Rhenium Cluster Complexes with Polyborohydride Anions, [Re6S8(Me2PzH)6]X (X = B10H10, B12H12).
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| Title: | Rhenium Cluster Complexes with Polyborohydride Anions, [Re |
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| Authors: | Davydova, M. P.1 (AUTHOR), Sukhikh, T. S.1 (AUTHOR), Rakhmanova, M. I.1 (AUTHOR), Brylev, K. A.1 (AUTHOR), Artem'ev, A. V.1 (AUTHOR) chemisufarm@yandex.ru |
| Source: | Journal of Structural Chemistry. Jan2024, Vol. 65 Issue 1, p186-195. 10p. |
| Subjects: | Rhenium, Anions, Phosphorescence |
| Abstract: | Interaction of [Re6S8(Me2PzH)6]Br2 with K2B10H10 and (Et3NH)2B12H12 yields novel [Re6S8(Me2PzH)6][B10H10] (1) and [Re6S8(Me2PzH)6][B12H12] (2) hybrid compounds combining [Re6S8 (Me2PzH)6]2+ metal-cluster cations and [BnHn]2– polyborohydride cluster anions (n = 10, 12) in their structure. Crystals of the prepared compounds exhibit an ionic 3D supramolecular structure formed by short H–B⋯H–C contacts. At room temperature, these compounds exhibit red phosphorescence with λmax = 680 nm (1) and 670 nm (2), respectively. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Structural Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Header | DbId: egs DbLabel: Engineering Source An: 175359798 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Rhenium Cluster Complexes with Polyborohydride Anions, [Re<subscript>6</subscript>S<subscript>8</subscript>(Me<subscript>2</subscript>PzH)<subscript>6</subscript>]X (X = B<subscript>10</subscript>H<subscript>10</subscript>, B<subscript>12</subscript>H<subscript>12</subscript>). – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Davydova%2C+M%2E+P%2E%22">Davydova, M. P.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sukhikh%2C+T%2E+S%2E%22">Sukhikh, T. S.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Rakhmanova%2C+M%2E+I%2E%22">Rakhmanova, M. I.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Brylev%2C+K%2E+A%2E%22">Brylev, K. A.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Artem'ev%2C+A%2E+V%2E%22">Artem'ev, A. V.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> chemisufarm@yandex.ru</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Structural+Chemistry%22">Journal of Structural Chemistry</searchLink>. Jan2024, Vol. 65 Issue 1, p186-195. 10p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Rhenium%22">Rhenium</searchLink><br /><searchLink fieldCode="DE" term="%22Anions%22">Anions</searchLink><br /><searchLink fieldCode="DE" term="%22Phosphorescence%22">Phosphorescence</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Interaction of [Re6S8(Me2PzH)6]Br2 with K2B10H10 and (Et3NH)2B12H12 yields novel [Re6S8(Me2PzH)6][B10H10] (1) and [Re6S8(Me2PzH)6][B12H12] (2) hybrid compounds combining [Re6S8 (Me2PzH)6]2+ metal-cluster cations and [BnHn]2– polyborohydride cluster anions (n = 10, 12) in their structure. Crystals of the prepared compounds exhibit an ionic 3D supramolecular structure formed by short H–B⋯H–C contacts. At room temperature, these compounds exhibit red phosphorescence with λmax = 680 nm (1) and 670 nm (2), respectively. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Structural Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1134/S0022476624010177 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 10 StartPage: 186 Subjects: – SubjectFull: Rhenium Type: general – SubjectFull: Anions Type: general – SubjectFull: Phosphorescence Type: general Titles: – TitleFull: Rhenium Cluster Complexes with Polyborohydride Anions, [Re6S8(Me2PzH)6]X (X = B10H10, B12H12). Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Davydova, M. P. – PersonEntity: Name: NameFull: Sukhikh, T. S. – PersonEntity: Name: NameFull: Rakhmanova, M. I. – PersonEntity: Name: NameFull: Brylev, K. A. – PersonEntity: Name: NameFull: Artem'ev, A. V. IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 01 Text: Jan2024 Type: published Y: 2024 Identifiers: – Type: issn-print Value: 00224766 Numbering: – Type: volume Value: 65 – Type: issue Value: 1 Titles: – TitleFull: Journal of Structural Chemistry Type: main |
| ResultId | 1 |
