Designing a hierarchical structure of nickel-cobalt-sulfide decorated on electrospun N-doped carbon nanofiber as an efficient electrode material for hybrid supercapacitors.

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Title: Designing a hierarchical structure of nickel-cobalt-sulfide decorated on electrospun N-doped carbon nanofiber as an efficient electrode material for hybrid supercapacitors.
Authors: Abdel-Salam, Ahmed I.1 (AUTHOR), Attia, Sayed Y.2 (AUTHOR), Mohamed, Saad G.1,2 (AUTHOR) saadmohamed@tims.gov.eg, El-Hosiny, Fouad I.3 (AUTHOR), Sadek, M.A.4 (AUTHOR), Rashad, M.M.5,6 (AUTHOR)
Source: International Journal of Hydrogen Energy. Feb2023, Vol. 48 Issue 14, p5463-5477. 15p.
Subjects: Supercapacitor electrodes, Supercapacitors, Energy density, Negative electrode, Doping agents (Chemistry), Electrodes, Cobalt
Abstract: The intent of designing and exploring novel active electrode materials is to enhance the electrochemical performance of supercapacitors. Herein, a hierarchical structure of nickel-cobalt-sulfide nanostructures (NiCo 2 S 4) decorated on the electrospun N -doped carbon nanofiber (CNF), NiCo 2 S 4 @CNF, is manipulated using a one-step and simple hydrothermal approach. The fabricated hierarchical structure of the NiCo 2 S 4 @CNF is featured by a large surface area and a high porosity that serve as ion diffusion channels. Therefore, it manifests high specific capacitance and specific capacity values of 377.2 C g−1 and 754.4 F g−1 at a current density of 1 A g−1, respectively. Furthermore, a NiCo 2 S 4 @CNF//CNF hybrid supercapacitor in which a positive electrode of NiCo 2 S 4 @CNF is assembled with a negative electrode of CNF to estimate the electrochemical performance of the NiCo 2 S 4 @CNF. As a result, the device has a superior energy density of 65.6 and 52.5 Wh kg−1 at a power density of 665 and 1313.8 W kg−1, respectively. Moreover, the device reveals good stability with capacitance retention of 72% after 3000 charge/discharge cycles. These outstanding results enable the designed hierarchical structure of the NiCo 2 S 4 @CNF to be a promising electrode material for supercapacitors (SCs) applications. [Display omitted] • The hierarchical structure of NiCo 2 S 4 @CNF was prepared to be used as an efficient electrode for a hybrid supercapacitor. • NiCo 2 S 4 @the electrospun N -doped CNF has a higher surface area and a high porosity that serves as ion diffusion channels. • NiCo 2 S 4 @CNF hierarchical structure exhibited a specific capacitance of 754.4 F g−1 at a current density of 1 A g−1. • NiCo 2 S 4 @CNF//CNF hybrid supercapacitor showed specific energy of 65.6 W h kg−1 at a specific power of 665 W kg−1. [ABSTRACT FROM AUTHOR]
Copyright of International Journal of Hydrogen Energy is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Designing a hierarchical structure of nickel-cobalt-sulfide decorated on electrospun N-doped carbon nanofiber as an efficient electrode material for hybrid supercapacitors.
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  Data: <searchLink fieldCode="AR" term="%22Abdel-Salam%2C+Ahmed+I%2E%22">Abdel-Salam, Ahmed I.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Attia%2C+Sayed+Y%2E%22">Attia, Sayed Y.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Mohamed%2C+Saad+G%2E%22">Mohamed, Saad G.</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> saadmohamed@tims.gov.eg</i><br /><searchLink fieldCode="AR" term="%22El-Hosiny%2C+Fouad+I%2E%22">El-Hosiny, Fouad I.</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sadek%2C+M%2EA%2E%22">Sadek, M.A.</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Rashad%2C+M%2EM%2E%22">Rashad, M.M.</searchLink><relatesTo>5,6</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22International+Journal+of+Hydrogen+Energy%22">International Journal of Hydrogen Energy</searchLink>. Feb2023, Vol. 48 Issue 14, p5463-5477. 15p.
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  Data: <searchLink fieldCode="DE" term="%22Supercapacitor+electrodes%22">Supercapacitor electrodes</searchLink><br /><searchLink fieldCode="DE" term="%22Supercapacitors%22">Supercapacitors</searchLink><br /><searchLink fieldCode="DE" term="%22Energy+density%22">Energy density</searchLink><br /><searchLink fieldCode="DE" term="%22Negative+electrode%22">Negative electrode</searchLink><br /><searchLink fieldCode="DE" term="%22Doping+agents+%28Chemistry%29%22">Doping agents (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Electrodes%22">Electrodes</searchLink><br /><searchLink fieldCode="DE" term="%22Cobalt%22">Cobalt</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The intent of designing and exploring novel active electrode materials is to enhance the electrochemical performance of supercapacitors. Herein, a hierarchical structure of nickel-cobalt-sulfide nanostructures (NiCo 2 S 4) decorated on the electrospun N -doped carbon nanofiber (CNF), NiCo 2 S 4 @CNF, is manipulated using a one-step and simple hydrothermal approach. The fabricated hierarchical structure of the NiCo 2 S 4 @CNF is featured by a large surface area and a high porosity that serve as ion diffusion channels. Therefore, it manifests high specific capacitance and specific capacity values of 377.2 C g−1 and 754.4 F g−1 at a current density of 1 A g−1, respectively. Furthermore, a NiCo 2 S 4 @CNF//CNF hybrid supercapacitor in which a positive electrode of NiCo 2 S 4 @CNF is assembled with a negative electrode of CNF to estimate the electrochemical performance of the NiCo 2 S 4 @CNF. As a result, the device has a superior energy density of 65.6 and 52.5 Wh kg−1 at a power density of 665 and 1313.8 W kg−1, respectively. Moreover, the device reveals good stability with capacitance retention of 72% after 3000 charge/discharge cycles. These outstanding results enable the designed hierarchical structure of the NiCo 2 S 4 @CNF to be a promising electrode material for supercapacitors (SCs) applications. [Display omitted] • The hierarchical structure of NiCo 2 S 4 @CNF was prepared to be used as an efficient electrode for a hybrid supercapacitor. • NiCo 2 S 4 @the electrospun N -doped CNF has a higher surface area and a high porosity that serves as ion diffusion channels. • NiCo 2 S 4 @CNF hierarchical structure exhibited a specific capacitance of 754.4 F g−1 at a current density of 1 A g−1. • NiCo 2 S 4 @CNF//CNF hybrid supercapacitor showed specific energy of 65.6 W h kg−1 at a specific power of 665 W kg−1. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of International Journal of Hydrogen Energy is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.ijhydene.2022.11.134
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 15
        StartPage: 5463
    Subjects:
      – SubjectFull: Supercapacitor electrodes
        Type: general
      – SubjectFull: Supercapacitors
        Type: general
      – SubjectFull: Energy density
        Type: general
      – SubjectFull: Negative electrode
        Type: general
      – SubjectFull: Doping agents (Chemistry)
        Type: general
      – SubjectFull: Electrodes
        Type: general
      – SubjectFull: Cobalt
        Type: general
    Titles:
      – TitleFull: Designing a hierarchical structure of nickel-cobalt-sulfide decorated on electrospun N-doped carbon nanofiber as an efficient electrode material for hybrid supercapacitors.
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              M: 02
              Text: Feb2023
              Type: published
              Y: 2023
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