View in EDS HTML Full Text PDF Full Text

Photoinitiated polymerization of beta-cyclodextrin-stabilized Pickering high internal phase emulsion for preparation of polymethacrylate microsphere and its adsorption towards dyes.

Saved in:
Bibliographic Details
Title: Photoinitiated polymerization of beta-cyclodextrin-stabilized Pickering high internal phase emulsion for preparation of polymethacrylate microsphere and its adsorption towards dyes.
Authors: Zhang, Yipeng1 (AUTHOR), Jiang, Ruohai1 (AUTHOR), Zhang, Yujie1 (AUTHOR), Huang, Chaozhang2 (AUTHOR), Xiong, Xiaopeng1 (AUTHOR) xpxiong@xmu.edu.cn
Source: Journal of Materials Science. Nov2023, Vol. 58 Issue 41, p16002-16018. 17p.
Subjects: Polymethacrylates, Glycidyl methacrylate, Polymerization, Emulsions, Adsorption (Chemistry), Drug carriers, Monomers
Abstract: Microsphere polymer material finds a wide range of applications in fields such as adsorbent, drug carrier, catalyst and coating, and receives continuous attention. We here report a novel strategy of quick synthesis of polymethacrylate microsphere via photoinitiated polymerization of methacrylate monomer in a high internal phase emulsion (HIPE). A low cost and environmentally friendly natural product of β-cyclodextrin (β-CD) has been directly used as Pickering emulsifier to stabilize the methacrylate monomer in water to prepare the HIPE. The factors to control the particle size such as the dosage of β-CD, volume fraction of monomer internal phase and amount of inert diluting solvent, have been investigated in detail. Meanwhile, the approach has been validated by using various methacrylate monomers. Our results indicate that using a diluting solvent can not only change the surface morphology but also control the inner microstructure of the microsphere. By using a poor solvent of cyclohexane as diluting agent, porous microsphere other than solid microsphere has been prepared, and it could be directly applied as adsorbent to decolor oil. Moreover, the obtained poly(glycidyl methacrylate) microsphere was post-modified to exhibit satisfactory adsorption efficiencies towards organic dye contaminates in water. Those results indicate powerful platform of the obtained microsphere with reactive groups for further modification to prepare functional materials for desired purposes. Based on the fast synthesis, high yield, low energy cost as well as no harmful waste, the preparation strategy reported in this work could be scalable, and the obtained microsphere may find promising potential applications. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
Full text is not displayed to guests.
FullText Links:
  – Type: pdflink
Text:
  Availability: 1
Header DbId: egs
DbLabel: Engineering Source
An: 173455605
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Photoinitiated polymerization of beta-cyclodextrin-stabilized Pickering high internal phase emulsion for preparation of polymethacrylate microsphere and its adsorption towards dyes.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Zhang%2C+Yipeng%22">Zhang, Yipeng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jiang%2C+Ruohai%22">Jiang, Ruohai</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhang%2C+Yujie%22">Zhang, Yujie</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Huang%2C+Chaozhang%22">Huang, Chaozhang</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xiong%2C+Xiaopeng%22">Xiong, Xiaopeng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> xpxiong@xmu.edu.cn</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Journal+of+Materials+Science%22">Journal of Materials Science</searchLink>. Nov2023, Vol. 58 Issue 41, p16002-16018. 17p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Polymethacrylates%22">Polymethacrylates</searchLink><br /><searchLink fieldCode="DE" term="%22Glycidyl+methacrylate%22">Glycidyl methacrylate</searchLink><br /><searchLink fieldCode="DE" term="%22Polymerization%22">Polymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Emulsions%22">Emulsions</searchLink><br /><searchLink fieldCode="DE" term="%22Adsorption+%28Chemistry%29%22">Adsorption (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Drug+carriers%22">Drug carriers</searchLink><br /><searchLink fieldCode="DE" term="%22Monomers%22">Monomers</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Microsphere polymer material finds a wide range of applications in fields such as adsorbent, drug carrier, catalyst and coating, and receives continuous attention. We here report a novel strategy of quick synthesis of polymethacrylate microsphere via photoinitiated polymerization of methacrylate monomer in a high internal phase emulsion (HIPE). A low cost and environmentally friendly natural product of β-cyclodextrin (β-CD) has been directly used as Pickering emulsifier to stabilize the methacrylate monomer in water to prepare the HIPE. The factors to control the particle size such as the dosage of β-CD, volume fraction of monomer internal phase and amount of inert diluting solvent, have been investigated in detail. Meanwhile, the approach has been validated by using various methacrylate monomers. Our results indicate that using a diluting solvent can not only change the surface morphology but also control the inner microstructure of the microsphere. By using a poor solvent of cyclohexane as diluting agent, porous microsphere other than solid microsphere has been prepared, and it could be directly applied as adsorbent to decolor oil. Moreover, the obtained poly(glycidyl methacrylate) microsphere was post-modified to exhibit satisfactory adsorption efficiencies towards organic dye contaminates in water. Those results indicate powerful platform of the obtained microsphere with reactive groups for further modification to prepare functional materials for desired purposes. Based on the fast synthesis, high yield, low energy cost as well as no harmful waste, the preparation strategy reported in this work could be scalable, and the obtained microsphere may find promising potential applications. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=173455605
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1007/s10853-023-09041-x
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 17
        StartPage: 16002
    Subjects:
      – SubjectFull: Polymethacrylates
        Type: general
      – SubjectFull: Glycidyl methacrylate
        Type: general
      – SubjectFull: Polymerization
        Type: general
      – SubjectFull: Emulsions
        Type: general
      – SubjectFull: Adsorption (Chemistry)
        Type: general
      – SubjectFull: Drug carriers
        Type: general
      – SubjectFull: Monomers
        Type: general
    Titles:
      – TitleFull: Photoinitiated polymerization of beta-cyclodextrin-stabilized Pickering high internal phase emulsion for preparation of polymethacrylate microsphere and its adsorption towards dyes.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Zhang, Yipeng
      – PersonEntity:
          Name:
            NameFull: Jiang, Ruohai
      – PersonEntity:
          Name:
            NameFull: Zhang, Yujie
      – PersonEntity:
          Name:
            NameFull: Huang, Chaozhang
      – PersonEntity:
          Name:
            NameFull: Xiong, Xiaopeng
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 11
              Text: Nov2023
              Type: published
              Y: 2023
          Identifiers:
            – Type: issn-print
              Value: 00222461
          Numbering:
            – Type: volume
              Value: 58
            – Type: issue
              Value: 41
          Titles:
            – TitleFull: Journal of Materials Science
              Type: main
ResultId 1