Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2.
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| Title: | Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO |
|---|---|
| Authors: | Martinez Quiñonez, Henry1 (AUTHOR) henry.martinez1@correo.uis.edu.co, Amaya, Álvaro A.2 (AUTHOR), Paez-Mozo, Edgar A.1 (AUTHOR), Martinez Ortega, Fernando1 (AUTHOR) fmartine@uis.edu.co |
| Source: | Topics in Catalysis. Aug2022, Vol. 65 Issue 9-12, p1088-1101. 14p. |
| Subjects: | Nanotubes, Monoterpenes, Pinene, Ultraviolet radiation, Elemental analysis, Alkenes |
| Abstract: | Selective Oxygen Atom Transfer to α-pinene, β-pinene, (R)-limonene and camphene by dioxo-Mo(VI)Ln complex {Ln = 2-aminothiazole-4-carboxylic acid} anchored on TiO2 nanotubes (TiO2-NT) using O2 as oxidant and UV light was studied at ambient conditions. The Catalytic system was characterized by FTIR, 1H NMR and 13C, and elemental analysis. Molecular oxygen reoxidizes the (Mo(IV)=O) reduced unit in the darkness, forming an oxo-peroxo-Mo intermediate. The catalyst under UV radiation transfers two oxygen atoms to the olefin. The α-pinene is found to be the most reactive monoterpene. [ABSTRACT FROM AUTHOR] |
| Copyright of Topics in Catalysis is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Header | DbId: egs DbLabel: Engineering Source An: 158725898 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO<subscript>2</subscript> Nanotubes for Selective Oxidation of Monoterpenes with Light and O<subscript>2</subscript>. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Martinez+Quiñonez%2C+Henry%22">Martinez Quiñonez, Henry</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> henry.martinez1@correo.uis.edu.co</i><br /><searchLink fieldCode="AR" term="%22Amaya%2C+Álvaro+A%2E%22">Amaya, Álvaro A.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Paez-Mozo%2C+Edgar+A%2E%22">Paez-Mozo, Edgar A.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Martinez+Ortega%2C+Fernando%22">Martinez Ortega, Fernando</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> fmartine@uis.edu.co</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Topics+in+Catalysis%22">Topics in Catalysis</searchLink>. Aug2022, Vol. 65 Issue 9-12, p1088-1101. 14p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Nanotubes%22">Nanotubes</searchLink><br /><searchLink fieldCode="DE" term="%22Monoterpenes%22">Monoterpenes</searchLink><br /><searchLink fieldCode="DE" term="%22Pinene%22">Pinene</searchLink><br /><searchLink fieldCode="DE" term="%22Ultraviolet+radiation%22">Ultraviolet radiation</searchLink><br /><searchLink fieldCode="DE" term="%22Elemental+analysis%22">Elemental analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Alkenes%22">Alkenes</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Selective Oxygen Atom Transfer to α-pinene, β-pinene, (R)-limonene and camphene by dioxo-Mo(VI)Ln complex {Ln = 2-aminothiazole-4-carboxylic acid} anchored on TiO2 nanotubes (TiO2-NT) using O2 as oxidant and UV light was studied at ambient conditions. The Catalytic system was characterized by FTIR, 1H NMR and 13C, and elemental analysis. Molecular oxygen reoxidizes the (Mo(IV)=O) reduced unit in the darkness, forming an oxo-peroxo-Mo intermediate. The catalyst under UV radiation transfers two oxygen atoms to the olefin. The α-pinene is found to be the most reactive monoterpene. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Topics in Catalysis is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1007/s11244-022-01656-9 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 14 StartPage: 1088 Subjects: – SubjectFull: Nanotubes Type: general – SubjectFull: Monoterpenes Type: general – SubjectFull: Pinene Type: general – SubjectFull: Ultraviolet radiation Type: general – SubjectFull: Elemental analysis Type: general – SubjectFull: Alkenes Type: general Titles: – TitleFull: Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Martinez Quiñonez, Henry – PersonEntity: Name: NameFull: Amaya, Álvaro A. – PersonEntity: Name: NameFull: Paez-Mozo, Edgar A. – PersonEntity: Name: NameFull: Martinez Ortega, Fernando IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 08 Text: Aug2022 Type: published Y: 2022 Identifiers: – Type: issn-print Value: 10225528 Numbering: – Type: volume Value: 65 – Type: issue Value: 9-12 Titles: – TitleFull: Topics in Catalysis Type: main |
| ResultId | 1 |
