Laminar flame speed correlations of ammonia/hydrogen mixtures at high pressure and temperature for combustion modeling applications.

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Title: Laminar flame speed correlations of ammonia/hydrogen mixtures at high pressure and temperature for combustion modeling applications.
Authors: Pessina, V.1 (AUTHOR) valentina.pessina@unimore.it, Berni, F.1 (AUTHOR), Fontanesi, S.1 (AUTHOR), Stagni, A.2 (AUTHOR), Mehl, M.2 (AUTHOR)
Source: International Journal of Hydrogen Energy. Jul2022, Vol. 47 Issue 61, p25780-25794. 15p.
Subjects: Hydrogen flames, Flame, High temperatures, Combustion, Chemical kinetics, Burning velocity, Ammonia
Abstract: Ammonia/hydrogen mixtures are among the most promising solutions to decarbonize the transportation and energy sector. The implementation of these alternative energy carriers in practical systems requires developing suitable numerical tools, able to estimate their burning velocities as a function of both thermodynamic conditions and mixture quality. In this study, laminar flame speed correlations for ammonia/hydrogen/air mixtures are provided for high pressures (40 bar–130 bar) and elevated temperatures (720 K–1200 K), and equivalence ratios ranging from 0.4 to 1.5. Based on an extensive dataset of chemical kinetics simulations for ammonia/hydrogen blends (0-20-40-60-80-90-100 mol% of hydrogen), dedicated correlations are derived using a regression fitting. Besides these blend-specific correlations, a generalized (i.e., hydrogen-content adaptive) formulation, with hydrogen content used as additional parameter, is proposed and compared to the dedicated correlations. • Ammonia/air mixtures with increasing hydrogen content for wide range of conditions. • Chemical kinetics simulations are performed at high pressures and temperatures. • Blend-specific correlations are developed for combustion CFD codes. • A generalized and hydrogen-content adaptive correlation is derived. • Limited prediction error and satisfying comparison with state-of-art is achieved. [ABSTRACT FROM AUTHOR]
Copyright of International Journal of Hydrogen Energy is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 158389883
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Items – Name: Title
  Label: Title
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  Data: Laminar flame speed correlations of ammonia/hydrogen mixtures at high pressure and temperature for combustion modeling applications.
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  Data: <searchLink fieldCode="AR" term="%22Pessina%2C+V%2E%22">Pessina, V.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> valentina.pessina@unimore.it</i><br /><searchLink fieldCode="AR" term="%22Berni%2C+F%2E%22">Berni, F.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Fontanesi%2C+S%2E%22">Fontanesi, S.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Stagni%2C+A%2E%22">Stagni, A.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Mehl%2C+M%2E%22">Mehl, M.</searchLink><relatesTo>2</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22International+Journal+of+Hydrogen+Energy%22">International Journal of Hydrogen Energy</searchLink>. Jul2022, Vol. 47 Issue 61, p25780-25794. 15p.
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  Data: <searchLink fieldCode="DE" term="%22Hydrogen+flames%22">Hydrogen flames</searchLink><br /><searchLink fieldCode="DE" term="%22Flame%22">Flame</searchLink><br /><searchLink fieldCode="DE" term="%22High+temperatures%22">High temperatures</searchLink><br /><searchLink fieldCode="DE" term="%22Combustion%22">Combustion</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+kinetics%22">Chemical kinetics</searchLink><br /><searchLink fieldCode="DE" term="%22Burning+velocity%22">Burning velocity</searchLink><br /><searchLink fieldCode="DE" term="%22Ammonia%22">Ammonia</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Ammonia/hydrogen mixtures are among the most promising solutions to decarbonize the transportation and energy sector. The implementation of these alternative energy carriers in practical systems requires developing suitable numerical tools, able to estimate their burning velocities as a function of both thermodynamic conditions and mixture quality. In this study, laminar flame speed correlations for ammonia/hydrogen/air mixtures are provided for high pressures (40 bar–130 bar) and elevated temperatures (720 K–1200 K), and equivalence ratios ranging from 0.4 to 1.5. Based on an extensive dataset of chemical kinetics simulations for ammonia/hydrogen blends (0-20-40-60-80-90-100 mol% of hydrogen), dedicated correlations are derived using a regression fitting. Besides these blend-specific correlations, a generalized (i.e., hydrogen-content adaptive) formulation, with hydrogen content used as additional parameter, is proposed and compared to the dedicated correlations. • Ammonia/air mixtures with increasing hydrogen content for wide range of conditions. • Chemical kinetics simulations are performed at high pressures and temperatures. • Blend-specific correlations are developed for combustion CFD codes. • A generalized and hydrogen-content adaptive correlation is derived. • Limited prediction error and satisfying comparison with state-of-art is achieved. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of International Journal of Hydrogen Energy is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.ijhydene.2022.06.007
    Languages:
      – Code: eng
        Text: English
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        PageCount: 15
        StartPage: 25780
    Subjects:
      – SubjectFull: Hydrogen flames
        Type: general
      – SubjectFull: Flame
        Type: general
      – SubjectFull: High temperatures
        Type: general
      – SubjectFull: Combustion
        Type: general
      – SubjectFull: Chemical kinetics
        Type: general
      – SubjectFull: Burning velocity
        Type: general
      – SubjectFull: Ammonia
        Type: general
    Titles:
      – TitleFull: Laminar flame speed correlations of ammonia/hydrogen mixtures at high pressure and temperature for combustion modeling applications.
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            NameFull: Pessina, V.
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            NameFull: Berni, F.
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            NameFull: Fontanesi, S.
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            NameFull: Stagni, A.
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            – D: 19
              M: 07
              Text: Jul2022
              Type: published
              Y: 2022
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