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Complex material analysis of a TiC coating produced by hot pressing with optical light microscopy, EDS, XRD, GDOES and EBSD.

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Title: Complex material analysis of a TiC coating produced by hot pressing with optical light microscopy, EDS, XRD, GDOES and EBSD.
Authors: Grad, Marius1,2 (AUTHOR) marius.grad@tu-ilmenau.de, Honig, Hauke1 (AUTHOR), Diemar, Andreas1,3 (AUTHOR), Flock, Dominik1 (AUTHOR), Spieß, Lothar1 (AUTHOR)
Source: Surface & Coatings Technology. Jan2024, Vol. 476, pN.PAG-N.PAG. 1p.
Subjects: X-ray diffraction, Materials analysis, Microscopy, Titanium carbide, Rietveld refinement, Carbon steel
Abstract: The present study investigates the interface between carbon steel and titanium samples annealed at different temperatures (ϑ 1 = ▪ and ϑ 2 = ▪). In both cases, an observable layer forms at the interface, with its thickness increasing from t ϑ 1 = 2.75 ± ▪ at ▪ to t ϑ 2 = 8.86 ± ▪ at ▪. The layer's composition and thickness evolve with temperature. Analysis reveals approximately 40 at.-% carbon concentration in the exterior region, indicating likely titanium carbide creation. X-ray diffraction identifies titanium carbide peaks, while microscopy and elemental mapping confirm compositional gradients at the interface. Electron Backscatter Diffraction (EBSD) shows a gradient in grain size near the TiC surface, reflecting TiC nucleation rates. XRD data detect both titanium carbide and titanium phases, with TiC becoming more prominent at ▪. Rietveld analysis further confirms TiC formation. Notably, distinct diffraction patterns on the contact and rear sides suggest a Ti(C, O, N) presence. Depth profiles exhibit varying surface and depth carbon concentrations, attributed to temperature effects. The study successfully demonstrates TiC coating fabrication through hot pressing, wherein Ti(C, O, N) coatings arise from titanium's affinity for reacting with oxygen and nitrogen. This research contributes to the understanding of phase transformations and interfacial properties in titanium-carbon steel systems. • Hot pressing provides a simple method for creating a TiC film on Ti substrates. • Theoretical considerations are proven by investigations with EDS, XRD, GDOES, EBSD. • EBSD analyses confirm a graded microstructure within the layer. • GDOES and EDS measurements indicate oxygen and nitrogen on the surface. • XRD verifies the presence of TiC and Ti(C,O,N), matching the element distribution. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
Description
Abstract:The present study investigates the interface between carbon steel and titanium samples annealed at different temperatures (ϑ 1 = ▪ and ϑ 2 = ▪). In both cases, an observable layer forms at the interface, with its thickness increasing from t ϑ 1 = 2.75 ± ▪ at ▪ to t ϑ 2 = 8.86 ± ▪ at ▪. The layer's composition and thickness evolve with temperature. Analysis reveals approximately 40 at.-% carbon concentration in the exterior region, indicating likely titanium carbide creation. X-ray diffraction identifies titanium carbide peaks, while microscopy and elemental mapping confirm compositional gradients at the interface. Electron Backscatter Diffraction (EBSD) shows a gradient in grain size near the TiC surface, reflecting TiC nucleation rates. XRD data detect both titanium carbide and titanium phases, with TiC becoming more prominent at ▪. Rietveld analysis further confirms TiC formation. Notably, distinct diffraction patterns on the contact and rear sides suggest a Ti(C, O, N) presence. Depth profiles exhibit varying surface and depth carbon concentrations, attributed to temperature effects. The study successfully demonstrates TiC coating fabrication through hot pressing, wherein Ti(C, O, N) coatings arise from titanium's affinity for reacting with oxygen and nitrogen. This research contributes to the understanding of phase transformations and interfacial properties in titanium-carbon steel systems. • Hot pressing provides a simple method for creating a TiC film on Ti substrates. • Theoretical considerations are proven by investigations with EDS, XRD, GDOES, EBSD. • EBSD analyses confirm a graded microstructure within the layer. • GDOES and EDS measurements indicate oxygen and nitrogen on the surface. • XRD verifies the presence of TiC and Ti(C,O,N), matching the element distribution. [ABSTRACT FROM AUTHOR]
ISSN:02578972
DOI:10.1016/j.surfcoat.2023.130265