Tailoring the optical properties (linear and nonlinear) of triple blended polymers via reinforcement of interchangeable proportions of mixed (SnO2 and NiO) nanofillers for promising applications.
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| Title: | Tailoring the optical properties (linear and nonlinear) of triple blended polymers via reinforcement of interchangeable proportions of mixed (SnO |
|---|---|
| Authors: | Abdel-Kader, Mohamed H.1,2 (AUTHOR) mhkader75@yahoo.com, Alhazime, Ali A.1 (AUTHOR), Mohamed, Mohamed Bakr1,2 (AUTHOR) |
| Source: | Optical & Quantum Electronics. Nov2023, Vol. 55 Issue 11, p1-21. 21p. |
| Subjects: | Optical properties, Optical conductivity, Field emission, Refractive index, Polymers, Sol-gel processes |
| Abstract: | The recognition and characterization of semi-biopolymeric CMC/PVP/PEG blends through the incorporation of high purity NiO and SnO2 nanofillers with different interchangeable proportions have been investigated. The sol–gel technique was used for preparing NiO and SnO2 nanofillers, while undoped and doped blends were prepared by the casting technique. A homogeneous distribution of the nanofillers within CMC/PVP/PEG blends was assessed by scanning electron microscopy (SEM) and field emission mapping. The structure of the resulting undoped and doped blends were studied by x-ray diffraction (XRD). The FTIR spectroscopic technique was used to evaluate the effect of incorporated nanofillers on the blend's structure. The UV–Vis spectrophotometer was used to study the optical properties of the prepared blends. Calculations were based on the well-known single oscillator model. The transparency of the resulting samples was reduced by 30% due to the 100% NiO nanoparticles. The energy gap (Eg) values were determined using two different approaches. A gradual decrease in Eg values from 4.8 to 4 eV with the nanoparticle doping sequence from 100% NiO to 100% SnO2 with a step (± 25%), has been noticed. The effect of doping proportions on other optical parameters such as: extinction coefficient, refractive index, real and imaginary dielectric parameters, optical conductivity, VELF, and SELF functions has been investigated. The third-order nonlinear susceptibility χ(3) and the nonlinear refractive index (n2) were calculated based on the linear optical parameters. The improvement in the linear and nonlinear parameters suggested its usage as a promising candidates for future optoelectronics manufacturing. [ABSTRACT FROM AUTHOR] |
| Copyright of Optical & Quantum Electronics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
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| Header | DbId: egs DbLabel: Engineering Source An: 172361427 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Tailoring the optical properties (linear and nonlinear) of triple blended polymers via reinforcement of interchangeable proportions of mixed (SnO<subscript>2</subscript> and NiO) nanofillers for promising applications. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Abdel-Kader%2C+Mohamed+H%2E%22">Abdel-Kader, Mohamed H.</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> mhkader75@yahoo.com</i><br /><searchLink fieldCode="AR" term="%22Alhazime%2C+Ali+A%2E%22">Alhazime, Ali A.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Mohamed%2C+Mohamed+Bakr%22">Mohamed, Mohamed Bakr</searchLink><relatesTo>1,2</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Optical+%26+Quantum+Electronics%22">Optical & Quantum Electronics</searchLink>. Nov2023, Vol. 55 Issue 11, p1-21. 21p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Optical+properties%22">Optical properties</searchLink><br /><searchLink fieldCode="DE" term="%22Optical+conductivity%22">Optical conductivity</searchLink><br /><searchLink fieldCode="DE" term="%22Field+emission%22">Field emission</searchLink><br /><searchLink fieldCode="DE" term="%22Refractive+index%22">Refractive index</searchLink><br /><searchLink fieldCode="DE" term="%22Polymers%22">Polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Sol-gel+processes%22">Sol-gel processes</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: The recognition and characterization of semi-biopolymeric CMC/PVP/PEG blends through the incorporation of high purity NiO and SnO2 nanofillers with different interchangeable proportions have been investigated. The sol–gel technique was used for preparing NiO and SnO2 nanofillers, while undoped and doped blends were prepared by the casting technique. A homogeneous distribution of the nanofillers within CMC/PVP/PEG blends was assessed by scanning electron microscopy (SEM) and field emission mapping. The structure of the resulting undoped and doped blends were studied by x-ray diffraction (XRD). The FTIR spectroscopic technique was used to evaluate the effect of incorporated nanofillers on the blend's structure. The UV–Vis spectrophotometer was used to study the optical properties of the prepared blends. Calculations were based on the well-known single oscillator model. The transparency of the resulting samples was reduced by 30% due to the 100% NiO nanoparticles. The energy gap (Eg) values were determined using two different approaches. A gradual decrease in Eg values from 4.8 to 4 eV with the nanoparticle doping sequence from 100% NiO to 100% SnO2 with a step (± 25%), has been noticed. The effect of doping proportions on other optical parameters such as: extinction coefficient, refractive index, real and imaginary dielectric parameters, optical conductivity, VELF, and SELF functions has been investigated. The third-order nonlinear susceptibility χ(3) and the nonlinear refractive index (n2) were calculated based on the linear optical parameters. The improvement in the linear and nonlinear parameters suggested its usage as a promising candidates for future optoelectronics manufacturing. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Optical & Quantum Electronics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1007/s11082-023-05266-x Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 21 StartPage: 1 Subjects: – SubjectFull: Optical properties Type: general – SubjectFull: Optical conductivity Type: general – SubjectFull: Field emission Type: general – SubjectFull: Refractive index Type: general – SubjectFull: Polymers Type: general – SubjectFull: Sol-gel processes Type: general Titles: – TitleFull: Tailoring the optical properties (linear and nonlinear) of triple blended polymers via reinforcement of interchangeable proportions of mixed (SnO2 and NiO) nanofillers for promising applications. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Abdel-Kader, Mohamed H. – PersonEntity: Name: NameFull: Alhazime, Ali A. – PersonEntity: Name: NameFull: Mohamed, Mohamed Bakr IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 11 Text: Nov2023 Type: published Y: 2023 Identifiers: – Type: issn-print Value: 03068919 Numbering: – Type: volume Value: 55 – Type: issue Value: 11 Titles: – TitleFull: Optical & Quantum Electronics Type: main |
| ResultId | 1 |
