Optimizations of performance of cellulose acetate modified by ZnSnO3/ZnO nanocomposites: electrical, dynamic mechanical analysis, and antibacterial activity.

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Title: Optimizations of performance of cellulose acetate modified by ZnSnO3/ZnO nanocomposites: electrical, dynamic mechanical analysis, and antibacterial activity.
Authors: Hezma, A.M.1 (AUTHOR), Labeeb, Ahmad M.2,3 (AUTHOR), El Desouky, Fawzy G.1,4 (AUTHOR) fa.goda@nrc.sci.eg
Source: Colloids & Surfaces A: Physicochemical & Engineering Aspects. Nov2023:Part B, Vol. 676, pN.PAG-N.PAG. 1p.
Subjects: Dynamic mechanical analysis, Cellulose acetate, Antibacterial agents, Nanocomposite materials, Escherichia coli, Composite materials
Abstract: In this work, ZnSnO 3 /ZnO/cellulose acetate nanocomposites have been efficiently fabricated by simple wet chemical co-precipitation and drop casting techniques. The study characterized the nanocomposite's microstructure, morphology, dielectric and impedance spectra, dynamic mechanical analyses, and antibacterial performance. The XRD results reveal the production of composite materials, including well-split materials of nanocrystalline nature, from both constitutive organic and non-organic materials. With the addition of nanoparticles to the cellulose acetate, the real components of electrical conductivity, permittivity, and impedance behaviors exhibit improved performances as a function of frequency dependence. The results of the dynamic mechanical analysis (DMA) showed that the nanocomposite has a significant impact on the DMA parameters at Tg (storage modulus, loss modulus, loss tangent, stiffness, and viscosity modulus) by enhancing interfacial adhesion and optimizing the stress transition demand and power dissipation between the CAmatrix and nanoparticles. Moreover, the antibacterial activity of nanocomposites films is more effective against E. coli (G-ve) bacteria with a relatively wide diameter than against S.aureus (G+ve) bacteria. This ZS/ZO/CA matrix, which is supported by ZS/ZO nanostructures, is intended to be structural mechanical elements in structural engineering, electrochemical solid state systems, and antibacterial. [Display omitted] • A simple, cost - effective, scalable, and effective approach for fabricating ZS/ZO/CA nanocomposites has been developed. • AC conductivity of ZS/ZO/CA nanocomposites, lower filler loadings (0.04, 0.08, and 0.12) exhibited better conductivity than CA. • The addition of CA and ZS/ZO nanoparticles increases internal friction and create excess power dissipation, which improves mechanical and dynamic mechanical characteristics when compared to unaltered CA. • The antibacterial activity of nanocomposites films is more effective against E. coli (G -ve) bacteria with a relatively wide diameter than against S. aureus (G +ve) bacteria. [ABSTRACT FROM AUTHOR]
Copyright of Colloids & Surfaces A: Physicochemical & Engineering Aspects is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Optimizations of performance of cellulose acetate modified by ZnSnO3/ZnO nanocomposites: electrical, dynamic mechanical analysis, and antibacterial activity.
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  Data: <searchLink fieldCode="JN" term="%22Colloids+%26+Surfaces+A%3A+Physicochemical+%26+Engineering+Aspects%22">Colloids & Surfaces A: Physicochemical & Engineering Aspects</searchLink>. Nov2023:Part B, Vol. 676, pN.PAG-N.PAG. 1p.
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  Data: <searchLink fieldCode="DE" term="%22Dynamic+mechanical+analysis%22">Dynamic mechanical analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Cellulose+acetate%22">Cellulose acetate</searchLink><br /><searchLink fieldCode="DE" term="%22Antibacterial+agents%22">Antibacterial agents</searchLink><br /><searchLink fieldCode="DE" term="%22Nanocomposite+materials%22">Nanocomposite materials</searchLink><br /><searchLink fieldCode="DE" term="%22Escherichia+coli%22">Escherichia coli</searchLink><br /><searchLink fieldCode="DE" term="%22Composite+materials%22">Composite materials</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: In this work, ZnSnO 3 /ZnO/cellulose acetate nanocomposites have been efficiently fabricated by simple wet chemical co-precipitation and drop casting techniques. The study characterized the nanocomposite's microstructure, morphology, dielectric and impedance spectra, dynamic mechanical analyses, and antibacterial performance. The XRD results reveal the production of composite materials, including well-split materials of nanocrystalline nature, from both constitutive organic and non-organic materials. With the addition of nanoparticles to the cellulose acetate, the real components of electrical conductivity, permittivity, and impedance behaviors exhibit improved performances as a function of frequency dependence. The results of the dynamic mechanical analysis (DMA) showed that the nanocomposite has a significant impact on the DMA parameters at Tg (storage modulus, loss modulus, loss tangent, stiffness, and viscosity modulus) by enhancing interfacial adhesion and optimizing the stress transition demand and power dissipation between the CAmatrix and nanoparticles. Moreover, the antibacterial activity of nanocomposites films is more effective against E. coli (G-ve) bacteria with a relatively wide diameter than against S.aureus (G+ve) bacteria. This ZS/ZO/CA matrix, which is supported by ZS/ZO nanostructures, is intended to be structural mechanical elements in structural engineering, electrochemical solid state systems, and antibacterial. [Display omitted] • A simple, cost - effective, scalable, and effective approach for fabricating ZS/ZO/CA nanocomposites has been developed. • AC conductivity of ZS/ZO/CA nanocomposites, lower filler loadings (0.04, 0.08, and 0.12) exhibited better conductivity than CA. • The addition of CA and ZS/ZO nanoparticles increases internal friction and create excess power dissipation, which improves mechanical and dynamic mechanical characteristics when compared to unaltered CA. • The antibacterial activity of nanocomposites films is more effective against E. coli (G -ve) bacteria with a relatively wide diameter than against S. aureus (G +ve) bacteria. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Colloids & Surfaces A: Physicochemical & Engineering Aspects is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.colsurfa.2023.132110
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      – Code: eng
        Text: English
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        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Dynamic mechanical analysis
        Type: general
      – SubjectFull: Cellulose acetate
        Type: general
      – SubjectFull: Antibacterial agents
        Type: general
      – SubjectFull: Nanocomposite materials
        Type: general
      – SubjectFull: Escherichia coli
        Type: general
      – SubjectFull: Composite materials
        Type: general
    Titles:
      – TitleFull: Optimizations of performance of cellulose acetate modified by ZnSnO3/ZnO nanocomposites: electrical, dynamic mechanical analysis, and antibacterial activity.
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            – D: 05
              M: 11
              Text: Nov2023:Part B
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              Y: 2023
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