predetermined the high susceptibility of water bodies in the Kola Peninsula to influences of parent soil-forming rocks at watersheds and to anthropogenic impacts. Selected typical alkaline and acid rocks of the area were used in static and dynamic experiments on leaching elements from these rocks. The extracting agents were doubly distilled water, sulfuric acid, solutions of fulvic acids, and solutions of fulvic acids after their degradation by sulfuric acid. The results show differences in the extraction of trace elements from rocks by the various extraction agents: the water extracts are characterized by the maximum recovery of some elements in experiments with alkaline rocks (the extraction Ni and Cu was four- and threefold greater than in the other experiments), and extracts by sulfuric acids from acid rocks resulted in higher concentrations of U (twofold) and Cu (less than one order of magnitude). Fulvic acids most strongly affect all of the studied rocks. According to data of discriminant analysis, the greatest contributions (with a coefficient close to 10) to the discrimination is made by the following parameters: trace elements of the La group, heavy-metal ions (Ni, Cu, and Pb), and pH. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Geochemistry International is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1134/S0016702922010050
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      – Code: eng
        Text: English
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      – SubjectFull: Organic compounds
        Type: general
      – SubjectFull: Thermodynamic control
        Type: general
      – SubjectFull: Fulvic acids
        Type: general
      – SubjectFull: Sulfuric acid
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      – SubjectFull: Mines & mineral resources
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      – SubjectFull: Trace elements
        Type: general
      – SubjectFull: Kola Peninsula (Russia)
        Type: general
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      – TitleFull: Role of Humic Organic Compounds in Controlling Equilibrium Speciation of Elements in Lakes in the Kola Peninsula: Experimental and Computation Results.
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              Text: Jan2022
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