Microstructure and mechanical properties of hypoeutectic Al–6Ce–3Ni-0.7Fe (wt.%) alloy.

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Title: Microstructure and mechanical properties of hypoeutectic Al–6Ce–3Ni-0.7Fe (wt.%) alloy.
Authors: Wu, Tiffany1 (AUTHOR) TiffanyWu2024@u.northwestern.edu, Plotkowski, Alex2 (AUTHOR) plotkowskiaj@ornl.gov, Shyam, Amit2 (AUTHOR) shyama@ornl.gov, Dunand, David C.1 (AUTHOR) dunand@northwestern.edu
Source: Materials Science & Engineering: A. Jun2023, Vol. 875, pN.PAG-N.PAG. 1p.
Subjects: Hypereutectic alloys, Eutectic alloys, Microstructure, Creep (Materials), High temperatures, Thermal stability, Alloys
Abstract: A hypoeutectic, Fe-modified Al–Ce–Ni alloy (Al–6Ce–3Ni-0.7Fe, wt.%) is studied in terms of microstructure, thermal stability, ambient temperature strengthening, and creep resistance. The as-cast microstructure consists of primary Al dendrites and interdendritic binary eutectic regions (Al–Al 11 Ce 3 and/or Al–Al 9 (Fe,Ni) 2), with micron/submicron lamellar spacing, depending on the location along the height of the ingot. The cast alloy exhibits excellent coarsening resistance at 400 °C, with mostly unchanged microstructure and microhardness after 6 weeks of aging, indicating good thermal stability of Al 11 Ce 3 and Al 9 (Fe,Ni) 2. Orowan strengthening and load transfer are identified as strengthening mechanisms at ambient and elevated temperature. A high volume fraction of the intermetallic phases (providing load transfer) and relatively coarse eutectic spacing (for modest Orowan strengthening) result in a moderate as-cast microhardness of 566 ± 32 MPa. Creep resistance at 300 and 350 °C is similar to a binary Al-12.5Ce eutectic alloy (with twice the Ce content) because of two countering effects: Al–6Ce–3Ni-0.7Fe shows a higher volume fraction of strengthening intermetallic phases, but it also exhibits a large fraction of primary Al dendrites which weaken the alloy. By contrast, the alloy, when laser-remelted at the surface, has a fully eutectic microstructure without primary aluminum dendrites achieved by high undercooling on solidification, with a refined network of eutectic phases that doubles the microhardness as compared to the cast alloy. Whereas coarsening is faster due to the shorter diffusion distances between the eutectic phases, hardness remains ∼30% higher than the as-cast alloy after ∼6 weeks aging at 400 °C. [ABSTRACT FROM AUTHOR]
Copyright of Materials Science & Engineering: A is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Microstructure and mechanical properties of hypoeutectic Al–6Ce–3Ni-0.7Fe (wt.%) alloy.
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  Data: <searchLink fieldCode="AR" term="%22Wu%2C+Tiffany%22">Wu, Tiffany</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> TiffanyWu2024@u.northwestern.edu</i><br /><searchLink fieldCode="AR" term="%22Plotkowski%2C+Alex%22">Plotkowski, Alex</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> plotkowskiaj@ornl.gov</i><br /><searchLink fieldCode="AR" term="%22Shyam%2C+Amit%22">Shyam, Amit</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> shyama@ornl.gov</i><br /><searchLink fieldCode="AR" term="%22Dunand%2C+David+C%2E%22">Dunand, David C.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> dunand@northwestern.edu</i>
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  Data: <searchLink fieldCode="JN" term="%22Materials+Science+%26+Engineering%3A+A%22">Materials Science & Engineering: A</searchLink>. Jun2023, Vol. 875, pN.PAG-N.PAG. 1p.
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  Data: <searchLink fieldCode="DE" term="%22Hypereutectic+alloys%22">Hypereutectic alloys</searchLink><br /><searchLink fieldCode="DE" term="%22Eutectic+alloys%22">Eutectic alloys</searchLink><br /><searchLink fieldCode="DE" term="%22Microstructure%22">Microstructure</searchLink><br /><searchLink fieldCode="DE" term="%22Creep+%28Materials%29%22">Creep (Materials)</searchLink><br /><searchLink fieldCode="DE" term="%22High+temperatures%22">High temperatures</searchLink><br /><searchLink fieldCode="DE" term="%22Thermal+stability%22">Thermal stability</searchLink><br /><searchLink fieldCode="DE" term="%22Alloys%22">Alloys</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: A hypoeutectic, Fe-modified Al–Ce–Ni alloy (Al–6Ce–3Ni-0.7Fe, wt.%) is studied in terms of microstructure, thermal stability, ambient temperature strengthening, and creep resistance. The as-cast microstructure consists of primary Al dendrites and interdendritic binary eutectic regions (Al–Al 11 Ce 3 and/or Al–Al 9 (Fe,Ni) 2), with micron/submicron lamellar spacing, depending on the location along the height of the ingot. The cast alloy exhibits excellent coarsening resistance at 400 °C, with mostly unchanged microstructure and microhardness after 6 weeks of aging, indicating good thermal stability of Al 11 Ce 3 and Al 9 (Fe,Ni) 2. Orowan strengthening and load transfer are identified as strengthening mechanisms at ambient and elevated temperature. A high volume fraction of the intermetallic phases (providing load transfer) and relatively coarse eutectic spacing (for modest Orowan strengthening) result in a moderate as-cast microhardness of 566 ± 32 MPa. Creep resistance at 300 and 350 °C is similar to a binary Al-12.5Ce eutectic alloy (with twice the Ce content) because of two countering effects: Al–6Ce–3Ni-0.7Fe shows a higher volume fraction of strengthening intermetallic phases, but it also exhibits a large fraction of primary Al dendrites which weaken the alloy. By contrast, the alloy, when laser-remelted at the surface, has a fully eutectic microstructure without primary aluminum dendrites achieved by high undercooling on solidification, with a refined network of eutectic phases that doubles the microhardness as compared to the cast alloy. Whereas coarsening is faster due to the shorter diffusion distances between the eutectic phases, hardness remains ∼30% higher than the as-cast alloy after ∼6 weeks aging at 400 °C. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Materials Science & Engineering: A is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.msea.2023.145072
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      – Code: eng
        Text: English
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        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Hypereutectic alloys
        Type: general
      – SubjectFull: Eutectic alloys
        Type: general
      – SubjectFull: Microstructure
        Type: general
      – SubjectFull: Creep (Materials)
        Type: general
      – SubjectFull: High temperatures
        Type: general
      – SubjectFull: Thermal stability
        Type: general
      – SubjectFull: Alloys
        Type: general
    Titles:
      – TitleFull: Microstructure and mechanical properties of hypoeutectic Al–6Ce–3Ni-0.7Fe (wt.%) alloy.
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            NameFull: Wu, Tiffany
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            NameFull: Plotkowski, Alex
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            NameFull: Shyam, Amit
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            NameFull: Dunand, David C.
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            – D: 06
              M: 06
              Text: Jun2023
              Type: published
              Y: 2023
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              Value: 875
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