CuCoNi–S anchored CoMoO4/MoO3 forming core–shell structure for high-performance asymmetric supercapacitors.

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Title: CuCoNi–S anchored CoMoO4/MoO3 forming core–shell structure for high-performance asymmetric supercapacitors.
Authors: Li, Tiansheng1 (AUTHOR), Zhao, Zhifeng2 (AUTHOR) zhifengzhao1980@163.com, Su, Zhanhua2 (AUTHOR), Sun, Rui1 (AUTHOR), Li, Xiaofeng1 (AUTHOR) lixiaofeng@hrbnu.edu.cn, Shang, Yongchen1 (AUTHOR) yongchenshang@163.com
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 11/14/2022, Vol. 51 Issue 42, p16111-16118. 8p.
Subjects: Supercapacitor electrodes, Metal sulfides, Energy density, Energy storage, Transition metals, Oxide electrodes
Abstract: Although the preparation of transition metal sulfides/oxides electrodes has been relatively perfected, it is still challenging to fabricate multi-component transition metal sulfides/oxides core–shell structure electrodes with excellent electrochemical performance. Herein, CoMoO4/MoO3@CuCoNi–S grown on nickel foam (NF) is first synthesized via facile hydrothermal and electrodeposition methods. The CoMoO4/MoO3@CuCoNi–S electrode presents an exceptional specific capacitance (2600.0 F g−1 at 1 A g−1) and 68.3% of its initial capacitance at 10 A g−1. Moreover, a CoMoO4/MoO3@CuCoNi–S//active carbon (AC) device is assembled for determining its electrochemical application. It reveals a high energy density of 42.1 W h kg−1 at a power density of 800.2 W kg−1, an extended voltage window of 1.6 V and excellent stability with 96.9% retention after 5000 cycles at 2 A g−1. This work offers a reference case for the development of multi-component transition metal sulfides/oxides core–shell structure composites for energy storage. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: CuCoNi–S anchored CoMoO<subscript>4</subscript>/MoO<subscript>3</subscript> forming core–shell structure for high-performance asymmetric supercapacitors.
– Name: Author
  Label: Authors
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  Data: <searchLink fieldCode="AR" term="%22Li%2C+Tiansheng%22">Li, Tiansheng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhao%2C+Zhifeng%22">Zhao, Zhifeng</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> zhifengzhao1980@163.com</i><br /><searchLink fieldCode="AR" term="%22Su%2C+Zhanhua%22">Su, Zhanhua</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sun%2C+Rui%22">Sun, Rui</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Li%2C+Xiaofeng%22">Li, Xiaofeng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> lixiaofeng@hrbnu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Shang%2C+Yongchen%22">Shang, Yongchen</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> yongchenshang@163.com</i>
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  Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. 11/14/2022, Vol. 51 Issue 42, p16111-16118. 8p.
– Name: Subject
  Label: Subjects
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  Data: <searchLink fieldCode="DE" term="%22Supercapacitor+electrodes%22">Supercapacitor electrodes</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+sulfides%22">Metal sulfides</searchLink><br /><searchLink fieldCode="DE" term="%22Energy+density%22">Energy density</searchLink><br /><searchLink fieldCode="DE" term="%22Energy+storage%22">Energy storage</searchLink><br /><searchLink fieldCode="DE" term="%22Transition+metals%22">Transition metals</searchLink><br /><searchLink fieldCode="DE" term="%22Oxide+electrodes%22">Oxide electrodes</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Although the preparation of transition metal sulfides/oxides electrodes has been relatively perfected, it is still challenging to fabricate multi-component transition metal sulfides/oxides core–shell structure electrodes with excellent electrochemical performance. Herein, CoMoO4/MoO3@CuCoNi–S grown on nickel foam (NF) is first synthesized via facile hydrothermal and electrodeposition methods. The CoMoO4/MoO3@CuCoNi–S electrode presents an exceptional specific capacitance (2600.0 F g−1 at 1 A g−1) and 68.3% of its initial capacitance at 10 A g−1. Moreover, a CoMoO4/MoO3@CuCoNi–S//active carbon (AC) device is assembled for determining its electrochemical application. It reveals a high energy density of 42.1 W h kg−1 at a power density of 800.2 W kg−1, an extended voltage window of 1.6 V and excellent stability with 96.9% retention after 5000 cycles at 2 A g−1. This work offers a reference case for the development of multi-component transition metal sulfides/oxides core–shell structure composites for energy storage. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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        Value: 10.1039/d2dt02532a
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        Text: English
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        PageCount: 8
        StartPage: 16111
    Subjects:
      – SubjectFull: Supercapacitor electrodes
        Type: general
      – SubjectFull: Metal sulfides
        Type: general
      – SubjectFull: Energy density
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      – SubjectFull: Energy storage
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      – SubjectFull: Transition metals
        Type: general
      – SubjectFull: Oxide electrodes
        Type: general
    Titles:
      – TitleFull: CuCoNi–S anchored CoMoO4/MoO3 forming core–shell structure for high-performance asymmetric supercapacitors.
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            NameFull: Li, Tiansheng
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            NameFull: Zhao, Zhifeng
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            NameFull: Su, Zhanhua
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            NameFull: Sun, Rui
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            NameFull: Li, Xiaofeng
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            NameFull: Shang, Yongchen
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              M: 11
              Text: 11/14/2022
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              Y: 2022
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              Value: 51
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