Multi-element Saha Boltzmann plot (MESBP) coupled calibration-free laser-induced breakdown spectroscopy (CF-LIBS): an efficient approach for quantitative elemental analysis.
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| Title: | Multi-element Saha Boltzmann plot (MESBP) coupled calibration-free laser-induced breakdown spectroscopy (CF-LIBS): an efficient approach for quantitative elemental analysis. |
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| Authors: | John, Lekha Mary1 (AUTHOR), Issac, R. C.1 (AUTHOR), Sankararaman, S.2 (AUTHOR), Anoop, K. K.1 (AUTHOR) anoopkk@cusat.ac.in |
| Source: | JAAS (Journal of Analytical Atomic Spectrometry). Nov2022, Vol. 37 Issue 11, p2451-2460. 10p. |
| Subjects: | Laser-induced breakdown spectroscopy, Elemental analysis, Quantitative research, Cobalt alloys |
| Abstract: | The development of calibration-free laser-induced breakdown spectroscopy (CF-LIBS) has reduced the challenges faced by quantitative elemental analysis using conventional methods and expanded the scope of LIBS as an analytical technique. In conventional CF-LIBS, the y-intercept of the Boltzmann plot is used for estimating the concentration of individual species in the sample and hence the sensitivity of species concentration to the slope is very high. Since the Boltzmann plot considers lines of single species, the conventional LIBS is prone to uncertainties in transition probability, statistical fluctuations, and self-absorption. These issues, to an extent, can be dealt with by considering a generalised approach for temperature evaluation, such as the multi-element Saha Boltzmann Plot (MESBP) method. In this work, we combined MESBP with time-gated CF-LIBS through a regressive algorithm to enhance the accuracy of quantitative analysis. A comparative study between CF-LIBS and MESBP-CF-LIBS has been performed by estimating the elemental concentration of a standard Vitallium alloy with 65% cobalt, 30% chromium and 5% molybdenum. In the MESBP-LIBS approach, we observed a reduction in distance value from 22 to 6, which represents a considerable improvement in the precision of quantitative elemental analysis. [ABSTRACT FROM AUTHOR] |
| Copyright of JAAS (Journal of Analytical Atomic Spectrometry) is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 160003580 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Multi-element Saha Boltzmann plot (MESBP) coupled calibration-free laser-induced breakdown spectroscopy (CF-LIBS): an efficient approach for quantitative elemental analysis. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22John%2C+Lekha+Mary%22">John, Lekha Mary</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Issac%2C+R%2E+C%2E%22">Issac, R. C.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sankararaman%2C+S%2E%22">Sankararaman, S.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Anoop%2C+K%2E+K%2E%22">Anoop, K. K.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> anoopkk@cusat.ac.in</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22JAAS+%28Journal+of+Analytical+Atomic+Spectrometry%29%22">JAAS (Journal of Analytical Atomic Spectrometry)</searchLink>. Nov2022, Vol. 37 Issue 11, p2451-2460. 10p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Laser-induced+breakdown+spectroscopy%22">Laser-induced breakdown spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Elemental+analysis%22">Elemental analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Quantitative+research%22">Quantitative research</searchLink><br /><searchLink fieldCode="DE" term="%22Cobalt+alloys%22">Cobalt alloys</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: The development of calibration-free laser-induced breakdown spectroscopy (CF-LIBS) has reduced the challenges faced by quantitative elemental analysis using conventional methods and expanded the scope of LIBS as an analytical technique. In conventional CF-LIBS, the y-intercept of the Boltzmann plot is used for estimating the concentration of individual species in the sample and hence the sensitivity of species concentration to the slope is very high. Since the Boltzmann plot considers lines of single species, the conventional LIBS is prone to uncertainties in transition probability, statistical fluctuations, and self-absorption. These issues, to an extent, can be dealt with by considering a generalised approach for temperature evaluation, such as the multi-element Saha Boltzmann Plot (MESBP) method. In this work, we combined MESBP with time-gated CF-LIBS through a regressive algorithm to enhance the accuracy of quantitative analysis. A comparative study between CF-LIBS and MESBP-CF-LIBS has been performed by estimating the elemental concentration of a standard Vitallium alloy with 65% cobalt, 30% chromium and 5% molybdenum. In the MESBP-LIBS approach, we observed a reduction in distance value from 22 to 6, which represents a considerable improvement in the precision of quantitative elemental analysis. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of JAAS (Journal of Analytical Atomic Spectrometry) is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1039/d2ja00218c Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 10 StartPage: 2451 Subjects: – SubjectFull: Laser-induced breakdown spectroscopy Type: general – SubjectFull: Elemental analysis Type: general – SubjectFull: Quantitative research Type: general – SubjectFull: Cobalt alloys Type: general Titles: – TitleFull: Multi-element Saha Boltzmann plot (MESBP) coupled calibration-free laser-induced breakdown spectroscopy (CF-LIBS): an efficient approach for quantitative elemental analysis. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: John, Lekha Mary – PersonEntity: Name: NameFull: Issac, R. C. – PersonEntity: Name: NameFull: Sankararaman, S. – PersonEntity: Name: NameFull: Anoop, K. K. IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 11 Text: Nov2022 Type: published Y: 2022 Identifiers: – Type: issn-print Value: 02679477 Numbering: – Type: volume Value: 37 – Type: issue Value: 11 Titles: – TitleFull: JAAS (Journal of Analytical Atomic Spectrometry) Type: main |
| ResultId | 1 |
