View in EDS

Highly efficient Friedel-Crafts acylation of veratrole over TiO2-SnOx solid solution catalyst.

Saved in:
Bibliographic Details
Title: Highly efficient Friedel-Crafts acylation of veratrole over TiO2-SnOx solid solution catalyst.
Authors: Lu, Haoyu1,2 (AUTHOR), Xie, Jin2 (AUTHOR), Wu, Xiaojing2 (AUTHOR), Ma, Qianli2 (AUTHOR), Cheng, Jianian2 (AUTHOR), Li, Zelong1,2 (AUTHOR) lizl@lzu.edu.cn, Hu, Dongcheng1 (AUTHOR) hudch@nwnu.edu.cn
Source: Applied Catalysis A: General. Nov2022, Vol. 648, pN.PAG-N.PAG. 1p.
Subjects: Solid solutions, Metal catalysts, Acid catalysts, Acylation, Metallic oxides, Lewis acids, Solid oxide fuel cells
Abstract: Friedel-Crafts (F-C) acylation reaction is one of the most effective processes to produce aromatic ketones. Classical homogeneous Lewis acid catalysts have difficulty in separation and solid waste generation, which limit their industrial application. Herein, binary metal oxide TiO 2 -SnO x were prepared, these solid solution catalysts show the highly efficient activity for the F-C reaction of veratrole and 4-chlorobenzoyl chloride (4-CBC). The optimized 0.1TiO 2 -SnO x catalyst exhibits the veratrole conversion of 74 % and the 4-chloro-3′,4′-dimethoxybenzophenone (CDMB) selectivity of 97 %. Additionally, it shows good stability. The outstanding catalytic performance of TiO 2 -SnO x can be attributed to homogeneous doping of Ti in SnO x at the atomic level, which results in the strong Lewis acid sites with high density on the surface of solid solution. This work revealed the superior Lewis acid catalyst with solid solution structure, constructed through binary metal oxide, can pave a new avenue for developing the solid Lewis acid with excellent catalytic performance. [Display omitted] • Binary metal oxide TiO 2 -SnO x solid solution catalysts were fabricated. • Friedel-Crafts acylation reaction of veratrole and 4-chlorobenzoyl chloride was performed. • TiO 2 -SnO x shows excellent stability under five cycles. • NH 3 -TPD and Py-IR analysis were used to investigate the acid properties. [ABSTRACT FROM AUTHOR]
Copyright of Applied Catalysis A: General is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 160166661
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Highly efficient Friedel-Crafts acylation of veratrole over TiO2-SnOx solid solution catalyst.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Lu%2C+Haoyu%22">Lu, Haoyu</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xie%2C+Jin%22">Xie, Jin</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wu%2C+Xiaojing%22">Wu, Xiaojing</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ma%2C+Qianli%22">Ma, Qianli</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Cheng%2C+Jianian%22">Cheng, Jianian</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Li%2C+Zelong%22">Li, Zelong</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> lizl@lzu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Hu%2C+Dongcheng%22">Hu, Dongcheng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> hudch@nwnu.edu.cn</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Applied+Catalysis+A%3A+General%22">Applied Catalysis A: General</searchLink>. Nov2022, Vol. 648, pN.PAG-N.PAG. 1p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Solid+solutions%22">Solid solutions</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+catalysts%22">Metal catalysts</searchLink><br /><searchLink fieldCode="DE" term="%22Acid+catalysts%22">Acid catalysts</searchLink><br /><searchLink fieldCode="DE" term="%22Acylation%22">Acylation</searchLink><br /><searchLink fieldCode="DE" term="%22Metallic+oxides%22">Metallic oxides</searchLink><br /><searchLink fieldCode="DE" term="%22Lewis+acids%22">Lewis acids</searchLink><br /><searchLink fieldCode="DE" term="%22Solid+oxide+fuel+cells%22">Solid oxide fuel cells</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Friedel-Crafts (F-C) acylation reaction is one of the most effective processes to produce aromatic ketones. Classical homogeneous Lewis acid catalysts have difficulty in separation and solid waste generation, which limit their industrial application. Herein, binary metal oxide TiO 2 -SnO x were prepared, these solid solution catalysts show the highly efficient activity for the F-C reaction of veratrole and 4-chlorobenzoyl chloride (4-CBC). The optimized 0.1TiO 2 -SnO x catalyst exhibits the veratrole conversion of 74 % and the 4-chloro-3′,4′-dimethoxybenzophenone (CDMB) selectivity of 97 %. Additionally, it shows good stability. The outstanding catalytic performance of TiO 2 -SnO x can be attributed to homogeneous doping of Ti in SnO x at the atomic level, which results in the strong Lewis acid sites with high density on the surface of solid solution. This work revealed the superior Lewis acid catalyst with solid solution structure, constructed through binary metal oxide, can pave a new avenue for developing the solid Lewis acid with excellent catalytic performance. [Display omitted] • Binary metal oxide TiO 2 -SnO x solid solution catalysts were fabricated. • Friedel-Crafts acylation reaction of veratrole and 4-chlorobenzoyl chloride was performed. • TiO 2 -SnO x shows excellent stability under five cycles. • NH 3 -TPD and Py-IR analysis were used to investigate the acid properties. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Applied Catalysis A: General is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=160166661
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.apcata.2022.118922
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Solid solutions
        Type: general
      – SubjectFull: Metal catalysts
        Type: general
      – SubjectFull: Acid catalysts
        Type: general
      – SubjectFull: Acylation
        Type: general
      – SubjectFull: Metallic oxides
        Type: general
      – SubjectFull: Lewis acids
        Type: general
      – SubjectFull: Solid oxide fuel cells
        Type: general
    Titles:
      – TitleFull: Highly efficient Friedel-Crafts acylation of veratrole over TiO2-SnOx solid solution catalyst.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Lu, Haoyu
      – PersonEntity:
          Name:
            NameFull: Xie, Jin
      – PersonEntity:
          Name:
            NameFull: Wu, Xiaojing
      – PersonEntity:
          Name:
            NameFull: Ma, Qianli
      – PersonEntity:
          Name:
            NameFull: Cheng, Jianian
      – PersonEntity:
          Name:
            NameFull: Li, Zelong
      – PersonEntity:
          Name:
            NameFull: Hu, Dongcheng
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 25
              M: 11
              Text: Nov2022
              Type: published
              Y: 2022
          Identifiers:
            – Type: issn-print
              Value: 0926860X
          Numbering:
            – Type: volume
              Value: 648
          Titles:
            – TitleFull: Applied Catalysis A: General
              Type: main
ResultId 1