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The Azaacepentalenide Anion: A New Aromatic, Bowl-Shaped Heterocycle.

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Title: The Azaacepentalenide Anion: A New Aromatic, Bowl-Shaped Heterocycle.
Authors: Mascal, Mark1 mascal@chem.ucdavis.edu, Bertran, Jordi Cerón1
Source: Journal of the American Chemical Society. 2/9/2005, Vol. 127 Issue 5, p1352-1353. 2p.
Subjects: Carbon, Aromatic compounds, Chemical structure, Molecular structure, Anions, Nitrogen
Abstract: This article discusses various issues related to the azaacepentalenide anion. Recently, the achievement of azafullerenes on a macroscopic scale has opened up a new dimension in carbon cage research. However, no convex aromatic polycycle including nitrogen in its framework appears to have yet been described. The article authors have for some time been studying a class of rigid, hemispherical tricycles of the azatriquinane family and have recently completed the synthesis of 10-azatriquinacene. The authors set sights on the analogous azaacepentalenide anion, and here, in this article, they describe the preparation of both azaacepentalenide anion and its perchloro derivative.
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 16097902
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: The Azaacepentalenide Anion: A New Aromatic, Bowl-Shaped Heterocycle.
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  Data: <searchLink fieldCode="AR" term="%22Mascal%2C+Mark%22">Mascal, Mark</searchLink><relatesTo>1</relatesTo><i> mascal@chem.ucdavis.edu</i><br /><searchLink fieldCode="AR" term="%22Bertran%2C+Jordi+Cerón%22">Bertran, Jordi Cerón</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+the+American+Chemical+Society%22">Journal of the American Chemical Society</searchLink>. 2/9/2005, Vol. 127 Issue 5, p1352-1353. 2p.
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  Data: <searchLink fieldCode="DE" term="%22Carbon%22">Carbon</searchLink><br /><searchLink fieldCode="DE" term="%22Aromatic+compounds%22">Aromatic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+structure%22">Chemical structure</searchLink><br /><searchLink fieldCode="DE" term="%22Molecular+structure%22">Molecular structure</searchLink><br /><searchLink fieldCode="DE" term="%22Anions%22">Anions</searchLink><br /><searchLink fieldCode="DE" term="%22Nitrogen%22">Nitrogen</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: This article discusses various issues related to the azaacepentalenide anion. Recently, the achievement of azafullerenes on a macroscopic scale has opened up a new dimension in carbon cage research. However, no convex aromatic polycycle including nitrogen in its framework appears to have yet been described. The article authors have for some time been studying a class of rigid, hemispherical tricycles of the azatriquinane family and have recently completed the synthesis of 10-azatriquinacene. The authors set sights on the analogous azaacepentalenide anion, and here, in this article, they describe the preparation of both azaacepentalenide anion and its perchloro derivative.
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=16097902
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      – Type: doi
        Value: 10.1021/ja043593c
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 2
        StartPage: 1352
    Subjects:
      – SubjectFull: Carbon
        Type: general
      – SubjectFull: Aromatic compounds
        Type: general
      – SubjectFull: Chemical structure
        Type: general
      – SubjectFull: Molecular structure
        Type: general
      – SubjectFull: Anions
        Type: general
      – SubjectFull: Nitrogen
        Type: general
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      – TitleFull: The Azaacepentalenide Anion: A New Aromatic, Bowl-Shaped Heterocycle.
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            NameFull: Mascal, Mark
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            NameFull: Bertran, Jordi Cerón
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            – D: 09
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              Text: 2/9/2005
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              Y: 2005
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