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Immobilized copper(II) complexes on montmorillonite and MCM-41 as selective catalysts for epoxidation of alkenes

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Title: Immobilized copper(II) complexes on montmorillonite and MCM-41 as selective catalysts for epoxidation of alkenes
Authors: Ghadiri, M.1, Farzaneh, F.1 farzaneh@alzahra.ac.ir, Ghandi, M.2, Alizadeh, M.2
Source: Journal of Molecular Catalysis A: Chemistry. May2005, Vol. 233 Issue 1/2, p127-131. 5p.
Subjects: Chemical inhibitors, Bipyridine, Epoxy compounds, Smectite
Abstract: Abstract: Copper(II) complexes with 2,2′-bipyridine(bpy) and 1,8-dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane (macrocycle) immobilized between silicate layers of montmorillonite and nanoreactors of MCM-41 successfully catalyze the epoxidation of norbornene and trans-2-hexene-1-ol with good to excellent reactivity and 48–100% selectivity toward the formation of the corresponding epoxides. [Copyright &y& Elsevier]
Copyright of Journal of Molecular Catalysis A: Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 17656430
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: Immobilized copper(II) complexes on montmorillonite and MCM-41 as selective catalysts for epoxidation of alkenes
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  Data: <searchLink fieldCode="AR" term="%22Ghadiri%2C+M%2E%22">Ghadiri, M.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Farzaneh%2C+F%2E%22">Farzaneh, F.</searchLink><relatesTo>1</relatesTo><i> farzaneh@alzahra.ac.ir</i><br /><searchLink fieldCode="AR" term="%22Ghandi%2C+M%2E%22">Ghandi, M.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Alizadeh%2C+M%2E%22">Alizadeh, M.</searchLink><relatesTo>2</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Molecular+Catalysis+A%3A+Chemistry%22">Journal of Molecular Catalysis A: Chemistry</searchLink>. May2005, Vol. 233 Issue 1/2, p127-131. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Chemical+inhibitors%22">Chemical inhibitors</searchLink><br /><searchLink fieldCode="DE" term="%22Bipyridine%22">Bipyridine</searchLink><br /><searchLink fieldCode="DE" term="%22Epoxy+compounds%22">Epoxy compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Smectite%22">Smectite</searchLink>
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  Label: Abstract
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  Data: Abstract: Copper(II) complexes with 2,2′-bipyridine(bpy) and 1,8-dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane (macrocycle) immobilized between silicate layers of montmorillonite and nanoreactors of MCM-41 successfully catalyze the epoxidation of norbornene and trans-2-hexene-1-ol with good to excellent reactivity and 48–100% selectivity toward the formation of the corresponding epoxides. [Copyright &y& Elsevier]
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  Data: <i>Copyright of Journal of Molecular Catalysis A: Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.molcata.2005.01.046
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        Text: English
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      – SubjectFull: Epoxy compounds
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      – TitleFull: Immobilized copper(II) complexes on montmorillonite and MCM-41 as selective catalysts for epoxidation of alkenes
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