Physico-Chemical Properties of CdTe/Glutathione Quantum Dots Obtained by Microwave Irradiation for Use in Monoclonal Antibody and Biomarker Testing.
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| Title: | Physico-Chemical Properties of CdTe/Glutathione Quantum Dots Obtained by Microwave Irradiation for Use in Monoclonal Antibody and Biomarker Testing. |
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| Authors: | Ruiz-Robles, M. A.1 (AUTHOR) mitchel.ruizrb@uanl.edu.mx, Solís-Pomar, Francisco J.1 (AUTHOR) claudio.gutierrezl@uanl.edu.mx, Travieso Aguilar, Gabriela2 (AUTHOR) gabriela.travieso@imre.uh.cu, Márquez Mijares, Maykel3 (AUTHOR) mmarquez@instec.cu, Garrido Arteaga, Raine4 (AUTHOR) rgarrido@finlay.edu.cu, Martínez Armenteros, Olivia4 (AUTHOR) omartinez@finlay.edu.cu, Gutiérrez-Lazos, C. D.1 (AUTHOR) eduardo.pereztj@uanl.edu.mx, Pérez-Tijerina, Eduardo G.1 (AUTHOR), Fundora Cruz, Abel3 (AUTHOR) abel.fundora@instec.cu |
| Source: | Nanomaterials (2079-4991). Apr2024, Vol. 14 Issue 8, p684. 18p. |
| Subjects: | Quantum dots, Inductively coupled plasma atomic emission spectrometry, Antibody titer, Glutathione, Microwave spectroscopy |
| Abstract: | In this report, we present the results on the physicochemical characterization of cadmium telluride quantum dots (QDs) stabilized with glutathione and prepared by optimizing the synthesis conditions. An excellent control of emissions and the composition of the nanocrystal surface for its potential application in monoclonal antibody and biomarker testing was achieved. Two samples (QDYellow, QDOrange, corresponding to their emission colors) were analyzed by dynamic light scattering (DLS), and their hydrodynamic sizes were 6.7 nm and 19.4 nm, respectively. Optical characterization by UV-vis absorbance spectroscopy showed excitonic peaks at 517 nm and 554 nm. Photoluminescence spectroscopy indicated that the samples have a maximum intensity emission at 570 and 606 nm, respectively, within the visible range from yellow to orange. Infrared spectroscopy showed vibrational modes corresponding to the functional groups OH-C-H, C-N, C=C, C-O, C-OH, and COOH, which allows for the formation of functionalized QDs for the manufacture of biomarkers. In addition, the hydrodynamic radius, zeta potential, and approximate molecular weight were determined by dynamic light scattering (DLS), electrophoretic light scattering (ELS), and static light scattering (SLS) techniques. Size dispersion and the structure of nanoparticles was obtained by Transmission Electron Microscopy (TEM) and by X-ray diffraction. In the same way, we calculated the concentration of Cd2+ ions expressed in mg/L by using the Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-OES). In addition to the characterization of the nanoparticles, the labeling of murine myeloid cells was carried out with both samples of quantum dots, where it was demonstrated that quantum dots can diffuse into these cells and connect mostly with the cell nucleus. [ABSTRACT FROM AUTHOR] |
| Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
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| Header | DbId: egs DbLabel: Engineering Source An: 176907532 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Physico-Chemical Properties of CdTe/Glutathione Quantum Dots Obtained by Microwave Irradiation for Use in Monoclonal Antibody and Biomarker Testing. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Ruiz-Robles%2C+M%2E+A%2E%22">Ruiz-Robles, M. A.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> mitchel.ruizrb@uanl.edu.mx</i><br /><searchLink fieldCode="AR" term="%22Solís-Pomar%2C+Francisco+J%2E%22">Solís-Pomar, Francisco J.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> claudio.gutierrezl@uanl.edu.mx</i><br /><searchLink fieldCode="AR" term="%22Travieso+Aguilar%2C+Gabriela%22">Travieso Aguilar, Gabriela</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> gabriela.travieso@imre.uh.cu</i><br /><searchLink fieldCode="AR" term="%22Márquez+Mijares%2C+Maykel%22">Márquez Mijares, Maykel</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> mmarquez@instec.cu</i><br /><searchLink fieldCode="AR" term="%22Garrido+Arteaga%2C+Raine%22">Garrido Arteaga, Raine</searchLink><relatesTo>4</relatesTo> (AUTHOR)<i> rgarrido@finlay.edu.cu</i><br /><searchLink fieldCode="AR" term="%22Martínez+Armenteros%2C+Olivia%22">Martínez Armenteros, Olivia</searchLink><relatesTo>4</relatesTo> (AUTHOR)<i> omartinez@finlay.edu.cu</i><br /><searchLink fieldCode="AR" term="%22Gutiérrez-Lazos%2C+C%2E+D%2E%22">Gutiérrez-Lazos, C. D.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> eduardo.pereztj@uanl.edu.mx</i><br /><searchLink fieldCode="AR" term="%22Pérez-Tijerina%2C+Eduardo+G%2E%22">Pérez-Tijerina, Eduardo G.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Fundora+Cruz%2C+Abel%22">Fundora Cruz, Abel</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> abel.fundora@instec.cu</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Nanomaterials+%282079-4991%29%22">Nanomaterials (2079-4991)</searchLink>. Apr2024, Vol. 14 Issue 8, p684. 18p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Quantum+dots%22">Quantum dots</searchLink><br /><searchLink fieldCode="DE" term="%22Inductively+coupled+plasma+atomic+emission+spectrometry%22">Inductively coupled plasma atomic emission spectrometry</searchLink><br /><searchLink fieldCode="DE" term="%22Antibody+titer%22">Antibody titer</searchLink><br /><searchLink fieldCode="DE" term="%22Glutathione%22">Glutathione</searchLink><br /><searchLink fieldCode="DE" term="%22Microwave+spectroscopy%22">Microwave spectroscopy</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: In this report, we present the results on the physicochemical characterization of cadmium telluride quantum dots (QDs) stabilized with glutathione and prepared by optimizing the synthesis conditions. An excellent control of emissions and the composition of the nanocrystal surface for its potential application in monoclonal antibody and biomarker testing was achieved. Two samples (QDYellow, QDOrange, corresponding to their emission colors) were analyzed by dynamic light scattering (DLS), and their hydrodynamic sizes were 6.7 nm and 19.4 nm, respectively. Optical characterization by UV-vis absorbance spectroscopy showed excitonic peaks at 517 nm and 554 nm. Photoluminescence spectroscopy indicated that the samples have a maximum intensity emission at 570 and 606 nm, respectively, within the visible range from yellow to orange. Infrared spectroscopy showed vibrational modes corresponding to the functional groups OH-C-H, C-N, C=C, C-O, C-OH, and COOH, which allows for the formation of functionalized QDs for the manufacture of biomarkers. In addition, the hydrodynamic radius, zeta potential, and approximate molecular weight were determined by dynamic light scattering (DLS), electrophoretic light scattering (ELS), and static light scattering (SLS) techniques. Size dispersion and the structure of nanoparticles was obtained by Transmission Electron Microscopy (TEM) and by X-ray diffraction. In the same way, we calculated the concentration of Cd2+ ions expressed in mg/L by using the Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-OES). In addition to the characterization of the nanoparticles, the labeling of murine myeloid cells was carried out with both samples of quantum dots, where it was demonstrated that quantum dots can diffuse into these cells and connect mostly with the cell nucleus. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.3390/nano14080684 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 18 StartPage: 684 Subjects: – SubjectFull: Quantum dots Type: general – SubjectFull: Inductively coupled plasma atomic emission spectrometry Type: general – SubjectFull: Antibody titer Type: general – SubjectFull: Glutathione Type: general – SubjectFull: Microwave spectroscopy Type: general Titles: – TitleFull: Physico-Chemical Properties of CdTe/Glutathione Quantum Dots Obtained by Microwave Irradiation for Use in Monoclonal Antibody and Biomarker Testing. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Ruiz-Robles, M. A. – PersonEntity: Name: NameFull: Solís-Pomar, Francisco J. – PersonEntity: Name: NameFull: Travieso Aguilar, Gabriela – PersonEntity: Name: NameFull: Márquez Mijares, Maykel – PersonEntity: Name: NameFull: Garrido Arteaga, Raine – PersonEntity: Name: NameFull: Martínez Armenteros, Olivia – PersonEntity: Name: NameFull: Gutiérrez-Lazos, C. D. – PersonEntity: Name: NameFull: Pérez-Tijerina, Eduardo G. – PersonEntity: Name: NameFull: Fundora Cruz, Abel IsPartOfRelationships: – BibEntity: Dates: – D: 15 M: 04 Text: Apr2024 Type: published Y: 2024 Identifiers: – Type: issn-print Value: 20794991 Numbering: – Type: volume Value: 14 – Type: issue Value: 8 Titles: – TitleFull: Nanomaterials (2079-4991) Type: main |
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