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Photocatalyst-Free, Visible-Light-Mediated C–H Perfluoroalkylation of Quinazolin-4(3 H)-ones with perfluoroalkyl Iodides.

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Title: Photocatalyst-Free, Visible-Light-Mediated C–H Perfluoroalkylation of Quinazolin-4(3 H)-ones with perfluoroalkyl Iodides.
Authors: Delouche, Thomas1 (AUTHOR), Gadiry-Diallo, Abdoul1 (AUTHOR), Besson, Thierry1 (AUTHOR), Ogoshi, Sensuke2 (AUTHOR), Fruit, Corinne1 (AUTHOR) corinne.fruit@univ-rouen.fr
Source: Synthesis. Nov2023, Vol. 55 Issue 21, p3670-3684. 15p.
Subjects: Fluoroalkyl compounds, Normal-phase chromatography, Iodides, Materials science, Thin layer chromatography
Abstract: SP 1 sp H NMR (300 MHz, acetone- I d i SB 6 sb ): = 11.66 (s, 1 H, H SB N-H sb ), 8.39 (d, I J i = 8.2 Hz, 1 H, H SB 7 sb ), 8.35 (d, I J i = 2.6 Hz, 1 H, H SB 2 sb ), 8.12 (d, I J i = 8.3 Hz, 1 H, H SB 6 sb ). SP 1 sp H NMR (300 MHz, acetone- I d i SB 6 sb ): = 11.49 (s, 1 H, H SB N-H sb ), 8.78 (d, I J i = 2.3 Hz, 1 H, H SB 5 sb ), 8.46 (d, I J i = 2.3 Hz, 1 H, H SB 7 sb ), 8.30 (d, I J i = 2.8 Hz, 1 H, H SB 2 sb ), 8.17-8.07 (m, 2 H, H SB 10or11 sb ), 8.03-7.94 (m, 2 H, H SB 10or11 sb ). SP 13 sp C NMR (75 MHz, acetone- I d i SB 6 sb ): = 157.11 (d, I J i = 15.3 Hz, C SB 4 sb ), 155.38 (dd, I J i = 263.6, 4.4 Hz, Cq), 150.58 (dd, I J i = 253.0, 4.6 Hz, Cq), 148.32 (Cq), 147.54 (C SB 2 sb ), 121.72 (Cq), 120.75 (d, I J i = 3.6 Hz, Cq), 120.03 (Cq), 120.0-104.00 (m, C SB CF sb ). SP 13 sp C NMR (75 MHz, acetone- I d i SB 6 sb ): = 159.44 (C SB 4 sb ), 155.77 (dd, I J i = 266.4, 19.7 Hz, Cq), 150.08 (dd, I J i = 250.8, 15.1 Hz, Cq), 147.14 (C SB 2 sb ), 146.85-146.21 (m, Cq), 122.57-121.48 (m, Cq), 119.05 (dd, I J i = 18.9, 3.4 Hz, C SB 5 sb ), 118.93-114.64 (m, Cq), 119.00-105.00 (m, C SB CF sb ). SP 13 sp C NMR (75 MHz, acetone- I d i SB 6 sb ): = 159.91 (dt, I J i = 252.3, 5.2 Hz, C SB 6 sb ), 157.63 (d, I J i = 3.8 Hz, C SB 4 sb ), 147.42 (Cq), 146.79 (C SB 2 sb ), 133.10 (d, I J i = 7.3 Hz, Cq), 126.29-125.29 (m, C SB 5,7,8 sb ),, 123.00-105.00 (m, C SB CF sb ). [Extracted from the article]
Copyright of Synthesis is the property of Georg Thieme Verlag Stuttgart and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 173036972
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  Label: Title
  Group: Ti
  Data: Photocatalyst-Free, Visible-Light-Mediated C–H Perfluoroalkylation of Quinazolin-4(3 H)-ones with perfluoroalkyl Iodides.
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  Data: <searchLink fieldCode="AR" term="%22Delouche%2C+Thomas%22">Delouche, Thomas</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Gadiry-Diallo%2C+Abdoul%22">Gadiry-Diallo, Abdoul</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Besson%2C+Thierry%22">Besson, Thierry</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ogoshi%2C+Sensuke%22">Ogoshi, Sensuke</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Fruit%2C+Corinne%22">Fruit, Corinne</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> corinne.fruit@univ-rouen.fr</i>
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  Data: <searchLink fieldCode="JN" term="%22Synthesis%22">Synthesis</searchLink>. Nov2023, Vol. 55 Issue 21, p3670-3684. 15p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Fluoroalkyl+compounds%22">Fluoroalkyl compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Normal-phase+chromatography%22">Normal-phase chromatography</searchLink><br /><searchLink fieldCode="DE" term="%22Iodides%22">Iodides</searchLink><br /><searchLink fieldCode="DE" term="%22Materials+science%22">Materials science</searchLink><br /><searchLink fieldCode="DE" term="%22Thin+layer+chromatography%22">Thin layer chromatography</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: SP 1 sp H NMR (300 MHz, acetone- I d i SB 6 sb ): = 11.66 (s, 1 H, H SB N-H sb ), 8.39 (d, I J i = 8.2 Hz, 1 H, H SB 7 sb ), 8.35 (d, I J i = 2.6 Hz, 1 H, H SB 2 sb ), 8.12 (d, I J i = 8.3 Hz, 1 H, H SB 6 sb ). SP 1 sp H NMR (300 MHz, acetone- I d i SB 6 sb ): = 11.49 (s, 1 H, H SB N-H sb ), 8.78 (d, I J i = 2.3 Hz, 1 H, H SB 5 sb ), 8.46 (d, I J i = 2.3 Hz, 1 H, H SB 7 sb ), 8.30 (d, I J i = 2.8 Hz, 1 H, H SB 2 sb ), 8.17-8.07 (m, 2 H, H SB 10or11 sb ), 8.03-7.94 (m, 2 H, H SB 10or11 sb ). SP 13 sp C NMR (75 MHz, acetone- I d i SB 6 sb ): = 157.11 (d, I J i = 15.3 Hz, C SB 4 sb ), 155.38 (dd, I J i = 263.6, 4.4 Hz, Cq), 150.58 (dd, I J i = 253.0, 4.6 Hz, Cq), 148.32 (Cq), 147.54 (C SB 2 sb ), 121.72 (Cq), 120.75 (d, I J i = 3.6 Hz, Cq), 120.03 (Cq), 120.0-104.00 (m, C SB CF sb ). SP 13 sp C NMR (75 MHz, acetone- I d i SB 6 sb ): = 159.44 (C SB 4 sb ), 155.77 (dd, I J i = 266.4, 19.7 Hz, Cq), 150.08 (dd, I J i = 250.8, 15.1 Hz, Cq), 147.14 (C SB 2 sb ), 146.85-146.21 (m, Cq), 122.57-121.48 (m, Cq), 119.05 (dd, I J i = 18.9, 3.4 Hz, C SB 5 sb ), 118.93-114.64 (m, Cq), 119.00-105.00 (m, C SB CF sb ). SP 13 sp C NMR (75 MHz, acetone- I d i SB 6 sb ): = 159.91 (dt, I J i = 252.3, 5.2 Hz, C SB 6 sb ), 157.63 (d, I J i = 3.8 Hz, C SB 4 sb ), 147.42 (Cq), 146.79 (C SB 2 sb ), 133.10 (d, I J i = 7.3 Hz, Cq), 126.29-125.29 (m, C SB 5,7,8 sb ),, 123.00-105.00 (m, C SB CF sb ). [Extracted from the article]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Synthesis is the property of Georg Thieme Verlag Stuttgart and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1055/a-2054-0482
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      – Code: eng
        Text: English
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        PageCount: 15
        StartPage: 3670
    Subjects:
      – SubjectFull: Fluoroalkyl compounds
        Type: general
      – SubjectFull: Normal-phase chromatography
        Type: general
      – SubjectFull: Iodides
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      – SubjectFull: Materials science
        Type: general
      – SubjectFull: Thin layer chromatography
        Type: general
    Titles:
      – TitleFull: Photocatalyst-Free, Visible-Light-Mediated C–H Perfluoroalkylation of Quinazolin-4(3 H)-ones with perfluoroalkyl Iodides.
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            NameFull: Delouche, Thomas
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            NameFull: Gadiry-Diallo, Abdoul
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            NameFull: Besson, Thierry
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            – D: 02
              M: 11
              Text: Nov2023
              Type: published
              Y: 2023
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