The density and pressure of helium nano-bubbles encapsulated in silicon.
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| Title: | The density and pressure of helium nano-bubbles encapsulated in silicon. |
|---|---|
| Authors: | Pyper, N. C.1 (AUTHOR), Thom, A. J. W.1 (AUTHOR), Whelan, Colm T.2 (AUTHOR) cwhelan@odu.edu |
| Source: | Proceedings of the Royal Society A: Mathematical, Physical & Engineering Sciences. Jul2023, Vol. 479 Issue 2275, p1-14. 14p. |
| Subjects: | Transmission electron microscopes, Electronic excitation, Helium, Scanning electron microscopes, Silicon, Equations of state, Helium atom, Electron density |
| Abstract: | The 1s2→1s2p(1P) excitation in compressed helium atoms in either the bulk material or encapsulated in a bubble is shifted to energies higher than in the free atom. For bulk helium, energy shifts predicted from non-empirical electronic structure computations are in excellent agreement with experimentally determined values. However, there are significant discrepancies both between the results of experiments on different bubbles and between these and the well established descriptions of the bulk. A critique is presented of previous analyses of earlier scanning transmission electron microscope measurements that are untrustworthy because the density dependence of the electron impact excitation cross section was neglected. Experimental electron energy loss data from an earlier study of helium encapsulated in silicon are reanalysed and it is shown that the properties of the helium in these bubbles do not differ significantly from those in the bulk, thereby enabling the densities in the bubbles to be determined. These enable bubble pressures to be deduced from a well established experimentally derived equation of state. It is shown that the errors of up to 80% in the incorrectly determined densities are greatly magnified in the predicted pressures which can be too large by factors of over seven. [ABSTRACT FROM AUTHOR] |
| Copyright of Proceedings of the Royal Society A: Mathematical, Physical & Engineering Sciences is the property of Royal Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 169731194 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: The density and pressure of helium nano-bubbles encapsulated in silicon. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Pyper%2C+N%2E+C%2E%22">Pyper, N. C.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Thom%2C+A%2E+J%2E+W%2E%22">Thom, A. J. W.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Whelan%2C+Colm+T%2E%22">Whelan, Colm T.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> cwhelan@odu.edu</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Proceedings+of+the+Royal+Society+A%3A+Mathematical%2C+Physical+%26+Engineering+Sciences%22">Proceedings of the Royal Society A: Mathematical, Physical & Engineering Sciences</searchLink>. Jul2023, Vol. 479 Issue 2275, p1-14. 14p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Transmission+electron+microscopes%22">Transmission electron microscopes</searchLink><br /><searchLink fieldCode="DE" term="%22Electronic+excitation%22">Electronic excitation</searchLink><br /><searchLink fieldCode="DE" term="%22Helium%22">Helium</searchLink><br /><searchLink fieldCode="DE" term="%22Scanning+electron+microscopes%22">Scanning electron microscopes</searchLink><br /><searchLink fieldCode="DE" term="%22Silicon%22">Silicon</searchLink><br /><searchLink fieldCode="DE" term="%22Equations+of+state%22">Equations of state</searchLink><br /><searchLink fieldCode="DE" term="%22Helium+atom%22">Helium atom</searchLink><br /><searchLink fieldCode="DE" term="%22Electron+density%22">Electron density</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: The 1s2→1s2p(1P) excitation in compressed helium atoms in either the bulk material or encapsulated in a bubble is shifted to energies higher than in the free atom. For bulk helium, energy shifts predicted from non-empirical electronic structure computations are in excellent agreement with experimentally determined values. However, there are significant discrepancies both between the results of experiments on different bubbles and between these and the well established descriptions of the bulk. A critique is presented of previous analyses of earlier scanning transmission electron microscope measurements that are untrustworthy because the density dependence of the electron impact excitation cross section was neglected. Experimental electron energy loss data from an earlier study of helium encapsulated in silicon are reanalysed and it is shown that the properties of the helium in these bubbles do not differ significantly from those in the bulk, thereby enabling the densities in the bubbles to be determined. These enable bubble pressures to be deduced from a well established experimentally derived equation of state. It is shown that the errors of up to 80% in the incorrectly determined densities are greatly magnified in the predicted pressures which can be too large by factors of over seven. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Proceedings of the Royal Society A: Mathematical, Physical & Engineering Sciences is the property of Royal Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1098/rspa.2023.0081 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 14 StartPage: 1 Subjects: – SubjectFull: Transmission electron microscopes Type: general – SubjectFull: Electronic excitation Type: general – SubjectFull: Helium Type: general – SubjectFull: Scanning electron microscopes Type: general – SubjectFull: Silicon Type: general – SubjectFull: Equations of state Type: general – SubjectFull: Helium atom Type: general – SubjectFull: Electron density Type: general Titles: – TitleFull: The density and pressure of helium nano-bubbles encapsulated in silicon. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Pyper, N. C. – PersonEntity: Name: NameFull: Thom, A. J. W. – PersonEntity: Name: NameFull: Whelan, Colm T. IsPartOfRelationships: – BibEntity: Dates: – D: 26 M: 07 Text: Jul2023 Type: published Y: 2023 Identifiers: – Type: issn-print Value: 13645021 Numbering: – Type: volume Value: 479 – Type: issue Value: 2275 Titles: – TitleFull: Proceedings of the Royal Society A: Mathematical, Physical & Engineering Sciences Type: main |
| ResultId | 1 |
