Corrosion Behavior of Ti 3 SiC 2 in Flowing Liquid Lead–Bismuth Eutectic at 500 °C.

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Title: Corrosion Behavior of Ti 3 SiC 2 in Flowing Liquid Lead–Bismuth Eutectic at 500 °C.
Authors: Lyu, Liangliang1 (AUTHOR), Qiu, Xi1 (AUTHOR), Yue, Huifang1 (AUTHOR), Zhou, Mingyang1 (AUTHOR) 18782951516@163.com, Zhu, Huiping2 (AUTHOR)
Source: Materials (1996-1944). Nov2022, Vol. 15 Issue 21, p7406. 9p.
Subjects: Accelerator-driven systems, Fast reactors, Scanning electron microscopes, Microhardness testing, Construction materials, Duplex stainless steel, Bismuth
Abstract: MAX phases are promising candidate structural materials for lead-cooled fast reactors (LFRs) and accelerator-driven sub-critical systems (ADSs) due to their excellent corrosion resistance in liquid LBE. In this work, one of the typical MAX phases, Ti3SiC2, was exposed to the flowing LBE with a saturated oxygen concentration at 500 °C for up to 3000 h. The corrosion behaviors, including the evolution of the corrosion layer, mechanical properties and wettability, were evaluated via X-ray diffraction, a scanning electron microscope equipped with an energy-dispersive X-ray, a microhardness test and contact angle measurement. The results reveal that a corrosion structure with a duplex layer was formed on the sample surfaces. The outer layer was a diffusion layer, which always remained thin (<3 μm) during the whole test due to the erosion effect caused by the flowing LBE. The inner layer was the stable protective oxide layer, and its thickness increased with exposure time. The growth of the corrosion structure improved the microhardness and reduced the wettability with regard to LBE, which was beneficial to inhibiting further surface corrosion of Ti3SiC2. [ABSTRACT FROM AUTHOR]
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  Data: Corrosion Behavior of Ti 3 SiC 2 in Flowing Liquid Lead–Bismuth Eutectic at 500 &#176;C.
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  Data: &lt;searchLink fieldCode=&quot;JN&quot; term=&quot;%22Materials+%281996-1944%29%22&quot;&gt;Materials (1996-1944)&lt;/searchLink&gt;. Nov2022, Vol. 15 Issue 21, p7406. 9p.
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  Label: Abstract
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  Data: MAX phases are promising candidate structural materials for lead-cooled fast reactors (LFRs) and accelerator-driven sub-critical systems (ADSs) due to their excellent corrosion resistance in liquid LBE. In this work, one of the typical MAX phases, Ti3SiC2, was exposed to the flowing LBE with a saturated oxygen concentration at 500 &#176;C for up to 3000 h. The corrosion behaviors, including the evolution of the corrosion layer, mechanical properties and wettability, were evaluated via X-ray diffraction, a scanning electron microscope equipped with an energy-dispersive X-ray, a microhardness test and contact angle measurement. The results reveal that a corrosion structure with a duplex layer was formed on the sample surfaces. The outer layer was a diffusion layer, which always remained thin (&lt;3 μm) during the whole test due to the erosion effect caused by the flowing LBE. The inner layer was the stable protective oxide layer, and its thickness increased with exposure time. The growth of the corrosion structure improved the microhardness and reduced the wettability with regard to LBE, which was beneficial to inhibiting further surface corrosion of Ti3SiC2. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: &lt;i&gt;Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder&#39;s express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.&lt;/i&gt; (Copyright applies to all Abstracts.)
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        Value: 10.3390/ma15217406
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 9
        StartPage: 7406
    Subjects:
      – SubjectFull: Accelerator-driven systems
        Type: general
      – SubjectFull: Fast reactors
        Type: general
      – SubjectFull: Scanning electron microscopes
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      – SubjectFull: Microhardness testing
        Type: general
      – SubjectFull: Construction materials
        Type: general
      – SubjectFull: Duplex stainless steel
        Type: general
      – SubjectFull: Bismuth
        Type: general
    Titles:
      – TitleFull: Corrosion Behavior of Ti 3 SiC 2 in Flowing Liquid Lead–Bismuth Eutectic at 500 °C.
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            NameFull: Lyu, Liangliang
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            NameFull: Zhou, Mingyang
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            – D: 01
              M: 11
              Text: Nov2022
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              Y: 2022
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              Value: 15
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