New use of an Ag electrode and a potentiodynamic method to control the presence of chlorides in porous media like concrete.

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Title: New use of an Ag electrode and a potentiodynamic method to control the presence of chlorides in porous media like concrete.
Authors: Martínez Ibernón, Ana1 (AUTHOR) anmarib@arqt.upv.es, Gasch, Isabel1 (AUTHOR), Romero, José M. Gandía1 (AUTHOR), Soto, Juan1 (AUTHOR)
Source: Electrochimica Acta. Jun2024, Vol. 488, pN.PAG-N.PAG. 1p.
Subjects: Porous materials, Real-time control, Chlorides, Reinforced concrete, Electrochemical sensors, Reinforced concrete corrosion
Abstract: Chloride detection in porous materials is important for the soil characterisation and the durability control of reinforced concrete structures. Chloride content in soil can affect soil fertility, and the presence of chlorides in reinforced concrete structures can trigger the corrosion of reinforcement, which leads to structure failure. In both cases, the material in which chlorides are detected is a porous medium. Traditionally in this type of materials, chlorides have been controlled by means of tedious laboratory tests, in which specimens of the material are used, as are passive sensor systems like potentiometric sensors. In the former, tests are usually costly and do not allow effective control in real time. In the latter, as the sensor is not excited, overlapping reactions occur on its surface that can lead to errors when estimating chloride content. In aqueous media, chloride detection is efficiently carried out by electrochemical sensors using potentiodynamic techniques. However, they have hardly been employed in porous media, in which the porous network contains the so-called "pore solution". The present work aims to evaluate the feasibility of using an Ag electrode together with a triangular sweep potentiodynamic signal using concretes of different porosities as a porous medium. This opens up a new study field in electrochemical sensor technology. [ABSTRACT FROM AUTHOR]
Copyright of Electrochimica Acta is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: New use of an Ag electrode and a potentiodynamic method to control the presence of chlorides in porous media like concrete.
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  Data: <searchLink fieldCode="JN" term="%22Electrochimica+Acta%22">Electrochimica Acta</searchLink>. Jun2024, Vol. 488, pN.PAG-N.PAG. 1p.
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  Data: <searchLink fieldCode="DE" term="%22Porous+materials%22">Porous materials</searchLink><br /><searchLink fieldCode="DE" term="%22Real-time+control%22">Real-time control</searchLink><br /><searchLink fieldCode="DE" term="%22Chlorides%22">Chlorides</searchLink><br /><searchLink fieldCode="DE" term="%22Reinforced+concrete%22">Reinforced concrete</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochemical+sensors%22">Electrochemical sensors</searchLink><br /><searchLink fieldCode="DE" term="%22Reinforced+concrete+corrosion%22">Reinforced concrete corrosion</searchLink>
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  Label: Abstract
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  Data: Chloride detection in porous materials is important for the soil characterisation and the durability control of reinforced concrete structures. Chloride content in soil can affect soil fertility, and the presence of chlorides in reinforced concrete structures can trigger the corrosion of reinforcement, which leads to structure failure. In both cases, the material in which chlorides are detected is a porous medium. Traditionally in this type of materials, chlorides have been controlled by means of tedious laboratory tests, in which specimens of the material are used, as are passive sensor systems like potentiometric sensors. In the former, tests are usually costly and do not allow effective control in real time. In the latter, as the sensor is not excited, overlapping reactions occur on its surface that can lead to errors when estimating chloride content. In aqueous media, chloride detection is efficiently carried out by electrochemical sensors using potentiodynamic techniques. However, they have hardly been employed in porous media, in which the porous network contains the so-called "pore solution". The present work aims to evaluate the feasibility of using an Ag electrode together with a triangular sweep potentiodynamic signal using concretes of different porosities as a porous medium. This opens up a new study field in electrochemical sensor technology. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Electrochimica Acta is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.electacta.2024.144230
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Porous materials
        Type: general
      – SubjectFull: Real-time control
        Type: general
      – SubjectFull: Chlorides
        Type: general
      – SubjectFull: Reinforced concrete
        Type: general
      – SubjectFull: Electrochemical sensors
        Type: general
      – SubjectFull: Reinforced concrete corrosion
        Type: general
    Titles:
      – TitleFull: New use of an Ag electrode and a potentiodynamic method to control the presence of chlorides in porous media like concrete.
        Type: main
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          Name:
            NameFull: Martínez Ibernón, Ana
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          Name:
            NameFull: Gasch, Isabel
      – PersonEntity:
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            NameFull: Romero, José M. Gandía
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            NameFull: Soto, Juan
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          Dates:
            – D: 01
              M: 06
              Text: Jun2024
              Type: published
              Y: 2024
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              Value: 488
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            – TitleFull: Electrochimica Acta
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