Synergistic tuning of photoluminescence and biocompatibility in CaS phosphor through dopant combinations of Eu3+, Dy3+, and Tm3+.

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Title: Synergistic tuning of photoluminescence and biocompatibility in CaS phosphor through dopant combinations of Eu3+, Dy3+, and Tm3+.
Authors: Kavitha, V.1 (AUTHOR), Rani, M. Prema1 (AUTHOR) premaakumar91@gmail.com, Sivaganesh, D.2 (AUTHOR), Ponsuriyaprakash, S.3 (AUTHOR)
Source: Journal of Nanoparticle Research. May2024, Vol. 26 Issue 5, p1-15. 15p.
Subjects: Electric dipole transitions, Phosphors, Doping agents (Chemistry), Photoluminescence, Erythrocytes, Terbium
Abstract: In this work, CaS phosphors were synthesized using the sol–gel method with doping of rare earth metals such as Eu, Dy, and Tm in combination. The optimization of the dopant concentration at 2% allowed for the adjustment of the samples' characteristics. Detailed analyses were carried out, including X-ray diffraction studies, evaluation of photoluminescence characteristics, examination of hemocompatibility, and determination of the average lifetime of the excited state for this novel set of CaS phosphors. The synthesized phosphors displayed intense greenish-yellow emissions at a wavelength of 543 nm, which can be attributed to the electric dipole transition resulting from the dopants. Among the different compositions, the CaS phosphors doped with 2% Eu and 2% Dy showed exceptional structural and morphological qualities. Additionally, this composition exhibited the highest hemolysis inhibition percentage, with 82.37% of red blood cells remaining viable. Moreover, this particular sample demonstrated the maximum light efficacy in terms of radiation and excitation purity. The study emphasizes the luminescent properties and biocompatibility of the CaS phosphor, particularly when enhanced through doping. The findings suggest promising potential for the application of these phosphors in the field of bioimaging. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Nanoparticle Research is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Synergistic tuning of photoluminescence and biocompatibility in CaS phosphor through dopant combinations of Eu<superscript>3+</superscript>, Dy<superscript>3+</superscript>, and Tm<superscript>3+</superscript>.
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Nanoparticle+Research%22">Journal of Nanoparticle Research</searchLink>. May2024, Vol. 26 Issue 5, p1-15. 15p.
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  Data: <searchLink fieldCode="DE" term="%22Electric+dipole+transitions%22">Electric dipole transitions</searchLink><br /><searchLink fieldCode="DE" term="%22Phosphors%22">Phosphors</searchLink><br /><searchLink fieldCode="DE" term="%22Doping+agents+%28Chemistry%29%22">Doping agents (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Photoluminescence%22">Photoluminescence</searchLink><br /><searchLink fieldCode="DE" term="%22Erythrocytes%22">Erythrocytes</searchLink><br /><searchLink fieldCode="DE" term="%22Terbium%22">Terbium</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: In this work, CaS phosphors were synthesized using the sol–gel method with doping of rare earth metals such as Eu, Dy, and Tm in combination. The optimization of the dopant concentration at 2% allowed for the adjustment of the samples' characteristics. Detailed analyses were carried out, including X-ray diffraction studies, evaluation of photoluminescence characteristics, examination of hemocompatibility, and determination of the average lifetime of the excited state for this novel set of CaS phosphors. The synthesized phosphors displayed intense greenish-yellow emissions at a wavelength of 543 nm, which can be attributed to the electric dipole transition resulting from the dopants. Among the different compositions, the CaS phosphors doped with 2% Eu and 2% Dy showed exceptional structural and morphological qualities. Additionally, this composition exhibited the highest hemolysis inhibition percentage, with 82.37% of red blood cells remaining viable. Moreover, this particular sample demonstrated the maximum light efficacy in terms of radiation and excitation purity. The study emphasizes the luminescent properties and biocompatibility of the CaS phosphor, particularly when enhanced through doping. The findings suggest promising potential for the application of these phosphors in the field of bioimaging. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Nanoparticle Research is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1007/s11051-024-05987-4
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 15
        StartPage: 1
    Subjects:
      – SubjectFull: Electric dipole transitions
        Type: general
      – SubjectFull: Phosphors
        Type: general
      – SubjectFull: Doping agents (Chemistry)
        Type: general
      – SubjectFull: Photoluminescence
        Type: general
      – SubjectFull: Erythrocytes
        Type: general
      – SubjectFull: Terbium
        Type: general
    Titles:
      – TitleFull: Synergistic tuning of photoluminescence and biocompatibility in CaS phosphor through dopant combinations of Eu3+, Dy3+, and Tm3+.
        Type: main
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            NameFull: Kavitha, V.
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            NameFull: Rani, M. Prema
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            NameFull: Sivaganesh, D.
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            NameFull: Ponsuriyaprakash, S.
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            – D: 01
              M: 05
              Text: May2024
              Type: published
              Y: 2024
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              Value: 26
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