Effective adsorption of Fuchsine dye on FeZnOAC: kinetic, isotherm, double-layer modelling and reusability study.
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| Title: | Effective adsorption of Fuchsine dye on FeZnOAC: kinetic, isotherm, double-layer modelling and reusability study. |
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| Authors: | Fegade, Umesh1 (AUTHOR) umeshfegade@gmail.com, Inamuddin2 (AUTHOR), Altalhi, Tariq3 (AUTHOR), Ahamed, Mohd Imran4 (AUTHOR), Kanchi, Suvardhan5,6 (AUTHOR) |
| Source: | International Journal of Environmental Analytical Chemistry. Dec2023, Vol. 103 Issue 16, p3954-3970. 17p. |
| Subjects: | Adsorption (Chemistry), Activated carbon, Dyes & dyeing, Sewage, Adsorption capacity, Statistical physics, Lead removal (Sewage purification) |
| Abstract: | The FeZnO (iron zinc bimetallic oxide) was synthesised using the ultrasound-assisted method and further converted into FeZnOAC (iron zinc bimetallic oxide-doped activated carbon) by treating it with activated carbon. As developed FeZnOAC is effectively used for the adsorption of Fuchsine dye from an aqueous dye solution. A 200 mg of FeZnOAC was sufficient for the rapid removal of Fuchsine (>97.64%) dye. The kinetic adsorption data is well fitted with a pseudo-second-order model. The Langmuir isothermal model shows a high regression coefficient (R2) than the Freundlich with a Qmax of 333.33 mg g−1. The dye adsorption at varying temperatures (i.e. 298–318 K) was based on a multi-layered statistical physics model. The n value (n < 0.5) obtained from the model indicates that the Fuchsine dye adsorbed on the surface of FeZnOAC is parallel adsorption. It shows that the dye molecules' adsorptive orientations are dependent on the temperature and nature of the system. The FeZnOAC is proven to be a potential adsorbent for the removal of Fuchsine due to the availability of more adsorption sites. Interestingly, FeZnOAC is used for regeneration studies up to five cycles with a maximum adsorption capacity of 97.4%. The as-synthesised FeZnOAC has been successfully applied to remove Fuchsine dye from industrial wastewater, resulting in an alternative candidate for commercialisation. [ABSTRACT FROM AUTHOR] |
| Copyright of International Journal of Environmental Analytical Chemistry is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 172309636 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Effective adsorption of Fuchsine dye on FeZnOAC: kinetic, isotherm, double-layer modelling and reusability study. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Fegade%2C+Umesh%22">Fegade, Umesh</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> umeshfegade@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Inamuddin%22">Inamuddin</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Altalhi%2C+Tariq%22">Altalhi, Tariq</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ahamed%2C+Mohd+Imran%22">Ahamed, Mohd Imran</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Kanchi%2C+Suvardhan%22">Kanchi, Suvardhan</searchLink><relatesTo>5,6</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22International+Journal+of+Environmental+Analytical+Chemistry%22">International Journal of Environmental Analytical Chemistry</searchLink>. Dec2023, Vol. 103 Issue 16, p3954-3970. 17p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Adsorption+%28Chemistry%29%22">Adsorption (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Activated+carbon%22">Activated carbon</searchLink><br /><searchLink fieldCode="DE" term="%22Dyes+%26+dyeing%22">Dyes & dyeing</searchLink><br /><searchLink fieldCode="DE" term="%22Sewage%22">Sewage</searchLink><br /><searchLink fieldCode="DE" term="%22Adsorption+capacity%22">Adsorption capacity</searchLink><br /><searchLink fieldCode="DE" term="%22Statistical+physics%22">Statistical physics</searchLink><br /><searchLink fieldCode="DE" term="%22Lead+removal+%28Sewage+purification%29%22">Lead removal (Sewage purification)</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: The FeZnO (iron zinc bimetallic oxide) was synthesised using the ultrasound-assisted method and further converted into FeZnOAC (iron zinc bimetallic oxide-doped activated carbon) by treating it with activated carbon. As developed FeZnOAC is effectively used for the adsorption of Fuchsine dye from an aqueous dye solution. A 200 mg of FeZnOAC was sufficient for the rapid removal of Fuchsine (>97.64%) dye. The kinetic adsorption data is well fitted with a pseudo-second-order model. The Langmuir isothermal model shows a high regression coefficient (R2) than the Freundlich with a Qmax of 333.33 mg g−1. The dye adsorption at varying temperatures (i.e. 298–318 K) was based on a multi-layered statistical physics model. The n value (n < 0.5) obtained from the model indicates that the Fuchsine dye adsorbed on the surface of FeZnOAC is parallel adsorption. It shows that the dye molecules' adsorptive orientations are dependent on the temperature and nature of the system. The FeZnOAC is proven to be a potential adsorbent for the removal of Fuchsine due to the availability of more adsorption sites. Interestingly, FeZnOAC is used for regeneration studies up to five cycles with a maximum adsorption capacity of 97.4%. The as-synthesised FeZnOAC has been successfully applied to remove Fuchsine dye from industrial wastewater, resulting in an alternative candidate for commercialisation. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of International Journal of Environmental Analytical Chemistry is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1080/03067319.2021.1917559 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 17 StartPage: 3954 Subjects: – SubjectFull: Adsorption (Chemistry) Type: general – SubjectFull: Activated carbon Type: general – SubjectFull: Dyes & dyeing Type: general – SubjectFull: Sewage Type: general – SubjectFull: Adsorption capacity Type: general – SubjectFull: Statistical physics Type: general – SubjectFull: Lead removal (Sewage purification) Type: general Titles: – TitleFull: Effective adsorption of Fuchsine dye on FeZnOAC: kinetic, isotherm, double-layer modelling and reusability study. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Fegade, Umesh – PersonEntity: Name: NameFull: Inamuddin – PersonEntity: Name: NameFull: Altalhi, Tariq – PersonEntity: Name: NameFull: Ahamed, Mohd Imran – PersonEntity: Name: NameFull: Kanchi, Suvardhan IsPartOfRelationships: – BibEntity: Dates: – D: 10 M: 12 Text: Dec2023 Type: published Y: 2023 Identifiers: – Type: issn-print Value: 03067319 Numbering: – Type: volume Value: 103 – Type: issue Value: 16 Titles: – TitleFull: International Journal of Environmental Analytical Chemistry Type: main |
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