Production of glass-ceramics from MSW-fly ash and Dexing copper mine-tailing: Crystallization kinetics, structure, properties and immobilization of heavy metals.

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Title: Production of glass-ceramics from MSW-fly ash and Dexing copper mine-tailing: Crystallization kinetics, structure, properties and immobilization of heavy metals.
Authors: Liu, Jianlei1 (AUTHOR), Peng, Huiling1 (AUTHOR), Peng, Huanan1 (AUTHOR), Zheng, Jie1 (AUTHOR), Zhang, Zhou1,2 (AUTHOR), Ye, Hongde1 (AUTHOR), Wang, Hongqian1 (AUTHOR), Yu, Zhumei1 (AUTHOR), Zhu, Xianhong1 (AUTHOR) XianhongZhu@163.com, Wang, Qikun1,3 (AUTHOR) 19B309004@stu.hit.edu.cn
Source: Ceramics International. Nov2023:Part A, Vol. 49 Issue 22, p35428-35437. 10p.
Subjects: Glass-ceramics, Copper, Heavy metals, Crystallization kinetics, Therapeutic immobilization, Vickers hardness, Chemical stability
Abstract: To reduce the environmental pollution from MSW-fly ash and Dexing copper mine-tailing and realize their maximum utilization, this research used them to synthesize novel eco-friendly glass-ceramics. Effects of different nucleation-crystallization temperatures on the crystal evolution, microstructure, properties, leaching behavior of heavy metals were discussed. The findings indicate that the crystallization activation energy E is 381 kJ/mol, and the crystallization mechanism is two-dimensional crystallization controlled by diffusion with an increasing nucleation rate. The difference in the nucleation-crystallization temperature will affect the precipitation and growth of crystal (CaAl 2 Si 2 O 8) in this glassy system, and further affect the microstructure and properties of the prepared glass-ceramics. Furthermore, because the glass-ceramics is the combination of glass and crystal, an obvious immobilization effect for heavy metals Fe, Mn and Cr can be obtained in our glass-ceramics. Apart from the high immobilization efficiencies for heavy metals, our glass-ceramics also show low density (2.715–2.761 g/cm3) and water absorption (0.026–0.045%), high Vickers hardness (5.72–6.39 GPa), good chemical stability (k H2SO4 : 3.68–28.72%, k NaOH : 0.01–0.96%), which confirms the potential and feasibility of the MSW-fly ash-Dexing copper mine-tailing-derived glass-ceramics as building decoration material. [ABSTRACT FROM AUTHOR]
Copyright of Ceramics International is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Production of glass-ceramics from MSW-fly ash and Dexing copper mine-tailing: Crystallization kinetics, structure, properties and immobilization of heavy metals.
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  Label: Authors
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  Data: <searchLink fieldCode="AR" term="%22Liu%2C+Jianlei%22">Liu, Jianlei</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Peng%2C+Huiling%22">Peng, Huiling</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Peng%2C+Huanan%22">Peng, Huanan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zheng%2C+Jie%22">Zheng, Jie</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhang%2C+Zhou%22">Zhang, Zhou</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ye%2C+Hongde%22">Ye, Hongde</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Hongqian%22">Wang, Hongqian</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yu%2C+Zhumei%22">Yu, Zhumei</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhu%2C+Xianhong%22">Zhu, Xianhong</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> XianhongZhu@163.com</i><br /><searchLink fieldCode="AR" term="%22Wang%2C+Qikun%22">Wang, Qikun</searchLink><relatesTo>1,3</relatesTo> (AUTHOR)<i> 19B309004@stu.hit.edu.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Ceramics+International%22">Ceramics International</searchLink>. Nov2023:Part A, Vol. 49 Issue 22, p35428-35437. 10p.
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  Data: <searchLink fieldCode="DE" term="%22Glass-ceramics%22">Glass-ceramics</searchLink><br /><searchLink fieldCode="DE" term="%22Copper%22">Copper</searchLink><br /><searchLink fieldCode="DE" term="%22Heavy+metals%22">Heavy metals</searchLink><br /><searchLink fieldCode="DE" term="%22Crystallization+kinetics%22">Crystallization kinetics</searchLink><br /><searchLink fieldCode="DE" term="%22Therapeutic+immobilization%22">Therapeutic immobilization</searchLink><br /><searchLink fieldCode="DE" term="%22Vickers+hardness%22">Vickers hardness</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+stability%22">Chemical stability</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: To reduce the environmental pollution from MSW-fly ash and Dexing copper mine-tailing and realize their maximum utilization, this research used them to synthesize novel eco-friendly glass-ceramics. Effects of different nucleation-crystallization temperatures on the crystal evolution, microstructure, properties, leaching behavior of heavy metals were discussed. The findings indicate that the crystallization activation energy E is 381 kJ/mol, and the crystallization mechanism is two-dimensional crystallization controlled by diffusion with an increasing nucleation rate. The difference in the nucleation-crystallization temperature will affect the precipitation and growth of crystal (CaAl 2 Si 2 O 8) in this glassy system, and further affect the microstructure and properties of the prepared glass-ceramics. Furthermore, because the glass-ceramics is the combination of glass and crystal, an obvious immobilization effect for heavy metals Fe, Mn and Cr can be obtained in our glass-ceramics. Apart from the high immobilization efficiencies for heavy metals, our glass-ceramics also show low density (2.715–2.761 g/cm3) and water absorption (0.026–0.045%), high Vickers hardness (5.72–6.39 GPa), good chemical stability (k H2SO4 : 3.68–28.72%, k NaOH : 0.01–0.96%), which confirms the potential and feasibility of the MSW-fly ash-Dexing copper mine-tailing-derived glass-ceramics as building decoration material. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Ceramics International is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.ceramint.2023.08.219
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      – Code: eng
        Text: English
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        PageCount: 10
        StartPage: 35428
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      – SubjectFull: Glass-ceramics
        Type: general
      – SubjectFull: Copper
        Type: general
      – SubjectFull: Heavy metals
        Type: general
      – SubjectFull: Crystallization kinetics
        Type: general
      – SubjectFull: Therapeutic immobilization
        Type: general
      – SubjectFull: Vickers hardness
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      – SubjectFull: Chemical stability
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              Text: Nov2023:Part A
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              Y: 2023
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