Globular Phyllosilicates of the Glauconite–Illite Series in the Cambrian and Ordovician Rocks of the Eastern Baltica (Northern Estonia, Western Lithuania, and Western Latvia).

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Title: Globular Phyllosilicates of the Glauconite–Illite Series in the Cambrian and Ordovician Rocks of the Eastern Baltica (Northern Estonia, Western Lithuania, and Western Latvia).
Authors: Ivanovskaya, T. A.1 (AUTHOR) tat.ivanovsckaya2012@yandex.ru, Sakharov, B. A.1 (AUTHOR) sakharovb@gmail.com, Zaitseva, T. S.2 (AUTHOR) z-t-s@mail.ru
Source: Lithology & Mineral Resources. Apr2023, Vol. 58 Issue 2, p158-176. 19p.
Subjects: Phyllosilicates, Diffraction patterns, X-ray diffraction, Vermiculite, Smectite
Geographic Terms: Latvia, Estonia, Lithuania
Abstract: The mineralogical, structural and crystal-chemical features of seven samples of globular phyllosilicates of the glauconite–illite series (GPS) from the Lower Cambrian sequences of Northern Estonia and Western Lithuania, from the Middle Cambrian sequences of Western Latvia, and also from the Lower Ordovician sequences of Northern Estonia and Western Latvia are considered for the first time. Based on Al index (KAl = VIAl/[VIFe3+ + VIAl]) varying from 0.27 to 0.59, the globular phyllosilicates are attributed to the glauconite–illite series, most of which are represented by glauconites (the Al index is KAl = 0.27–0.46) and one sample, by Al-glauconite (KAl = 0.59). The K2O content in minerals is from 7.12 to 7.90%. The content of expandable layers (4–13%), their types (smectite, vermiculite), and the character of their alternation (R = 0, R = 2) were determined for the first time in the studied samples by simulation of experimental X-ray diffraction patterns from oriented specimens. Simulation of X-ray diffraction patterns obtained from unoriented specimens made it possible to determine the degree of three-dimensional order and mean values of the unit-cell parameter b (9.056–9.094 Å), as well as the distribution of their individual micaceous varieties. Based on these data, the microheterogeneity of the Cambrian and Ordovician GPSs was established and compared with the heterogeneity in the previously studied Riphean GPS (Drits et al., 2013). The obtained Rb-Sr и K‑Ar ages for the studied Middle Cambrian and Lower Ordovician samples, as well as the earlier published dates for the Lower Cambrian samples, are "rejuvenated" relative to age limits accepted for the Cambrian and Lower Ordovician (Gradstein et al., 2020). The relationship of the Cambrian and Lower Ordovician "rejuvenated" isotopic dates and the discovered GPS heterogeneity, as well as possible reasons for its occurrence, are discussed. [ABSTRACT FROM AUTHOR]
Copyright of Lithology & Mineral Resources is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Globular Phyllosilicates of the Glauconite–Illite Series in the Cambrian and Ordovician Rocks of the Eastern Baltica (Northern Estonia, Western Lithuania, and Western Latvia).
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  Data: The mineralogical, structural and crystal-chemical features of seven samples of globular phyllosilicates of the glauconite–illite series (GPS) from the Lower Cambrian sequences of Northern Estonia and Western Lithuania, from the Middle Cambrian sequences of Western Latvia, and also from the Lower Ordovician sequences of Northern Estonia and Western Latvia are considered for the first time. Based on Al index (KAl = VIAl/[VIFe3+ + VIAl]) varying from 0.27 to 0.59, the globular phyllosilicates are attributed to the glauconite–illite series, most of which are represented by glauconites (the Al index is KAl = 0.27–0.46) and one sample, by Al-glauconite (KAl = 0.59). The K2O content in minerals is from 7.12 to 7.90%. The content of expandable layers (4–13%), their types (smectite, vermiculite), and the character of their alternation (R = 0, R = 2) were determined for the first time in the studied samples by simulation of experimental X-ray diffraction patterns from oriented specimens. Simulation of X-ray diffraction patterns obtained from unoriented specimens made it possible to determine the degree of three-dimensional order and mean values of the unit-cell parameter b (9.056–9.094 Å), as well as the distribution of their individual micaceous varieties. Based on these data, the microheterogeneity of the Cambrian and Ordovician GPSs was established and compared with the heterogeneity in the previously studied Riphean GPS (Drits et al., 2013). The obtained Rb-Sr и K‑Ar ages for the studied Middle Cambrian and Lower Ordovician samples, as well as the earlier published dates for the Lower Cambrian samples, are "rejuvenated" relative to age limits accepted for the Cambrian and Lower Ordovician (Gradstein et al., 2020). The relationship of the Cambrian and Lower Ordovician "rejuvenated" isotopic dates and the discovered GPS heterogeneity, as well as possible reasons for its occurrence, are discussed. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Lithology & Mineral Resources is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1134/S002449022270002X
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      – Code: eng
        Text: English
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        PageCount: 19
        StartPage: 158
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      – SubjectFull: Phyllosilicates
        Type: general
      – SubjectFull: Diffraction patterns
        Type: general
      – SubjectFull: X-ray diffraction
        Type: general
      – SubjectFull: Vermiculite
        Type: general
      – SubjectFull: Smectite
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      – SubjectFull: Latvia
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      – SubjectFull: Estonia
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      – SubjectFull: Lithuania
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      – TitleFull: Globular Phyllosilicates of the Glauconite–Illite Series in the Cambrian and Ordovician Rocks of the Eastern Baltica (Northern Estonia, Western Lithuania, and Western Latvia).
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              Text: Apr2023
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