Observation of recoverable energy response in Na0.5Bi0.5TiO3–Ba0.85Sr0.15Zr0.1Ti0.9O3–Ni0.7Zn0.3Fe2O4 lead-free composites for energy storage applications.

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Title: Observation of recoverable energy response in Na0.5Bi0.5TiO3–Ba0.85Sr0.15Zr0.1Ti0.9O3–Ni0.7Zn0.3Fe2O4 lead-free composites for energy storage applications.
Authors: Goel, Rahul1 (AUTHOR), Aggarwal, Mehak1 (AUTHOR), Syal, Rajat1,2 (AUTHOR), Sharma, Gyaneshwar3 (AUTHOR), Dhiman, Shobhna1 (AUTHOR), Singh, Arun Kumar4 (AUTHOR), Kumar, Sanjeev1 (AUTHOR) sanjeev04101977@gmail.com
Source: Journal of Materials Science: Materials in Electronics. Mar2023, Vol. 34 Issue 7, p1-15. 15p.
Abstract: From the energy storage perspective, ferroelectric materials with excellent polarizing characteristics are considered as desirable candidates. We report synthesis of lead-free binary composite of Na0.5Bi0.5TiO3 (NBT)–Ba0.85Sr0.15Zr0.1Ti0.9O3 (BSZT) to realize morphotrophic phase boundary (MPB) system having promising ferroic characteristics. Further, to avail excellent energy storage characteristics, we introduce Ni0.7Zn0.3Fe2O4 (NZFO) as a non-ferroelectric material. The introduction of non-ferroelectric subsystem enhances the energy storage efficiency via domain engineering. The structural, ferroelectric, and morphological behaviour of the novel composites were investigated in order to probe their electrical and energy storage response. Polarization vs. electric field (P–E) loops become slimmer as content of non-ferroelectric subcomponent is increased. The log J vs. log E fitting is used to estimate the individual conduction mechanism. Energy density WU ~ 107 mJ/cm3 and 69 mJ/cm3 with efficiency η ~ 39.8% and 39.2% is observed in 10% and 20% ferrite composites, respectively, which further emphasize that the energy storage response of MPB-based ferroic system may be optimized via domain engineering. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Materials Science: Materials in Electronics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Observation of recoverable energy response in Na<subscript>0.5</subscript>Bi<subscript>0.5</subscript>TiO<subscript>3</subscript>–Ba<subscript>0.85</subscript>Sr<subscript>0.15</subscript>Zr<subscript>0.1</subscript>Ti<subscript>0.9</subscript>O<subscript>3</subscript>–Ni<subscript>0.7</subscript>Zn<subscript>0.3</subscript>Fe<subscript>2</subscript>O<subscript>4</subscript> lead-free composites for energy storage applications.
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  Data: <searchLink fieldCode="AR" term="%22Goel%2C+Rahul%22">Goel, Rahul</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Aggarwal%2C+Mehak%22">Aggarwal, Mehak</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Syal%2C+Rajat%22">Syal, Rajat</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sharma%2C+Gyaneshwar%22">Sharma, Gyaneshwar</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Dhiman%2C+Shobhna%22">Dhiman, Shobhna</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Singh%2C+Arun+Kumar%22">Singh, Arun Kumar</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Kumar%2C+Sanjeev%22">Kumar, Sanjeev</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> sanjeev04101977@gmail.com</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Materials+Science%3A+Materials+in+Electronics%22">Journal of Materials Science: Materials in Electronics</searchLink>. Mar2023, Vol. 34 Issue 7, p1-15. 15p.
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: From the energy storage perspective, ferroelectric materials with excellent polarizing characteristics are considered as desirable candidates. We report synthesis of lead-free binary composite of Na0.5Bi0.5TiO3 (NBT)–Ba0.85Sr0.15Zr0.1Ti0.9O3 (BSZT) to realize morphotrophic phase boundary (MPB) system having promising ferroic characteristics. Further, to avail excellent energy storage characteristics, we introduce Ni0.7Zn0.3Fe2O4 (NZFO) as a non-ferroelectric material. The introduction of non-ferroelectric subsystem enhances the energy storage efficiency via domain engineering. The structural, ferroelectric, and morphological behaviour of the novel composites were investigated in order to probe their electrical and energy storage response. Polarization vs. electric field (P–E) loops become slimmer as content of non-ferroelectric subcomponent is increased. The log J vs. log E fitting is used to estimate the individual conduction mechanism. Energy density WU ~ 107 mJ/cm3 and 69 mJ/cm3 with efficiency η ~ 39.8% and 39.2% is observed in 10% and 20% ferrite composites, respectively, which further emphasize that the energy storage response of MPB-based ferroic system may be optimized via domain engineering. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Journal of Materials Science: Materials in Electronics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1007/s10854-023-10112-7
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        Text: English
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      – TitleFull: Observation of recoverable energy response in Na0.5Bi0.5TiO3–Ba0.85Sr0.15Zr0.1Ti0.9O3–Ni0.7Zn0.3Fe2O4 lead-free composites for energy storage applications.
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            – D: 01
              M: 03
              Text: Mar2023
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