Bibliographic Details
| Title: |
Immobilized copper(II) complexes on montmorillonite and MCM-41 as selective catalysts for epoxidation of alkenes |
| Authors: |
Ghadiri, M.1, Farzaneh, F.1 farzaneh@alzahra.ac.ir, Ghandi, M.2, Alizadeh, M.2 |
| Source: |
Journal of Molecular Catalysis A: Chemistry. May2005, Vol. 233 Issue 1/2, p127-131. 5p. |
| Subjects: |
Chemical inhibitors, Bipyridine, Epoxy compounds, Smectite |
| Abstract: |
Abstract: Copper(II) complexes with 2,2′-bipyridine(bpy) and 1,8-dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane (macrocycle) immobilized between silicate layers of montmorillonite and nanoreactors of MCM-41 successfully catalyze the epoxidation of norbornene and trans-2-hexene-1-ol with good to excellent reactivity and 48–100% selectivity toward the formation of the corresponding epoxides. [Copyright &y& Elsevier] |
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| Database: |
Engineering Source |