Polyvinyl Butyral Polymeric Host Material-Based Fluorescent Thin Films to Achieve Highly Efficient Red and Green Colour Conversion for Advanced Next-Generation Displays.

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Title: Polyvinyl Butyral Polymeric Host Material-Based Fluorescent Thin Films to Achieve Highly Efficient Red and Green Colour Conversion for Advanced Next-Generation Displays.
Authors: Gaurav, Ashish1 (AUTHOR), Lin, Yi-Shan1 (AUTHOR), Tsai, Chih-Yuan1 (AUTHOR), Huang, Jung-Kuan1 (AUTHOR), Lin, Ching-Fuh1,2,3 (AUTHOR) lincf@ntu.edu.tw
Source: Nanomaterials (2079-4991). Mar2023, Vol. 13 Issue 6, p1009. 13p.
Subjects: Polyvinyl butyral, Fourier transform infrared spectroscopy, Thin films, Hybrid materials, Intermolecular forces
Abstract: Rare-earth element-free fluorescent materials are eco-friendlier than other traditional fluorescent precursors, such as quantum dots and phosphors. In this study, we explore a simple and facile solution-based technique to prepare fluorescent films, which are highly stable under ordinary room conditions and show hydrophobic behaviour. The proposed hybrid material was designed with hybrid composites that use polyvinyl butyral (PVB) as a host doped with organic dyes. The red and green fluorescent films exhibited quantum yields of 89% and 80%, respectively, and both are very uniform in thickness and water resistant. Additionally, PVB was further compared with another polymeric host, such as polyvinylpyrrolidone (PVP), to evaluate their binding ability and encapsulation behaviour. Next, the effect of PVB on the optical and chemical properties of the fluorescent materials was studied using UV spectroscopy and Fourier transform infrared spectroscopy. The analysis revealed that no new bond was formed between the host material and fluorescent precursor during the process, with intermolecular forces being present between different molecules. Moreover, the thickness of the fluorescent film and quantum yield relation were evaluated. Finally, the hydrophobic nature, strong binding ability, and optical enhancement by PVB provide a powerful tool for fabricating a highly efficient fluorescent film with enhanced stability in an external environment based on its promising encapsulation properties. These efficient fluorescent films have a bright potential in colour conversion for next-generation display applications. [ABSTRACT FROM AUTHOR]
Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Polyvinyl Butyral Polymeric Host Material-Based Fluorescent Thin Films to Achieve Highly Efficient Red and Green Colour Conversion for Advanced Next-Generation Displays.
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  Data: <searchLink fieldCode="JN" term="%22Nanomaterials+%282079-4991%29%22">Nanomaterials (2079-4991)</searchLink>. Mar2023, Vol. 13 Issue 6, p1009. 13p.
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  Data: <searchLink fieldCode="DE" term="%22Polyvinyl+butyral%22">Polyvinyl butyral</searchLink><br /><searchLink fieldCode="DE" term="%22Fourier+transform+infrared+spectroscopy%22">Fourier transform infrared spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Thin+films%22">Thin films</searchLink><br /><searchLink fieldCode="DE" term="%22Hybrid+materials%22">Hybrid materials</searchLink><br /><searchLink fieldCode="DE" term="%22Intermolecular+forces%22">Intermolecular forces</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Rare-earth element-free fluorescent materials are eco-friendlier than other traditional fluorescent precursors, such as quantum dots and phosphors. In this study, we explore a simple and facile solution-based technique to prepare fluorescent films, which are highly stable under ordinary room conditions and show hydrophobic behaviour. The proposed hybrid material was designed with hybrid composites that use polyvinyl butyral (PVB) as a host doped with organic dyes. The red and green fluorescent films exhibited quantum yields of 89% and 80%, respectively, and both are very uniform in thickness and water resistant. Additionally, PVB was further compared with another polymeric host, such as polyvinylpyrrolidone (PVP), to evaluate their binding ability and encapsulation behaviour. Next, the effect of PVB on the optical and chemical properties of the fluorescent materials was studied using UV spectroscopy and Fourier transform infrared spectroscopy. The analysis revealed that no new bond was formed between the host material and fluorescent precursor during the process, with intermolecular forces being present between different molecules. Moreover, the thickness of the fluorescent film and quantum yield relation were evaluated. Finally, the hydrophobic nature, strong binding ability, and optical enhancement by PVB provide a powerful tool for fabricating a highly efficient fluorescent film with enhanced stability in an external environment based on its promising encapsulation properties. These efficient fluorescent films have a bright potential in colour conversion for next-generation display applications. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3390/nano13061009
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      – Code: eng
        Text: English
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        PageCount: 13
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      – SubjectFull: Polyvinyl butyral
        Type: general
      – SubjectFull: Fourier transform infrared spectroscopy
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      – SubjectFull: Thin films
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      – SubjectFull: Hybrid materials
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      – SubjectFull: Intermolecular forces
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      – TitleFull: Polyvinyl Butyral Polymeric Host Material-Based Fluorescent Thin Films to Achieve Highly Efficient Red and Green Colour Conversion for Advanced Next-Generation Displays.
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            NameFull: Gaurav, Ashish
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            – D: 15
              M: 03
              Text: Mar2023
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